Highly efficient and stable perovskite solar cells using thionyl chloride as a p-type dopant for spiro-OMeTAD
TL;DR: In this paper, a dopant, thionyl chloride (SOCl2), was introduced to oxidize spiro-OMeTAD and generate more spiro OO-TAD.
About: This article is published in Journal of Alloys and Compounds.The article was published on 2020-12-20. It has received 17 citations till now. The article focuses on the topics: Dopant & Perovskite (structure).
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TL;DR: In this paper, the authors proposed a method to suppress recombination in Pb-based perovskite-based solar cells to improve the performance of third-generation solar cells.
Abstract: Passivating defects to suppress recombination is a valid tactic to improve the performance of third-generation perovskite-based solar cells. Pb0 is the primary defect in Pb-based perovskites. Here,...
28 citations
TL;DR: In this article , the concept of spirolinkage for synthesis of spiro-based hole transport material (HTM) is discussed, followed by an overview of the desirable optical and electrical properties of SPIRO•OMeTAD.
Abstract: The hole transport material (HTM) of organic–inorganic perovskite solar cells (PVSCs) plays a very important role for achieving high power conversion efficiency and long‐term stability. 2,2’,7,7’‐tetrakis[N,N‐di(4‐methoxyphenyl)amino]‐9‐9’‐spirobifluorene (spiro‐OMeTAD) is the first solid‐state HTM used in PVSCs and has gained tremendous attention during the last decade. Herein, the concept of spirolinkage for synthesis of spiro‐based HTMs is discussed, followed by an overview of the desirable optical and electrical properties of spiro‐OMeTAD. Recent progress in efficiency improvements of spiro‐based PVSCs is analyzed systematically, and the impacts of interface engineering, dopant‐free spiro‐OMeTAD, and novel spiro‐based HTMs are reviewed in detail. The hole mobility of spiro‐OMeTAD depends on the types of dopants and doping concentration. Commonly used lithium bis(trifluoromethylsulfonyl)imide and 4‐tert‐butylpyridine additives reduce the PVSC stability due to hygroscopicity and corrosiveness, respectively. The effects of additives on device stability and the techniques to improve the long‐term stability of spiro‐based PVSCs are also discussed. The review and analysis of various methods and strategies presented is useful for the perovskite research community, providing guidance and directions toward the further development of spiro‐based HTMs for PVSCs with improved efficiency and stability.
14 citations
TL;DR: In this paper , an HTL composition-conditioning agent (CCA), SpiroBD•2OEG, is designed, which contains a Spiro•OMeTAD-like backbone, functional pyridine units, and oligo (ethylene glycol) chains.
Abstract: The doped Spiro‐OMeTAD hole transport layer (HTL) formed using the lithium bis(trifluoromethane) sulfonimide salt and 4‐tert‐butylpyridine with phenethylammonium iodide surface treatment on a perovskite film has continuously dominated the record power conversion efficiencies (PCEs) of perovskite solar cells (pero‐SCs). However, unstable HTL compositions and iodide salts can cause severe device degradation. In this study, an HTL composition‐conditioning agent (CCA), Spiro‐BD‐2OEG, is designed, which contains a Spiro‐OMeTAD‐like backbone, functional pyridine units, and oligo (ethylene glycol) chains. This finely designed CCA presents good miscibility with Spiro‐OMeTAD and its dopants and acts as a conditioning agent through weak bond interactions. As a result, the CCA‐regulated HTL shows a pinhole‐free and smooth morphology with enhanced Spiro‐OMeTAD ordering and improves dopant stability. In addition, the gradient‐distributed CCA in the HTL can narrow the energy level offset with the valence band of the perovskite. The resultant pero‐SCs exhibit an excellent PCE of 24.19% without any interface treatment and weak size dependence. A remarkable PCE of 22.63% is obtained even for a 1.004‐cm2 device. Importantly, the strategy shows good universality and significantly promotes the long‐term stability of the pero‐SCs based on the classical doped Spiro‐OMeTAD.
12 citations
TL;DR: In this article, an extremely cheap, environmentally friendly and nature cellulose derivative with plentiful hydrogen bonds, cellulose acetate (CA), is introduced into perovskite precursor solution to serve as bifunctional green additive.
9 citations
TL;DR: The carrier dynamic transportation behaviour at the CIS/perovskite interface was studied, which showed that CIS QDs as HTMs in PSCs can strongly quench the fluorescence and increase the photobleaching recovery rate.
Abstract: Inorganic quantum dot (QD)-based hole-transport materials (HTMs) have proved their potential in perovskite solar cells (PSCs). In this work, CuInS2 quantum dots (CIS QDs) were applied as HTMs for PSCs with the architecture of TiO2/Cs0.17FA0.83Pb(Br0.2I0.8)3/HTM/Au. By optimizing the preparation process, a high-quality perovskite thin film could be obtained. When the speed was 5000 rpm, the speed acceleration was 3000 rpm per s and heat treated at 150 °C, the perovskite film had low surface roughness (15.26 nm) and obvious grain boundary. The photoelectric conversion efficiency (PCE) of PSCs was greatly improved from 2.83% to 12.33% utilizing CIS QDs at an optimal concentration and with surface ligands as HTMs. Surface ligands can control the size and shape of CIS QDs, and thus affect the performance of PSCs. The carrier dynamic transportation behaviour at the CIS/perovskite interface was studied, which showed that CIS QDs as HTMs in PSCs can strongly quench the fluorescence and increase the photobleaching recovery rate. Therefore, CIS QDs are promising inorganic HTMs for the fabrication of PSCs.
