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Integrated Ladinian bio-chronostratigraphy and geochrononology of Monte San Giorgio (Southern Alps, Switzerland)

15 May 2012-Swiss Journal of Geosciences (SP Birkhäuser Verlag Basel)-Vol. 105, Iss: 1, pp 85-108
TL;DR: In this article, a single-zircon U-Pb dating was performed using ID-TIMS and chemical abrasion (CA) pre-treatment technique on volcanic ash layers intercalated in the biostratigraphically defined intervals of the Meride Limestone.
Abstract: New biostratigraphic data significantly improve the age assignment of the Ladinian succession of Monte San Giorgio (UNESCO World Heritage List site, Southern Alps, Switzerland), whose world-famous fossil marine vertebrate faunas are now dated to the substage and zone levels. High-resolution single-zircon U–Pb dating was performed using ID-TIMS and chemical abrasion (CA) pre-treatment technique on volcanic ash layers intercalated in the biostratigraphically-defined intervals of the Meride Limestone. It yielded ages of 241.07 ± 0.13 Ma (Cava superiore beds, P. gredleri Zone), 240.63 ± 0.13 Ma (Cassina beds, P gredleri/P. archelaus transition Zone) and 239.51 ± 0.15 Ma (Lower Kalkschieferzone, P. archelaus Zone). Our results suggest that the time interval including the vertebrate-bearing Middle Triassic section spans around 4 Myr and is thus significantly shorter than so far assumed. The San Giorgio Dolomite and the Meride Limestone correlate with intervals of the Buchenstein Formation and the Wengen Formation in the reference section at Bagolino, where the Global boundary Stratotype Section and Point (GSSP) for the base of the Ladinian was defined. The new radio-isotopic ages of the Meride Limestone are up to 2 Myr older than those published for the biostratigraphically-equivalent intervals at Bagolino but they are consistent with the recent re-dating of the underlying Besano Formation, also performed using the CA technique. Average sedimentation rates at Monte San Giorgio are by more than an order of magnitude higher compared to those assumed for the Buchenstein Formation, which formed under sediment-starved pelagic conditions, and reflect prevailing high subsidence and high carbonate mud supply from the adjoining Salvatore/Esino platforms. Finally, the high-resolution U–Pb ages allow a correlation of the vertebrate faunas of the Cava superiore/Cava inferiore beds with the marine vertebrate record of the Prosanto Formation (Upper Austroalpine), so far precluded by the poor biostratigraphic control of the latter.

Summary (3 min read)

1 Introduction

  • The Middle Triassic succession of Monte San Giorgio (Southern Alps, Switzerland/Italy; Fig. 1) has been inscribed on the UNESCO World Heritage List because of its unique palaeontological value and it is, in particular, world-famous for the exceptionally well-preserved fossil fishes and marine reptiles.
  • By contrast, the scarce age-diagnostic fossils so far reported from the overlying San Giorgio Dolomite and Meride Limestone formations provide only an uncomplete biostratigraphic framework while reliable radio-isotopic ages are not available at all.
  • Conclusions on topics, which are crucial for this Lagerstätte, such as the assessment of evolutionary rates of its fossil vertebrate faunas, remain highly speculative.
  • The authors apply this technique, coupled with the annealing/chemical abrasion (CA) pre-treatment procedure of Mattinson (2005), to the Ladinian sequence of Monte San Giorgio, which, in addition, has been constrained by new biostratigraphic data.

2 Geological setting

  • The Monte San Giorgio belongs to the Southern Alps, a fold-and-thrust belt extending over an area of 500 km (east to west) by 50–150 km (north to south) and bounded by the Insubric/Periadriatic Lineament to the north and west.
  • While in the north and in the east shallow-water sedimentation continued, during the latest Anisian and Ladinian in the Monte San Giorgio area the formation of an intraplatform basin with restricted circulation resulted in the deposition of the Besano Formation, the San Giorgio Dolomite and the Meride Limestone (Bernasconi 1994; Furrer 1995, 2003).
  • The overlying Upper Meride Limestone is a sequence of alternating wellbedded limestones and marlstones, mainly representing dilute lime mud turbidites.
  • Whatever the origin of the Middle Triassic volcanic episode, due to their lateral persistence these tephra layers proved ideal markers for precise correlations of sections up to 200 km apart (Brack and Rieber 1993; Brack and Muttoni 2000; Brühwiler et al. 2007).

