Influence of supplementary cementitious materials on the sustainability parameters of cements and concretes in the Indian context
TL;DR: In this paper, the authors proposed a framework for sustainability assessment, in terms of the CO2 emissions and energy demand, that can be adopted in cases where suitable databases are not readily available.
Abstract: The consumption of cement in India and other emerging economies is expected to increase because of the continuing push towards development of housing and infrastructure. The increasing production of cement and utilization of concrete are bound to have a major impact on sustainability. The present work proposes a framework for sustainability assessment, in terms of the CO2 emissions and energy demand, that can be adopted in cases where suitable databases are not readily available. Case studies for cement manufacture have been considered in South India, with different system boundaries such as ground-to-gate, gate-to-gate and CSI. The assessment made using data from the plant and other sources highlights the benefits of using supplementary cementitious materials (SCMs) in terms of reducing the impact of cement and concrete. More importantly, limestone calcined clay cement shows considerable promise in terms of reduction in CO2 emissions and energy demand in both cement and concrete, with more improvement in higher grade concrete.
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TL;DR: In this article, the authors presented data on the chloride diffusion coefficient (Dcl), ageing coefficient (m) and chloride threshold (Clth) related to seven concrete mixes (four M35 and three M50) with OPC, OPC+PFA (pulverised fuel ash) and limestone-calcined clay cement (LC3).
Abstract: This paper presents data on the chloride diffusion coefficient (Dcl), ageing coefficient (m) and chloride threshold (Clth) related to seven concrete mixes (four M35 and three M50) with OPC, OPC + PFA (pulverised fuel ash) and limestone-calcined clay cement (LC3). Using these, the service lives of a typical bridge pier and girder with the PFA and LC3 concrete were found to be much higher than those with OPC concrete of similar strength. From life-cycle assessment, the CO2 footprint of PFA and LC3 concrete were found to be significantly lower than those of OPC concrete of similar strength. Further, the CO2 emissions per unit of concrete per year of estimated service life, as a combined indicator of service life and carbon footprint, are similar for concrete with PFA and LC3, which are much lower than that with OPC.
120 citations
TL;DR: A review of the literature available on the subject of the recently developed limestone calcined clay cement (LC3) can be found in this article, where an introduction to the background leading to the development of LC3 is discussed.
Abstract: This article reviews the rapidly developing state-of-the-art literature available on the subject of the recently developed limestone calcined clay cement (LC3). An introduction to the background leading to the development of LC3 is first discussed. The chemistry of LC3 hydration and its production are detailed. The influence of the properties of the raw materials and production conditions are discussed. The mixture design of concrete using LC3 and the mechanical and durability properties of LC3 cement and concrete are then compared with other cements. At the end the economic and environmental aspects of the production and use of LC3 are discussed. The paper ends with suggestions on subjects on which further research is required.
114 citations
TL;DR: In this article, a review summarises literature to examine the transition from portland limestone cement system to composite ternary binder systems involving limestone and the interaction of fine limestone is classified and elaborated under two broad umbrellas: physical and chemical interactions.
