Influence of thermal processing conditions in 3D printing on the crystallinity and mechanical properties of PEEK material
TL;DR: In this article, a temperature control 3D printing system was used to calculate the crystallinity and mechanical properties of polyether-ether-ketone (PEEK) material and perform tension tests.
About: This article is published in Journal of Materials Processing Technology.The article was published on 2017-10-01. It has received 377 citations till now. The article focuses on the topics: Peek & Crystallinity.
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300 citations
TL;DR: In this article, the effect of build orientation, layer thickness and fiber volume content on the impact performance of 3D printed continuous carbon, glass, and Kevlar® fiber reinforced nylon composites, manufactured by FDM technique, was evaluated.
Abstract: Fused deposition modelling (FDM) is a promising additive manufacturing technology and an alternative of conventional processes for the fabrication of fibre reinforced composites due to its ability to build functional parts having complex geometries. Continuous fibre reinforced thermoplastic composites (CFRTPCs) are becoming more significant in industrial applications due to their inherit advantages such as excellent mechanical performance, recycling and potential lightweight structures [1,2]. However, a major concern affecting the efficient use of 3D printed composites is the effect of impact damage on the structural integrity, compared to conventional pre-preg composites. The aim of this study is to evaluate the effect of build orientation, layer thickness and fibre volume content on the impact performance of 3D printed continuous carbon, glass, and Kevlar® fibre reinforced nylon composites, manufactured by FDM technique. Charpy impact tests are carried out to determine impact strength. SEM images of fractured surfaces are examined to assess failure mechanics of the different configurations. It is observed that the effect of layer thickness of nylon samples on the impact performance was different for flat and on-edge samples. Impact strength increases as layer thickness increases in flat samples but, conversely, it decreases in on-edge samples, depicting a more brittle fracture. In addition, the results show that impact strength increases as fibre volume content increases in most cases. Glass fibre reinforced samples exhibits the highest impact strength and carbon fibre reinforced samples the lowest one and similar to nylon performance. Furthermore, on-edge reinforced samples exhibit higher values of impact strength than flat reinforced samples. Finally, the results obtained demonstrate that impact strength exhibited by 3D printed composites are significantly higher than the usual 3D printed thermoplastics and, in some cases, even better than common pre-preg materials.
270 citations
TL;DR: In this article, the effect of layer thickness and fibre volume content on the interlaminar bonding performance of 3D printed continuous carbon, glass and Kevlar® fibre reinforced nylon composites manufactured by FDM technique was evaluated.
242 citations
TL;DR: In this article, the challenges involved in the preparation of composite feedstock filaments and printing issues during the printing of nano composites, short and continuous fiber composites are discussed, and detailed explanation is given about the analytical and numerical models used for simulating the FDM printing process and for estimating the mechanical properties of the printed parts.
Abstract: Fused Deposition Modeling (FDM) is a widely used additive manufacturing technology for fabrication of complex geometric parts using thermoplastic polymers. The quality issues and inferior properties of fabricated parts limited this process to manufacture parts for industrial level applications. Reinforcing the polymer with nanoparticles, short fibers or continuous fibers improve mechanical, thermal and electrical properties compared to the neat polymer. Several works have been carried out since last two decades to print quality products through FDM by using composite materials. The success of expanding this technique to industrial applications depends on the preparation of printable composite feedstock filament and printing without defects. This article reviews the challenges involved in the preparation of composite feedstock filaments and printing issues during the printing of nano composites, short and continuous fiber composites. The printing process of various thermoplastic composites ranging from amorphous to crystalline polymers is discussed. Also, detailed explanation is given about the analytical and numerical models used for simulating the FDM printing process and for estimating the mechanical properties of the printed parts. This critical review mainly helps the young researchers working in the area of processing of composite materials via 3D printing.
241 citations
TL;DR: In this article, a finite element analysis (FEA) was used to simulate the melting conditions and fluidity of PEEK in a flow channel, in order to determine the parameters required to 3D print PEEK parts with sufficient surface quality and improved mechanical properties.
204 citations
References
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01 Jan 2007
TL;DR: Theoretical models and simulations of polymers have been used to study the molecular dynamics of different molecular architectures and properties of polymeric networks and gels as discussed by the authors, including the properties of different types of networks.