3 Biostratigraphy

  • The Besano Formation hosts a continuous macrofossil record (ammonoids and daonellid bivalves) ranging from the late Anisian (upper R. reitzi Amm. Zone) to the earliest Ladinian (lower E. curionii Amm. Zone) and represents a well-studied key section for the Anisian/Ladinian boundary.
  • The 0-m level in the stratigraphic column corresponds to Bed 85 of the Besano Formation (N. secedensis Amm. Zone) in the standard profile at locality Mirigioli (Site P. 902; Rieber 1973b).

3.2.1 Material and methods

  • In order to provide reliable biochronologic constraints to the new radio-isotopic dating, a more detailed biostratigraphic subdivision of the studied section has been attempted.
  • After 24 h, the muddy residue was separated, thoroughly wet sieved and dried.
  • Lower Meride Limestone, Cava superiore beds, Val Serrata.
  • Lower Meride Limestone, Val Porina b Radiolarians and selected sporomorphs were mounted on stubs and photographed with a Mira Tescan scanning electron microscope (SEM) at the Institut de Géologie et Paléontologie of the University of Lausanne (UNIL).

3.2.2 Results

  • Fieldwork yielded some new ammonoid and bivalve finds (Figs. 4, 5).
  • O Kyrtomisporis ervei Van der Eem 1983, sample Ca 13/14, Lower Meride Limestone. w Duplicisporites granulatus (Leschik, 1955) Van der Eem 1983, sample VM-D10, Lower Kalkschieferzone.
  • Assemblages have been defined by the first (FO) and last occurrence (LO) of marker taxa and by the distribution of the main groups, Ovalipollis in particular, throughout the section (Hochuli and Roghi 2002).

4 Geochronology

  • 1 Radio-isotopic ages from previous studies Among the earlier radio-isotopic age data of particular significance for the Triassic geochronology one must mention the K–Ar and 40Ar/39Ar ages of Hellmann and Lippolt (1981), determined on K-feldspars from upper Anisian bentonite beds of the Besano Formation of Monte San Giorgio.
  • At that time, these results represented the by far best documented tie between Triassic biostratigraphic and chronologic time scales.

4.2.1 Material and methods

  • Twenty-two U–Pb determinations have been made on zircons from three ash layers selected for radio-isotopic dating (Figs. 1a, 2, 4).
  • The sampled bed is the thickest bentonite horizon in the Monte San Giorgio section and the most reliable marker horizon of the Kalkschieferzone.
  • Zircon grains were extracted by standard mineral separation techniques.
  • All 206Pb/238U dates are calculated using the 238U and 235U decay constants of Jaffey et al. (1971) and corrected for initial U/Th disequilibrium using an assumed Th/U magma ratio of 4, typical for magmatic systems.

4.2.2 Results

  • Table 1 lists the 206Pb/238U dates and uncertainties for each of the individual zircon analyses while the results are summarised in Figs.
  • The remaining older zircon dates are excluded and interpreted as reflecting the reworking of older material in the magmatic environment.
  • The MSWD value is within the range of acceptable values for the given number of data points (Wendt and Carl 1991).

5 Discussion

  • 1 Comparison with other sections and bio/ chronostratigraphic correlation However, the new radio-isotopic ages for samples RS09/4, Ca31 and RS09/5a as well as the suggested correlation of the sections at Monte San Giorgio and Bagolino are consistent with the age trend indicated for Bagolino on the basis of new data (Fig. 10; see also Brack et al. 2007: fig. 11).
  • It also supports the correlation of the Kalkschieferzone with the upper part of the Cunardo Formation (western Varese Province, Italy; Fig. 1b), which, on the basis of ammonoid occurrences, has been ascribed to the P. archelaus Amm. Zone (Calabrese and Balini 1995).
  • The inferred sedimentation rates exceed by more than 20 times those reported from the Bagolino section (see above) or equivalent Buchenstein-type sections outside the Southern Alps (e.g. Brühwiler et al. 2007).
  • Since the latter fauna was U–Pb dated to an age of 240.91 ± 0.26 Ma (Furrer et al. 2008; ID–TIMS with CA pre-treatment technique), a time equivalence of this fauna with those from the Cava superiore/Cava inferiore beds is now inferred.