Abstract: The review summarises literature to examine the transition from portland limestone cement system to composite ternary binder systems involving limestone. Interest in limestone addition as an ideal component in multicomponent binder systems has surged as evident from the large volume of literature published in the recent past. A ternary blended system, with co-substitution of limestone, has the potential to complement the reaction of the supplementary cementitious materials (SCMs). The direct addition of limestone powder helps to attain higher substitution levels of portland cement clinker, improve early age properties, and supplement SCM's reactivity. However, the dilution of hydrates could hamper the long-term benefits. In this review, the interaction of fine limestone is classified and elaborated under two broad umbrellas: physical and chemical interactions. The physical interactions can manifest in three ways, namely, filler action, shearing action and improved packing, which alters reaction rate and extent at early ages. The chemical interactions also modify the reaction kinetics and phase assemblage due to nucleation of C-S-H on calcite surfaces, preservation of the ettringite phase and formation of carboaluminates. Two different forms of carboaluminate hydrates — hemicarboaluminate and mono-carboaluminate can be present in the hydrate matrix depending on the balance between carbonate ions and aluminates in the pore solution. Several factors such as replacement level, particle size, choice of SCM, its reactivity and reactive aluminates content, sulphate levels, curing temperature, and duration of curing can control the carboaluminate formation, reaction degree of SCMs and chemical interaction from limestone additions. A combination of physical and chemical effects makes fine limestone a potential material for co-substitution with aluminosilicate based SCMs, mainly fly ash, slag, and calcined clay. In this review, the factors affecting limestone-SCM composites are summarised based on a detailed literature survey. The effects of SCM-limestone cement composites on hydration kinetics, reaction chemistry, the reactivity of SCMs, the stability of hydrated phases, and contribution to the physical structure development and macroscopic properties by evaluating hydration and mechanical properties are discussed. The importance of AFm (Al2O3–Fe2O3-mono) phases in various deterioration mechanisms in concrete and their influence on performance characteristics in different exposure environment is critically appraised.
95 citations
TL;DR: In this article, a prospective approach to conduct sustainability assessment based on the life cycle of 3D printed structures is presented, which also highlights the importance of considering the functional requirements of the mixes used for 3D printing.
Abstract: This paper explores the sustainability aspects of binders used in concrete 3D concrete printing. Firstly, a prospective approach to conduct sustainability-assessment based on the life cycle of 3D printed structures is presented, which also highlights the importance of considering the functional requirements of the mixes used for 3D printing. The potential of the material production phase is emphasized to enhance the sustainability potential of 3DCP by reducing the embodied impacts. The literature on the different binder systems used for producing 3D printable mixtures is reviewed. This review includes binders based on portland cement and supplementary cementing materials (SCMs) such as fly ash, silica-fume and slag. Also, alternative binders such as geopolymer, calcium sulfo-aluminate cement (CSA), limestone calcined clay cement (LC3) and reactive magnesium oxide systems are explored. Finally, sustainability assessment by quantifying the environmental impacts in terms of energy consumed and CO2 emissions of mixtures is illustrated with different binder systems. This paper underlines the effect of using SCMs and alternative binder systems for improving the sustainability of 3D printed structures.
78 citations
TL;DR: In this article, the role of microstructure in terms of the chemical composition of C-A-S-H and its physical states in the different systems is identified as the critical factor governing the development of micro-structure.
Abstract: This paper discusses the role of physical structure alterations on three binder types: plain portland cement, fly ash-based binder and calcined clay-limestone binder. The kinetics of physical structure development and the relevance in transport properties were distinguished using an interlinked parameter in concrete and paste. A systematic experimental investigation was carried out on a range of critical parameters such as strength development, resistivity development, transport characteristics and the time-dependent change in transport parameter. The role of microstructure in terms of the chemical composition of C-A-S-H and its physical states in the different systems is identified as the critical factor governing the development of microstructure. Chloride resistance was assessed by chloride migration experiments for a period of 4 years. The durability behaviours of the concrete with various binder were generalised using pore network parameters such as formation factor and tortuosity. A sensitivity analysis was used to dissect the contribution of the pore solution dilution and pore connectivity to the change in the pore network parameter. Based on the rise in macroscopic physical characteristics (i.e., formation factor here), a two-fold structure development mechanism to conceptualise microstructural evolution in cement composites is presented. Initially, capillary pore space reduces to a critical size range (i.e., 10–30 nm), which is followed by the densification of the physical state of the microstructure. At the point of densification, the pores become largely disconnected which leads to a dramatic increase in the formation factor. The binding matrix in calcined clay concretes reaches the critical pore size at an early age which leads to early densification of capillary pore space region in comparison to fly ash concretes.
