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Journal ArticleDOI

Hybrid Nanorod-Polymer Solar Cells

Wendy U. Huynh, +2 more
- 29 Mar 2002 - 
- Vol. 295, Iss: 5564, pp 2425-2427
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TLDR
It is demonstrated that semiconductor nanorods can be used to fabricate readily processed and efficient hybrid solar cells together with polymers and Tuning the band gap by altering the nanorod radius enabled us to optimize the overlap between the absorption spectrum of the cell and the solar emission spectrum.
Abstract
We demonstrate that semiconductor nanorods can be used to fabricate readily processed and efficient hybrid solar cells together with polymers. By controlling nanorod length, we can change the distance on which electrons are transported directly through the thin film device. Tuning the band gap by altering the nanorod radius enabled us to optimize the overlap between the absorption spectrum of the cell and the solar emission spectrum. A photovoltaic device consisting of 7-nanometer by 60-nanometer CdSe nanorods and the conjugated polymer poly-3(hexylthiophene) was assembled from solution with an external quantum efficiency of over 54% and a monochromatic power conversion efficiency of 6.9% under 0.1 milliwatt per square centimeter illumination at 515 nanometers. Under Air Mass (A.M.) 1.5 Global solar conditions, we obtained a power conversion efficiency of 1.7%.

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Citations
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Book

Dye-sensitized Solar Cells

TL;DR: The dye-sensitized solar cells (DSC) as discussed by the authors provides a technically and economically credible alternative concept to present day p-n junction photovoltaic devices, where light is absorbed by a sensitizer, which is anchored to the surface of a wide band semiconductor.
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Electrospinning: A Fascinating Method for the Preparation of Ultrathin Fibers

TL;DR: Electrospinning is a highly versatile method to process solutions or melts, mainly of polymers, into continuous fibers with diameters ranging from a few micrometers to a few nanometers, applicable to virtually every soluble or fusible polymer.
References
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Journal ArticleDOI

A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films

TL;DR: In this article, the authors describe a photovoltaic cell, created from low-to medium-purity materials through low-cost processes, which exhibits a commercially realistic energy-conversion efficiency.
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Semiconductor Clusters, Nanocrystals, and Quantum Dots

TL;DR: In this article, the authors focus on the properties of quantum dots and their ability to join the dots into complex assemblies creates many opportunities for scientific discovery, such as the ability of joining the dots to complex assemblies.
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Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
Journal ArticleDOI

Shape control of CdSe nanocrystals

TL;DR: Control of the growth kinetics of the II–VI semiconductor cadmium selenide can be used to vary the shapes of the resulting particles from a nearly spherical morphology to a rod-like one, with aspect ratios as large as ten to one.
Journal ArticleDOI

Formation of high-quality CdTe, CdSe, and CdS nanocrystals using CdO as precursor.

TL;DR: This paper proves that Cd(CH3)2 can be replaced by CdO and develops a one-pot synthesis which does not require separated preparation of cadmium complex and is reproducible and simple and thus can be readily scaled up for industrial production.
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