6 Conclusions

  • The newly defined biostratigraphic and geochronologic constraints for the Ladinian sequence of Monte San Giorgio allow to resolve to the zone level the age of the classic fossil-bearing horizons of the Meride Limestone, which are assigned to the P. gredleri Amm.
  • Bulk sedimentation rates exceeding 200 m/Myr are representative for the San Giorgio Dolomite and the Meride Limestone (at least up to the Lower Kalkschieferzone), mainly composed of reworked carbonate mud stirred up from the surrounding platforms.
  • The first author is indebted to Evelyn Kustatscher and David Bodman for the stimulating discussions about palynological aspects, to Paulian Dumitrica (IGP, UNI Lausanne) for the revision of the determination of the radiolarian specimens illustrated herein and especially to Daniel Bernoulli (UNI Basel) for comments on an earlier version of the manuscript.
  • This paper greatly benefited from constructive comments by Heinz Furrer and Urs Schaltegger (UNI Genève) and especially from a very careful review by Peter Brack (ETH Zürich) which greatly contributed to improve the manuscript.

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Integrated Ladinian bio-chronostratigraphy and geochrononology
of Monte San Giorgio (Southern Alps, Switzerland)
Rudolf Stockar
Peter O. Baumgartner
Daniel Condon
Received: 18 November 2011 / Accepted: 14 March 2012 / Published online: 15 May 2012
Ó Swiss Geological Society 2012
Abstract New biostratigraphic data significantly improve
the age assignment of the Ladinian succession of Monte
San Giorgio (UNESCO World Heritage List site, Southern
Alps, Switzerland), whose world-famous fossil marine
vertebrate faunas are now dated to the substage and zone
levels. High-resolution single-zircon U–Pb dating was
performed using ID-TIMS and chemical abrasion (CA)
pre-treatment technique on volcanic ash layers intercalated
in the biostratigraphically-defined intervals of the Meride
Limestone. It yielded ages of 241.07 ± 0.13 Ma (Cava
superiore beds, P. gredleri Zone), 240.63 ± 0.13 Ma
(Cassina beds, P gredleri/P. archelaus transition Zone) and
239.51 ± 0.15 Ma (Lower Kalkschieferzone, P. archelaus
Zone). Our results suggest that the time interval including
the vertebrate-bearing Middle Triassic section spans
around 4 Myr and is thus significantly shorter than so far
assumed. The San Giorgio Dolomite and the Meride
Limestone correlate with intervals of the Buchenstein
Formation and the Wengen Formation in the reference
section at Bagolino, where the Global boundary Stratotype
Section and Point (GSSP) for the base of the Ladinian was
defined. The new radio-isotopic ages of the Meride
Limestone are up to 2 Myr older than those published for
the biostratigraphically-equivalent intervals at Bagolino
but they are consistent with the recent re-dating of the
underlying Besano Formation, also performed using the
CA technique. Average sedimentation rates at Monte San
Giorgio are by more than an order of magnitude higher
compared to those assumed for the Buchenstein Formation,
which formed under sediment-starved pelagic conditions,
and reflect prevailing high subsidence and high carbonate
mud supply from the adjoining Salvatore/Esino platforms.
Finally, the high-resolution U–Pb ages allow a correlation
of the vertebrate faunas of the Cava superiore/Cava infe-
riore beds with the marine vertebrate record of the Prosanto
Formation (Upper Austroalpine), so far precluded by the
poor biostratigraphic control of the latter.
Keywords Ladinian Monte San Giorgio
Meride Limestone Buchenstein Formation
Biostratigraphy Geochronology U–Pb Ash bed
Zircon
Abbreviation
MCSN Museo cantonale di storia naturale, Lugano,
Switzerland
1 Introduction
The Middle Triassic succession of Monte San Giorgio
(Southern Alps, Switzerland/Italy; Fig. 1) has been inscri-
bed on the UNESCO World Heritage List because of its
unique palaeontological value and it is, in particular,
world-famous for the exceptionally well-preserved fossil
fishes and marine reptiles. Although this section is a rich
Editorial Handling: Daniel Marty.
R. Stockar (&) P. O. Baumgartner
Institut de Ge
´
ologie et Pale
´
ontologie, Universite
´
de Lausanne,
Anthropole, 1015 Lausanne, Switzerland
e-mail: rudolf.stockar@ti.ch
R. Stockar
Museo Cantonale di Storia Naturale, Viale Cattaneo 4,
6900 Lugano, Switzerland
D. Condon
NERC Isotope Geosciences Laboratory, British Geological
Survey, Nottingham NG12 5GG, England, UK
Swiss J Geosci (2012) 105:85–108
DOI 10.1007/s00015-012-0093-5