75 citations
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5,509 citations
TL;DR: In this article, the authors present the results of comprehensive carbon footprint estimates for both geopolymer and OPC concrete, including energy expending activities associated with mining and transport of raw materials, manufacturing and concrete construction.
Abstract: Concrete for construction has traditionally been based on an Ordinary Portland Cement (OPC) binder. Geopolymers, an alternative binder based on fly ash (a fine waste collected from the emissions liberated by coal burning power stations) that is activated by an alkaline activator, have potential to lower the significant carbon footprint of OPC concrete. This paper presents the results of comprehensive carbon footprint estimates for both geopolymer and OPC concrete, including energy expending activities associated with mining and transport of raw materials, manufacturing and concrete construction. Previous studies have shown a wide variation of reported emission estimates: the results of this study are benchmarked with data from those studies.
1,274 citations
TL;DR: The main conclusions of an analysis of low-CO2, eco-efficient cement-based materials, carried out by a multi-stakeholder working group initiated by the United Nations Environment Program Sustainable Building and Climate Initiative (UNEP-SBCI) are presented, based on the white papers published in this special issue as discussed by the authors.
Abstract: The main conclusions of an analysis of low-CO2, eco-efficient cement-based materials, carried out by a multi-stakeholder working group initiated by the United Nations Environment Program Sustainable Building and Climate Initiative (UNEP-SBCI) are presented, based on the white papers published in this special issue. We believe that Portland-based cement approaches will dominate in the near future due to economies of scale, levels of process optimisation, availability of raw materials and market confidence. Two product-based approaches can deliver substantial additional reductions in their global CO2 emissions, reducing the need for costly investment in carbon capture and storage (CCS) over the next 20–30 years: 1. Increased use of low-CO2 supplements (SCMs) as partial replacements for Portland cement clinker. 2. More efficient use of Portland cement clinker in mortars and concretes. However, other emerging technologies could also play an important role in emissions mitigation in the longer term, and thus merit further investigation.
1,268 citations
TL;DR: In this article, the authors present a new analysis of global process emissions from cement production and show that global process CO2 emissions in 2016 were 1.45±0.20 metric tonne CO2, equivalent to about 4% of emissions from fossil fuels.
Abstract: . The global production of cement has grown very rapidly in recent years, and after fossil fuels and land-use change, it is the third-largest source of anthropogenic emissions of carbon dioxide. The required data for estimating emissions from global cement production are poor, and it has been recognised that some global estimates are significantly inflated. Here we assemble a large variety of available datasets and prioritise official data and emission factors, including estimates submitted to the UNFCCC plus new estimates for China and India, to present a new analysis of global process emissions from cement production. We show that global process emissions in 2016 were 1.45±0.20 Gt CO2, equivalent to about 4 % of emissions from fossil fuels. Cumulative emissions from 1928 to 2016 were 39.3±2.4 Gt CO2, 66 % of which have occurred since 1990. Emissions in 2015 were 30 % lower than those recently reported by the Global Carbon Project. The data associated with this article can be found at https://doi.org/10.5281/zenodo.831455 .
811 citations
01 May 2008
TL;DR: In this article, the authors describe the development of an open-access, reliable database for embodied energy and carbon (dioxide) emissions associated with the construction industry, which is made publicly available via an online website and has attracted significant interest from industry, academia, government departments and agencies.
Abstract: The development of an open-access, reliable database for embodied energy and carbon (dioxide) emissions associated with the construction industry is described. The University of Bath's inventory of carbon and energy database lists almost 200 different materials. The data were extracted from peer-reviewed literature on the basis of a defined methodology and a set of five criteria. The database was made publicly available via an online website and has attracted significant interest from industry, academia, government departments and agencies, among others. Feedback from such professional users has played an important part in the choice of ‘best values’ for ‘cradleto-site’ embodied energy and carbon from the range found in the literature. The variation in published data stems from differences in boundary definitions (including geographic origin), age of the data sources and rigour of the original life-cycle assessments. Although principally directed towards UK construction, the material set included in the d...
789 citations