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Open AccessJournal ArticleDOI

Influence of polyvinylpyrrolidone on optical, electrical, and dielectric properties of poly(2-ethyl-2-oxazoline)-polyvinylpyrrolidone blends

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TLDR
In this article, a poly(2-ethyl-2-oxazoline) is blended with polyvinylpyrrolidone (PVP) to improve the optical and electrical properties of the material.
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This article is published in Journal of Molecular Liquids.The article was published on 2017-12-01 and is currently open access. It has received 25 citations till now. The article focuses on the topics: Dielectric & Dielectric loss.

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Book ChapterDOI

Introduction to Spectroscopy

TL;DR: In this article, the electromagnetic spectrum in Figure 1 illustrates the many different types of electromagnetic radiation, including gamma rays (γ-rays), X-rays, ultraviolet (UV) radiation, visible light, infrared (IR), microwaves, and radio waves.
Journal ArticleDOI

Overall Investigation of Poly (Phenylene Sulfide) from Synthesis and Process to Applications—A Review

TL;DR: In this paper, the authors provide an overall investigation of PPS polymer and PPS-based composites from synthesis and process to applications, focusing on the aspect of thermal behavior and mechanical properties.
Journal ArticleDOI

Chitosan/poly(2-ethyl-2-oxazoline) films for ocular drug delivery: Formulation, miscibility, in vitro and in vivo studies

TL;DR: These films were formulated with sodium fluorescein as a model drug and were evaluated for their potential application in ocular drug delivery both in vitro and in vivo; it was established that the films are biocompatible and mucoadhesive.
Journal ArticleDOI

Design of Polymer Blends Based on Chitosan:POZ with Improved Dielectric Constant for Application in Polymer Electrolytes and Flexible Electronics

Abstract: There is a considerable demand for the development and application of polymer materials in the flexible electronic- and polymer-based electrolyte technologies. Chitosan (CS) and poly(2-ethyl-2-oxazoline) (POZ) materials were blended with different ratios to obtain CS:POZ blend films using a straightforward solution cast technique. The work was involved a range of characteristic techniques, such as impedance spectroscopy, X-ray diffraction (XRD), and optical microscopy. From the XRD spectra, an enhancement in the amorphous nature in CS:POZ blend films was revealed when compared to the pure state of CS. The enhancement was verified from the peak broadening in CS:POZ blend films in relative to the one in crystalline peaks of the CS polymer. The optical micrograph study was used to designate the amorphous and crystalline regions by assigning dark and brilliant phases, respectively. Upon increasing POZ concentration, the dielectric constant was found to increase up to ɛ′ = 6.48 (at 1 MHz) at 15 wt.% of POZ, and then a drop was observed beyond this amount. The relatively high dielectric constant and dielectric loss were found at elevated temperatures. The increase of POZ concentration up to 45 wt.% made the loss tangent to shift to the lower frequency side, which is related to increasing resistivity. The increases of dielectric constant and dielectric loss with temperature were attributed to the increase of polarisation. The loss tangent peaks were found to shift to the higher frequency side as temperature elevated. Obvious relaxation peaks were observed in the imaginary part of electric modulus, and no peaks were found in the dielectric loss spectra. The concentration dependent of M″ peaks was found to follow the same trend of loss tangent peaks versus POZ content. The relaxation process was studied in terms of electric modulus parameters.
Journal ArticleDOI

Co-precipitation of anthocyanins of the extract obtained from blackberry residues by pressurized antisolvent process

TL;DR: In this article, an ethanolic anthocyanin-rich extract was obtained from blackberry residues through ultrasound assisted extraction, and extracts were co-precipitated with the biodegradable polymer polyvinylpyrrolidone (PVP) through the supercritical antisolvent process (SAS), using carbon dioxide as antisolent.
References
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Book

Electronic processes in non-crystalline materials

TL;DR: The Fermi Glass and the Anderson Transition as discussed by the authorsermi glass and Anderson transition have been studied in the context of non-crystalline Semiconductors, such as tetrahedrally-bonded semiconductors.
Journal ArticleDOI

Optical Properties and Electronic Structure of Amorphous Germanium

TL;DR: In this article, the optical constants of amorphous Ge were determined for the photon energies from 0.08 to 1.6 eV, and the absorption is due to k-conserving transitions of holes between the valence bands as in p-type crystals.
BookDOI

Amorphous and liquid semiconductors

Jan Tauc
TL;DR: In this article, the nature of the amorphous state and the electronic properties of the Amorphous Semi-conductors have been investigated in the context of liquid semiconductors.
Book

Introduction to Spectroscopy

TL;DR: In this paper, the authors present an overview of the basic concepts of one-dimensional NMR, including spin spin-spin coupling, spin-spin coupling, Heteronuclear coupling with other nuclei, and 13C coupling constants.
Related Papers (5)
Frequently Asked Questions (16)
Q1. What are the contributions in this paper?

In this paper, the optical energy band gap and the width of the band tail of localized states in the forbidden band gap were measured at frequencies from 10 Hz to 8 MHz using an LCR meter. 

Hydrogen bonding and dipole-dipole interactions are the main causes for a good polymer-polymer miscibility and compatibility [6–9]. 

The electronic and ionic polarizations are more effective at higher frequencies which are responsible for the lower dielectric losses. 

The conductivity of the polymer blend depends on the concentration of filler polymer, the tendency of the filler polymer to aggregate, and the morphology of the matrix polymer. 

The ultraviolet-visible (UV-Vis) spectroscopy was utilised to evaluate various optical properties of blends such as absorption band edge, optical energy band gap, and Urbach energy. 

bio-degradable and bio-compatible polymer blends have pharmaceutical applications, especially in transdermal drug delivery system (TDDS) [18,19]. 

Aggregation of PVP in blends with higher PVP content (i.e. 40, 60, and 80 wt%) resists the absorption of incident light, and will result in less absorption. 

The high DC in the blend with 20 wt% PVP is due to the formation of a conducting path which made it easier for the electrical charge to hop through. 

Polymer blends have attracted substantial attention due to their technological importance for a variety of applications such as materials for fuel cells, electrostatic charge dissipation, embedded capacitors, electrochemical sensors, and in photonics, electronics and biotechnology [13–15]. 

According to Maxwell-Wagner-Sillar interfacial model, the interfaces between PEOX and PVP segments acts as potential barrier, and the charge carriers in the segment behaves like charges in a potential well. 

The higher values of tan are due to the increase in the number of self-associated bonds formed by the intermolecular interaction. 

Theeffective interaction between –CH3 groups of PEOX and carbonyl groups of PVP reduces the cohesive forces between the macromolecular PEOX and PVP polymer chains, which improveAC CEP TED MAN USC RIP Tthe segmental mobility in the blend. 

Twhen the PVP is added at larger concentration to the PEOX matrix, and also, due to fewer free electrons available for conduction process. 

Taking the natural logarithm on both sides of equation (3),0ln ln hE (4)The value of E can be obtained from the slope of linear portion in a graph of ln versus h. 

The relative permittivity, *, of a material is a complex quantity:* j (5)where ' is the dielectric constant (i.e. real part of *), and '' is the dielectric energy loss (i.e.imaginary part of *). 

The optical and electrical properties of polymer blends are very important in addition to their mechanical and thermal properties.