archive for the depositional environment of thanatocoe-
noses, which had (and still have) a major impact on the
Middle Triassic palaeontology, the lack of sufficiently
precise bio- and chronostratigraphic constraints still pre-
cludes a quantified assessment of both the basin and biota
evolution. A unique exception is the upper Anisian-low-
ermost Ladinian Besano Formation, which provided a
detailed age-diagnostic ammonoid and bivalve record and
also yielded high-resolution radio-isotopic age data (Brack
and Rieber 1993; Brack et al. 2005; Mundil et al. 2010). By
contrast, the scarce age-diagnostic fossils so far reported
from the overlying San Giorgio Dolomite and Meride
Limestone formations provide only an uncomplete bio-
stratigraphic framework while reliable radio-isotopic ages
are not available at all. Consequently, conclusions on
topics, which are crucial for this Lagersta
¨
tte, such as the
assessment of evolutionary rates of its fossil vertebrate
faunas, remain highly speculative.
U–Pb isotopic dating using isotope dilution thermal
ionization mass spectrometry (ID-TIMS) on single zircon
grains from volcaniclastic layers intercalated within fossil-
bearing marine sediments provides at present the best
means of directly cross-correlating biostratigraphic and
geochronologic data. We apply this technique, coupled
with the annealing/chemical abrasion (CA) pre-treatment
procedure of Mattinson (2005), to the Ladinian sequence of
Monte San Giorgio, which, in addition, has been con-
strained by new biostratigraphic data.
The main goals of this study are the following:
1. to re-define the biostratigraphic subdivisions of the
Ladinian sequence at Monte San Giorgio and to
correlate it with the reference section at Bagolino
(northern Italy), bearing the GSSP for the base of
Ladinian,
2. to resolve the age of the world-famous marine
vertebrate faunas of the Meride Limestone to the
substage and ammonoid zone level,
3. to correlate the fossil vertebrate faunas of the Meride
Limestone with analogous faunas from the Upper
Australpine realm which, although lacking a sufficient
biostratigraphic control, are well-constrained by high-
resolution radio-isotopic dating,
4. to assess the average sedimentation rates of the basinal
deposits composing the San Giorgio Dolomite and the
Meride Limestone,
5. to provide new high-resolution radio-isotopic ages for
the Ladinan Stage and to compare them with the
available geochronologic data.
2 Geological setting
The Monte San Giorgio belongs to the Southern Alps, a
fold-and-thrust belt extending over an area of 500 km (east
to west) by 50–150 km (north to south) and bounded by the
Lake Lugano
Lake Lugano
45°54' N
1 Km
1 0 Km
8°57' E
RS09/5a
Ca31
RS09/4
a
Porto Ceresio
Besano
Serpiano
Meride
Monte San Giorgio
a
b
Va
l Serrat
a
Va
l Porina
Val Mara
Fig. 1 a Simplified map of Monte San Giorgio showing the Middle Triassic carbonate succession and the location of the radio-isotopically dated
samples. b Location of the Middle Triassic sections mentioned in the text
86 R. Stockar et al.

