Journal ArticleDOI
Homogeneous catalytic transfer-hydrogenation of α, β-unsaturated carbonyl compounds by dichlorotris (triphenylphosphine) ruthenium (II)
Yoel Sasson,Jochanan Blum +1 more
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This article is published in Tetrahedron Letters.The article was published on 1971-01-01. It has received 80 citations till now. The article focuses on the topics: Dichlorotris(triphenylphosphine)ruthenium(II).read more
Citations
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Dehydrogenation as a substrate-activating strategy in homogeneous transition-metal catalysis.
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Mechanistic aspects of transition metal-catalyzed hydrogen transfer reactions.
TL;DR: In this tutorial review recent mechanistic studies on transition metal-catalyzed hydrogen transfer reactions are discussed and an important question is whether the substrate coordinates to the metal (inner-sphere hydrogen transfer) or if there is a direct concerted transfer of hydrogen from the metal to substrate (outer-spheres hydrogen transfer).
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Ruthenium-Catalyzed Reactions for Organic Synthesis.
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Aqueous-phase asymmetric transfer hydrogenation of ketones--a greener approach to chiral alcohols.
Xiao-Feng Wu,Jianliang Xiao +1 more
TL;DR: An account of the progress made on aqueous-phase transfer hydrogenation (TH) reactions, with a focus on ATH, is presented.
References
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Journal ArticleDOI
Homogeneous Hydrogenation and Hydroformylation using Ruthenium Complexes
TL;DR: This paper showed that the rhodium (I) complex, RhCl(PPh3)3, is an extremely efficient catalyst for homogeneous hydrogenation of olefines and acetylenes at 25°C and at < 1 atmosphere pressure in benzene solutions.
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Hydrogen transfer reaction from alcohols catalysed by rhodium carbonyl phosphine complexes
TL;DR: The hydrogen transfer from alcohols or alkoxides to olefins is catalysed by the RhCl 3 -tertiary phosphines system as discussed by the authors, and the change in the catalytic activity with the nature of the phosphines have been correlated with the ability of Rh 0 phosphine complexes to abstract hydrogen from alkoxide.
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Homogeneous Catalytic Isomerization of Allylbenzene and Phenylbutenes by Some Platinum‐Metal Oomplexes
J. Blum,Y. Pickholtz +1 more
TL;DR: In this article, the isomerization of Allylbenzene, p-allylanisole, 4-phenylbut-1-ene and trans-1phenyl-but-2-ene catalyzed by various ruthenium, rhodium and iridium complexes has been investigated.