8 citations
References
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TL;DR: Two organolead halide perovskite nanocrystals were found to efficiently sensitize TiO(2) for visible-light conversion in photoelectrochemical cells, which exhibit strong band-gap absorptions as semiconductors.
Abstract: Two organolead halide perovskite nanocrystals, CH3NH3PbBr3 and CH3NH3PbI3, were found to efficiently sensitize TiO2 for visible-light conversion in photoelectrochemical cells. When self-assembled on mesoporous TiO2 films, the nanocrystalline perovskites exhibit strong band-gap absorptions as semiconductors. The CH3NH3PbI3-based photocell with spectral sensitivity of up to 800 nm yielded a solar energy conversion efficiency of 3.8%. The CH3NH3PbBr3-based cell showed a high photovoltage of 0.96 V with an external quantum conversion efficiency of 65%.
16,634 citations
TL;DR: A low-cost, solution-processable solar cell, based on a highly crystalline perovskite absorber with intense visible to near-infrared absorptivity, that has a power conversion efficiency of 10.9% in a single-junction device under simulated full sunlight is reported.
Abstract: The energy costs associated with separating tightly bound excitons (photoinduced electron-hole pairs) and extracting free charges from highly disordered low-mobility networks represent fundamental losses for many low-cost photovoltaic technologies. We report a low-cost, solution-processable solar cell, based on a highly crystalline perovskite absorber with intense visible to near-infrared absorptivity, that has a power conversion efficiency of 10.9% in a single-junction device under simulated full sunlight. This "meso-superstructured solar cell" exhibits exceptionally few fundamental energy losses; it can generate open-circuit photovoltages of more than 1.1 volts, despite the relatively narrow absorber band gap of 1.55 electron volts. The functionality arises from the use of mesoporous alumina as an inert scaffold that structures the absorber and forces electrons to reside in and be transported through the perovskite.
9,158 citations
TL;DR: In this article, a review describes the rapid progress that has been made in hybrid organic-inorganic perovskite solar cells and their applications in the photovoltaic sector.
Abstract: Within the space of a few years, hybrid organic–inorganic perovskite solar cells have emerged as one of the most exciting material platforms in the photovoltaic sector. This review describes the rapid progress that has been made in this area.
5,463 citations
TL;DR: In this paper, an organic halide salt phenethylammonium iodide (PEAI) was used on HC(NH2)2-CH3NH3 mixed perovskite films for surface defect passivation.
Abstract: In recent years, the power conversion efficiency of perovskite solar cells has increased to reach over 20%. Finding an effective means of defect passivation is thought to be a promising route for bringing further increases in the power conversion efficiency and the open-circuit voltage (VOC) of perovskite solar cells. Here, we report the use of an organic halide salt phenethylammonium iodide (PEAI) on HC(NH2)2–CH3NH3 mixed perovskite films for surface defect passivation. We find that PEAI can form on the perovskite surface and results in higher-efficiency cells by reducing the defects and suppressing non-radiative recombination. As a result, planar perovskite solar cells with a certificated efficiency of 23.32% (quasi-steady state) are obtained. In addition, a VOC as high as 1.18 V is achieved at the absorption threshold of 1.53 eV, which is 94.4% of the Shockley–Queisser limit VOC (1.25 V). Planar perovskite solar cells that have been passivated using the organic halide salt phenethylammonium iodide are shown to have suppressed non-radiative recombination and operate with a certified power conversion efficiency of 23.3%.
3,064 citations
TL;DR: A simple vacuum flash–assisted solution processing method is devised to obtain shiny, smooth, crystalline perovskite films of high electronic quality over large areas, which enables the realization of highly efficient large-area PSCs for practical deployment.
Abstract: Metal halide perovskite solar cells (PSCs) currently attract enormous research interest because of their high solar-to-electric power conversion efficiency (PCE) and low fabrication costs, but their practical development is hampered by difficulties in achieving high performance with large-size devices. We devised a simple vacuum flash-assisted solution processing method to obtain shiny, smooth, crystalline perovskite films of high electronic quality over large areas. This enabled us to fabricate solar cells with an aperture area exceeding 1 square centimeter, a maximum efficiency of 20.5%, and a certified PCE of 19.6%. By contrast, the best certified PCE to date is 15.6% for PSCs of similar size. We demonstrate that the reproducibility of the method is excellent and that the cells show virtually no hysteresis. Our approach enables the realization of highly efficient large-area PSCs for practical deployment.
1,586 citations