Insubric/Periadriatic Lineament to the north and west. To
the east, the Southern Alps continue into the external
Dinarides, whereas, to the south, the front of the South-
Alpine wedge is buried below the post-orogenic deposits of
the Po Plain. In Middle Triassic times, the South-Alpine
domain was situated on a passive continental margin open
to the tropical western Neo-Tethys (e.g. Stampfli and Borel
2002), which was progressively submerged by a long-term
transgression from the east. The marine ingression reached
the eastern South-Alpine domain in the Late Permian and
the westernmost (i.e. west of Lake Como) South-Alpine
domain in late Anisian times. The palaeogeographic sce-
nario was complicated by intensive Middle Triassic
transtensive–transpressive tectonics, which resulted in a
structural compartmentalization consisting in repeatedly
uplifted and subsiding blocks. The geodynamic signifi-
cance of these events is still debated and as puzzling as the
character of the time-equivalent magmatism (see further
below). However, even if unquestionably affecting the
crustal structure of the Southern Alps, this tectonic activity
does not seem to be related to the Late Triassic–Early
Jurassic rifting of the Alpine Tethys and the opening of the
Ligurian Ocean (Bertotti et al. 1993). The increasing dif-
ferentiation of depositional environments occurring from
late Anisian times onwards resulted in the development of
a rapidly changing pattern of carbonate platforms, locally
anoxic intraplatform basins and open-marine pelagic
basins (Brack and Rieber 1993). Close to the base of the
E. curionii Amm. Zone (earliest Ladinian), water depths
reached maximum values (around 800 m) in the Dolomites
(eastern Southern Alps), while they were likely shallower
towards the western Southern Alps (Brack and Rieber
1993; Brack et al. 2005).
2.1 The Middle Triassic sequence of Monte San
Giorgio
The Monte San Giorgio basin is located at the western
termination of the South-Alpine domain described above.
This unique ‘remote’ location resulted in a peculiar
sedimentary succession and in at least temporarily severe
dysoxic to anoxic bottom water conditions (Kuhn-Schnyder
and Vonderschmitt 1954; Zorn 1971; Rieber 1973a;
Bernasconi 1994; Furrer 1995, 2003;Ro
¨
hl et al. 2001; Etter
2002; Stockar 2010). The Middle Triassic succession at
Monte San Giorgio (Fig. 2) starts with fluvio-deltaic
deposits dated to the late Anisian (Bellano Formation,
Illyrian; Sommaruga et al. 1997), unconformably overlying
a Lower Permian volcanic basement. The upper Anisian
sediments testify to the progressive transgression of a
shallow sea from the east and to the initiation of carbonate
platform growth (Salvatore Dolomite/Esino Limestone;
Zorn 1971) north of a land area buried today below the Po
plain (Picotti et al. 2007). Dolomitized microbial lime-
stones, characterized by stromatolitic lamination, were
deposited in a shallow subtidal to intertidal environment
(Lower Salvatore Dolomite). While in the north and in the
east shallow-water sedimentation continued, during the
latest Anisian and Ladinian in the Monte San Giorgio area
the formation of an intraplatform basin with restricted
circulation resulted in the deposition of the Besano For-
mation, the San Giorgio Dolomite and the Meride
Limestone (Bernasconi 1994; Furrer 1995, 2003). The
Besano Formation (‘‘Grenzbitumenzone’’; Frauenfelder
1916) directly overlies the Lower Salvatore Dolomite and
is composed of a 16 m thick alternation of black shales and
laminated dolostones. Its uppermost part includes the
Anisian/Ladinian boundary (=base of the E. curionii Amm.
Zone; Brack and Rieber 1993; Brack et al. 2005). Most of
the spectacular vertebrate fossils (reptiles and fishes)
together with important index fossils including ammonoids
and daonellid bivalves come from this formation (e.g.
Rieber 1969, 1973b; Kuhn-Schnyder 1974;Bu
¨
rgin et al.
1989). The Besano Formation grades upwards into the San
Giorgio Dolomite and the Meride Limestone, all together
constituting an around 600 m thick sequence.
Fig. 2 Stratigraphic section of the Middle Triassic sediments in the
Monte San Giorgio area with the main vertebrate-bearing levels
(modified and updated from Furrer 1995). Radio-isotopically dated
volcanic ash layers are indicated. RS09/4, RS09/5a and Ca31: this
paper. MSG.09: Mundil et al. (1996, 2010)
Ladinian of Monte San Giorgio 87