Abstract: Preface to the Second Edition. -Preface to the First Edition. -STRUCTURE. -Chain Structures. -Names, Acronyms, Classes, and Structures of Some Important Polymers. -THEORY. -The Rotational Isomeric State Model. -Computational Parameters. -Theoretical Models and Simulations of Polymer Chains. -Scaling, Exponents, and Fractal Dimensions. -THERMODYNAMIC PROPERTIES. -Densities, Coefficients of Thermal Expansion, and Compressibilities of Amorphous Polymers. -Thermodynamic Properties of Proteins. -Heat Capacities of Polymers. -Thermal Conductivity. -Thermodynamic Quantities Governing Melting. -The Glass Temperature. -Sub-Tg Transitions. -Polymer-Solvent Interaction Parameter c. -Theta Temperatures. -Solubility Parameters. -Mark-Houwink-Staudinger-Sakurada Constants. -Polymers and Supercritical Fluids. -Thermodynamics of Polymer Blends. -SPECTROSCOPY. -NMR Spectroscopy of Polymers. -Broadband Dielectric Spectroscopy to Study the Molecular Dynamics of Polymers Having Different Molecular Architectures. -Group Frequency Assignments for Major Infrared Bands Observed in Common Synthetic Polymers. -Small Angle Neutron and X-Ray Scattering. -MECHANICAL PROPERTIES. -Mechanical Properties. -Chain Dimensions and Entanglement Spacings. -Temperature Dependences of the Viscoelastic Response of Polymer Systems. -Adhesives. -Some Mechanical Properties of Typical Polymer-Based Composites. -Polymer Networks and Gels. -Force Spectroscopy of Polymers: Beyond Single Chain Mechanics. -REINFORCING PHASES. -Carbon Black. -Properties of Polymers Reinforced with Silica. -Physical Properties of Polymer/Clay Nanocomposites. -Polyhedral Oligomeric Silsesquioxane (POSS). -Carbon Nanotube Polymer Composites: Recent Developments in Mechanical Properties. -Reinforcement Theories. -CRYSTALLINITY AND MORPHOLOGY. -Densities of Amorphous and Crystalline Polymers. -Unit Cell Information on Some Important Polymers. -Crystallization Kinetics of Polymers. -Block Copolymer Melts. -Polymer Liquid Crystals and Their Blends. -The Emergence of a New Macromolecular Architecture: 'The Dendritic State'. -Polyrotaxanes. -Foldamers: Nanoscale Shape Control at the Interface Between Small Molecules and High Polymers. -Recent Advances in Supramolecular Polymers. -ELECTRO-OPTICAL AND MAGNETIC PROPERTIES. -Conducting Polymers: Electrical Conductivity. -Conjugated Polymer Electroluminescence. -Magnetic, Piezoelectric, Pyroelectric, and Ferroelectric Properties of Synthetic and Biological Polymers. -Nonlinear Optical Properties of Polymers. -Refractive Index, Stress-Optical Coefficient, and Optical Configuration Parameter of Polymers. -RESPONSES TO RADIATION, HEAT, AND CHEMICAL AGENTS. -Ultraviolet Radiation and Polymers. -The Effects of Electron Beam and g-Irradiation on Polymeric Materials. -Flammability. -Thermal-Oxidative Stability and Degradation of Polymers. -Synthetic Biodegradable Polymers for Medical Applications. -Biodegradability of Polymers. -Properties of Photoresist Polymers. -Pyrolyzability of Preceramic Polymers. -OTHER PROPERTIES. -Surface and Interfacial Properties. -Acoustic Properties. -Permeability of Polymers to Gases and Vapors. -MISCELLANEOUS. -Definitions. -Units and Conversion Factors. -Subject Index
2,230 citations
TL;DR: The morphology and related properties for the aromatic thermoplastic poly(aryl-ether-etherketone) (PEEK) [C6H4O C6H 4 O OC 6H4-CO]n were described in this article, including crystallinity, crystallization and melting behaviour, Iamellar thickness and spherulitic structure.
833 citations
TL;DR: In this paper, a systematic review of the literature related to dimensional accuracy and surface roughness for fused deposition modeling and similar extrusion-based additive manufacturing or rapid prototyping processes is presented.
Abstract: Purpose – The purpose of this paper is to critically review the literature related to dimensional accuracy and surface roughness for fused deposition modeling and similar extrusion-based additive manufacturing or rapid prototyping processes. Design/methodology/approach – A systematic review of the literature was carried out by focusing on the relationship between process and product design parameters and the dimensional and surface properties of finished parts. Methods for evaluating these performance parameters are also reviewed. Findings – Fused deposition modeling® and related processes are the most widely used polymer rapid prototyping processes. For many applications, resolution, dimensional accuracy and surface roughness are among the most important properties in final parts. The influence of feedstock properties and system design on dimensional accuracy and resolution is reviewed. Thermal warping and shrinkage are often major sources of dimensional error in finished parts. This phenomenon is explor...
555 citations
TL;DR: In this article, an Acrylonitrile butadiene styrene (ABS) nanocomposites with organic modified montmorillonite (OMMT) were prepared by melt intercalation and evaluated by tensile, flexural, thermal expansion and dynamic mechanical tests.
444 citations
TL;DR: In this paper, a low-cost 3D printing of polyetheretherketone (PEEK)-based medical devices using filament-based extrusion additive manufacturing (AM) process is reported.
Abstract: There has been a trend in recent years to develop polyetheretherketone (PEEK)-based medical devices due to the excellent cell biocompatibility and desirable mechanical properties of PEEK, which has elastic modulus comparable to cortical bone. Different manufacturing techniques such as injection moulding, particulate leaching, compression moulding, and selective laser sintering (SLS) have been used to produce porous PEEK for biomedical applications. Despite a large number of publications on extrusion-based additive manufacturing (AM) of porous structures using various materials, there have been very few general reports on extrusion AM of low quality small PEEK parts without defects such as warpage and delamination and no further assessment of mechanical properties. Successful low-cost 3D printing of PEEK structures using filament-based extrusion AM process is reported in this paper for the first time. Hot extrusion head design, extrusion temperature, and ambient temperature were identified as impor...
297 citations