Journal ArticleDOI
Hydrogen Transfer from Organic Compounds Catalysed by Transition Metal Complexes
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In this paper, a review deals with the new rapidly developing field of homogeneous catalysis and coordination chemistry, namely with reactions involving hydrogen transfer from organic compounds to transition metal complexes accompanied by the dissociation of a C-H bond and the formation of a metal-hydrogen bond.Abstract:
The review deals with the new rapidly developing field of homogeneous catalysis and coordination chemistry, namely with reactions involving hydrogen transfer from organic compounds to transition metal complexes accompanied by the dissociation of a C–H bond and the formation of a metal–hydrogen bond. Particular attention has been devoted to catalytic reactions in which transition metal compounds serve as catalysts of hydrogen transfer and of the reduction of organic compounds by the C–H bonds of other organic molecules. The bibliography includes 177 references.read more
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Journal ArticleDOI
Kinetic coupling and hydrogen surface fugacities in heterogeneous catalysis: I. Alkane reactions on Te/NaX, H-ZSM5, and Ga/H-ZSM5
TL;DR: In this article, the authors proposed that rate-limiting hydrogen desorption steps, and the high surface hydrogen fugacities that result, control the rate and selectivity of dehydrogenation and related reactions on many nonmetal surfaces.
Journal ArticleDOI
Funktionelle Trimethylphosphinderivate, II. Ambivalentes Verhalten von Tetrakis(trimethylphosphin)eisen : Das Isomerengleichgewicht
TL;DR: In this paper, the reduction of FeCl2 in THF in the presence of excess trimethylphosphine (L) leads to a compound of the composition L4Fe (1).
Book ChapterDOI
Hydrogenation Reactions Catalyzed by Transition Metal Complexes
TL;DR: In this paper, the authors focus on the hydrogenation reactions catalyzed by transition metal complexes, with the aim of developing catalysts for selective hydrogenation under mild conditions, and demonstrate the degree of understanding that can be attained for a homogeneous hydrogenation catalyst at the molecular level.
Journal ArticleDOI
Asymmetric homogeneous catalysis by ruthenium complexes
Journal ArticleDOI
Transfer of hydrogen from alcohols to ketones catalyzed by iridium complexes with 2,2′-bipyridine, 1,10-phenanthroline, and their derivatives
TL;DR: In this article, the dependence of the rate and the stereoselectivity on the complex, the concentrations of the water and KOH is studied in detail, and a reaction mechanism is proposed.
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