The base of the San Giorgio Dolomite is defined at layer
187 of the standard profile at locality Mirigioli (Site P. 902;
Rieber 1973b; Bernasconi 1994) where the Besano For-
mation was excavated bed by bed between 1950 and 1968
and yielded exceptional vertebrate fossils (Kuhn-Schnyder
1974). The section is no longer accessible, but thickness
and lithofacies are laterally consistent enough to allow a
reliable correlation of single beds at different localities of
the Monte San Giorgio area. The transition from the
Besano Formation to the San Giorgio Dolomite is marked
by the disappearance of black shales, by a reduction of
laminated dolostones and by a major decrease in the
organic matter content (Bernasconi 1994). Sections in Val
Porina and Val Serrata (Fig. 1a) show that the San Giorgio
Dolomite results from early and late diagenetic dolomiti-
zation, the latter cutting across stratification and affecting
the original limestones in an irregular pattern up to a major
volcaniclastic bed (‘‘Val Serrata tuff’’) lying around 165 m
above the base of this unit (Fig. 2).
The Lower Meride Limestone chiefly consists of well-
bedded limestones. Most of the carbonate was likely derived
from the adjacent highly productive Salvatore/Esino car-
bonate platforms providing a constant supply of carbonate
mud to the basin. Three intervals (Cava inferiore beds, Cava
superiore beds and Cassina beds), mainly consisting of
finely laminated limestones with intercalated volcanic ash
layers, are present in the upper part of the Lower Meride
Limestone and yielded different vertebrate fossil assem-
blages (Peyer 1931; Sander 1989; Furrer 1995, 2003;
Stockar 2010). The top of the Lower Meride Limestone is
defined by a very irregular discontinuous dolomite horizon
(‘‘Dolomitband’’; Frauenfelder 1916), averaging around
30 m in thickness (Wirz 1945; Furrer 1995). The overlying
Upper Meride Limestone is a sequence of alternating well-
bedded limestones and marlstones, mainly representing
dilute lime mud turbidites. The uppermost part comprises
the 120 m thick ‘Kalkschieferzone’ (Senn 1924), made up
of thin-bedded, mostly laminated, limestones and marl-
stones with peculiar faunas of fishes, reptiles, crustaceans
and insects. It represents the latest stage of the intra-plat-
form basin, recording strong seasonal variations of salinity
and water level, which was progressively buried by an
increasing input of siliciclastic material (Furrer 1995).
The east–west extension of the Monte San Giorgio basin
is estimated to have been about 10 km or up to 20 km if it
was located in the same basin as the Perledo–Varenna
Formation outcropping to the east of Lake Como (Gianotti
and Tannoia 1988; Bernasconi 1994). Basin depths are
regarded as varying between 30 and 130 m (Monte San
Giorgio basin; Zorn 1971; Rieber 1973a; Bernasconi 1994)
and 160–260 m (Perledo–Varenna Formation; Gaetani
et al. 1992). Further to the east, the depositional setting of
the Perledo–Varenna Formation was, in turn, separated
from the pelagic deposits of the ‘Buchenstein’ facies by
shallow-water barriers (Esino Platform, an equivalent to
the Salvatore Platform in the lake Como region), only a
few meters deep (Gaetani et al. 1992). Finally, as the
Meride Limestone is considered to be the source rock of
the Trecate–Villafortuna oil fields (Po Plain; Picotti et al.
2007), the intra-platform basin system probably extended
southwards for over 60 km.
For the compilation of the composite section illustrated
in this paper, stratigraphic successions have been studied at
the cm-scale at the following localities (approximated
Swiss National Coordinates refer to the centre of the sec-
tions): Val Porina (716
0
600/85
0
100), Valle della Cassina
(717
0
150/84
0
950), Val Sceltrich (717
0
000/84
0
400), Val
Serrata (717
0
850/84
0
150 and 717
0
900/83
0
700) and Fontana
Fredda–Val Mara (717
0
050/83
0
350). The widespread
occurrence of volcanic ash beds, sometimes associated
with weathering-resistant silicified horizons, as well as the
lateral persistence of bedding patterns allow an unambig-
uous correlation of the studied sections. A major
unresolved uncertainty occurs at the base of the Kalk-
schieferzone (Val Mara; Fig. 1a), where a fault with
unknown displacement precludes to observe the transition
to the underlying part of the Upper Meride Limestone.
2.2 The Middle Triassic volcanic ash layers
in the Southern Alps
Middle Triassic pelagic sediments containing zircon-bear-
ing acidic volcaniclastic horizons, usually with a greenish
colour, are widespread in the Southern Alps. Sedimento-
logic and petrographic features indicate an air-borne origin
of the sand- to silt-sized particles of these so-called ‘Pietra
Verde’ layers, which Brack et al. (2005) suggested to have
probably originated from eruption centres mainly located
outside the present Southern Alps. Beyond the Southern
Alps, comparable volcaniclastic layers occur in the Eastern
Alps (e.g. Bru
¨
hwiler et al. 2007; Furrer et al. 2008), in the
Brianc¸onnais unit of the Western Alps (Caby and Galli
1964) and further afield (e.g. Balaton Highland, Hungary;
Pa
´
lfy et al. 2003). Current interpretations of this wide-
spread volcanic activity are highly divergent but chiefly
relate it to the evolution of the Maliac–Meliata Ocean to
the east. According to these models, the volcanic episode
could result from the extension associated with the opening
of this ocean in a general strike-slip scenario or from the
subduction of its young lithosphere (or of a segment of the
Palaeo-Tethys) generating a volcanic arc on continental
crust (see Bernoulli 2007 for a review).
Whatever the origin of the Middle Triassic volcanic
episode, due to their lateral persistence these tephra layers
proved ideal markers for precise correlations of sections up
to 200 km apart (Brack and Rieber 1993; Brack and
88 R. Stockar et al.

Muttoni 2000; Bru
¨
hwiler et al. 2007). Moreover, starting in
1996 (Mundil et al. 1996), several of these horizons have
been dated by U–Pb single zircon techniques, allowing a
geochronologic framework to be established.
In the reference section at Bagolino (eastern Lombardy,
northern Italy), bearing the GSSP for the base of the
Ladinian Stage (Brack et al. 2005), Pietra Verde layers
occur throughout the Buchenstein Formation section but
they are chiefly concentrated in three intervals (Fig. 3).
Pietra Verde layers first appear in the upper part of the
interval transitional from the pelagic Prezzo Limestone to
the siliceous nodular limestones of the Buchenstein For-
mation and follow a first stack of beige weathering tuff
beds (‘‘Ta-tuffs’’). Millimetre- to a few decimetre-thick
greenish acidic ash beds concentrate at the 56–62, 68–76
and 82–92 m intervals, constituting the so-called Lower,
Middle and Upper Pietra Verde respectively. At the top of
the Upper Pietra Verde, a major change in sedimentation
occurs which marks the abrupt switch to the siliciclastic
Wengen Formation. Pietra Verde layers constitute a pow-
erful tool to correlate Buchenstein-type sections across the
Southern Alps (Brack and Rieber 1993; Brack and Muttoni
2000; Muttoni et al. 2004) and could be laterally safely
traced as far as the Dolomites where, at Seceda, lies the
principal auxiliary section for the GSSP.
At Monte San Giorgio, intercalations of volcanic ash
layers occur throughout the upper Anisian–Ladinian
section, i.e. from the Besano Formation to the Kalkschie-
ferzone of the Upper Meride Limestone. Only in the
uppermost part (Upper Kalkschieferzone) they are missing.
Their lateral persistence makes them a reliable tool for bed-
by-bed correlations among partial sections. The ash layers
are air-borne tuffs altered to bentonite, without any detrital
admixture; at least the thicker ones show a distinct grada-
tion with a sand-sized basal part. Bentonites are usually
easily detectable in outcrop as they weather to an orange
colour. Thickness usually ranges from less than one milli-
metre to few centimetres. In the reference profile of the
Besano Formation (Rieber 1973b; Bernasconi 1994) 36 ash
layers have been recognized, while in the overlying San
Giorgio Dolomite and Meride Limestone over thirty ash
layers, between a few millimetres to 50 cm thick, have been
reported by Wirz (1945). Sub-mm yellowish bentonite
seams, however, are very frequent in the Meride Limestone
but they can be detected only on fresh bedding surfaces, as
highlighted by bed-by-bed excavations (e.g. Stockar 2010).
Somewhat different is the so-called ‘Val Serrata tuff’
(Lower Meride Limestone), a tuffite with a carbonate
cement representing one of the most reliable marker beds of
the sequence. It consists of a lower and an upper bed, up to 4
and 3 m thick respectively, bracketing the 1.5-m-thick
fossiliferous sequence informally called ‘Cava inferiore
beds’ (Sander 1989; Furrer 1999a). Composition of the
volcanic ash layers is very similar throughout the section.
They consist of a grey microcrystalline matrix of mixed-
layer illite-smectite clay minerals containing phenocrysts of
alkali feldspar, quartz and sometimes euhedral biotite.
Fig. 3 Simplified stratigraphic log of Bagolino section (GSSP for the
base of the Ladinian Stage) with U–Pb-zircon ages (BAG samples;
Mundil et al. 1996) and distribution of ammonoid taxa co-occurring in
the Ladinian section of Monte San Giorgio (Brack and Rieber 1993;
Brack et al. 2005; Schatz 2005). Also shown are the correlatable
U–Pb zircon ages (SEC samples; Mundil et al. 1996) and biostrati-
graphic data on palynomorphs (Hochuli and Roghi 2002; Bru
¨
hwiler
et al. 2007) and daonellids (Schatz 2005) from Seceda, the principal
auxiliary section in the Dolomites. The GSSP is defined by the lowest
occurrence of the ammonoid Eoprotrachyceras curionii (base of the
E. curionii Amm. Zone); it lies at the 63.25-m level of the Bagolino
reference column. Ammonoid zonal scheme according to Brack and
Rieber (1993), with the Fassanian Substage comprising both the
E. curionii and P. gredleri Amm. Zones (Brack et al. 2005). LPV, MPV,
UPV Lower, Middle and Upper Pietra Verde intervals respectively
Ladinian of Monte San Giorgio 89

Citations
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TL;DR: In this article, the sedimentary succession of the Permian to Middle Triassic of the Albanian Alps is described, as part of the eastern Adria passive margin towards the Tethys.
Abstract: The sedimentary succession of the Permian to Middle Triassic of the Albanian Alps is described, as part of the eastern Adria passive margin towards the Tethys. A carbonate ramp deepening towards NE in present day coordinates developed during the Middle Permian and was affected by block faulting with the deposition of carbonate breccia. The Early Triassic was characterized by intense terrigenous deposition with several cobble conglomerate units up to 80 m-thick, and by oolitic carbonate shoals. The fine clastic deposition ended gradually during the earliest Anisian and a wide calcarenitic ramp occupied the area, with small local carbonate mounds. Basinward, the red nodular limestone of the Han Bulog Formation was interbedded with calcarenitic material exported from the ramp. Drowning to more open conditions occurred towards the end of the Pelsonian. Subsequently, cherty limestone and tuffitic layers spread over the entire area. Towards the end of the Ladinian, with the end of the volcanic activity, red pelagic limestone was deposited locally for a short period. By the latest Ladinian most of the area returned to shallow-water conditions, with a peritidal carbonate platform. In the Theth area, in contrast, a basin with black organic-rich dolostone and limestone developed which seems to be unique in that part of the Adria passive margin. The occurrence of cobble conglomerate units in the Lower Triassic testifies to very active block faulting and high accommodation, not yet described for the area.

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TL;DR: In this paper, the authors analyzed the high-resolution gamma-ray and magnetic susceptibility series from the complete Anisian stage and tuned these series to interpreted 405-kyr long-eccentricity cycles.

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BookDOI
01 Jan 2018
Abstract: The Upper Triassic chronostratigraphic scale consists of one Series, the Upper Triassic, divided into three stages (in ascending order)—Carnian, Norian and Rhaetian. Only the base of the Carnian currently has an agreed on GSSP (global boundary stratotype section and point), though agreement on GSSPs for the bases of the Norian and Rhaetian is imminent. Substages of the Carnian and Norian provide more detailed subdivisions of Late Triassic time than do the relatively long Carnian and Norian stages. These substages need boundary definitions and greater use in Late Triassic correlations. Numerical chronology of the Late Triassic is based on very few radioisotopic ages from volcanic ash beds directly related to marine biostratigraphy. The numerical calibration of the Late Triassic favored here is Carnian ~220–237 Ma, Norian ~205–220 Ma and Rhaetian ~201–205 Ma. Late Triassic magnetostratigraphy is fraught with problems because the most complete record from the Newark Supergroup of eastern North America cannot be correlated based on pattern matching to any co-eval magnetostratigraphy from a marine section. The long Norian (beginning at ~228 Ma) was created by magnetostratigraphic correlations that abandoned biostratigraphic constraints and has produced extensive miscorrelation, particularly of nonmarine Carnian strata. A reliable Late Triassic magnetostratigraphy is a succession of multichrons that identifies the Carnian-early Norian and late Norian-Rhaetian as dominantly of normal polarity. Late Triassic cyclostratigraphy of the Newark Supergroup has been advanced as a floating astrochronology of the Late Triassic, but is problematic given evident hiatuses in the Newark record and the presence of non-cyclical lithofacies. Isotope stratigraphy of the Late Triassic, for example the late Rhaetian carbon-isotope excursion, has great potential for use in Late Triassic correlations. The Late Triassic timescale is still very much a work in progress that needs more precise chronostratigraphic definitions, additional numerical ages directly related to marine biostratigraphy, a wholesale rethinking of magnetostratigraphic correlations and additional cyclostratigraphic and isotopic data to achieve greater precision and stability. S.G. Lucas (*) New Mexico Museum of Natural History and Science, 1801 Mountain Road N. W., Albuquerque, NM 87104-1375, USA e-mail: spencer.lucas@state.nm.us

35 citations

Journal ArticleDOI
TL;DR: In this article, the authors present a comprehensive high-precision zircon U-Pb geochronology dataset for the major intrusive complexes and several volcanic ash layers and integrate this with a high-resolution stratigraphic framework of Middle Triassic volcano-sedimentary successions.
Abstract: Middle Triassic magmatism in the Southern Alps (northern Italy) consists of widespread volcanoclastic deposits, basaltic lava flows and intrusive complexes. Despite their importance in understanding the geodynamic evolution of the westernmost Tethys, the timing of magmatic activity and the links between the different igneous products remain poorly understood. We present a comprehensive high-precision zircon U–Pb geochronology dataset for the major intrusive complexes and several volcanic ash layers and integrate this with a high-resolution stratigraphic framework of Middle Triassic volcano-sedimentary successions. The main interval of Middle Triassic magmatism lasted at least 5.07 ± 0.06 myr. Magmatic activity started with silicic eruptions between 242.653 ± 0.036 and 238.646 ± 0.037 Ma, followed by a Supplementary material: Isotope dilution thermal ionization mass spectrometry U–Pb and laser ablation inductively coupled plasma mass spectrometry trace element data tables, sample coordinates, supplementary geochemical data, cathodoluminescence images of isotope dilution thermal ionization mass spectrometry dated zircons and supplementary field documentation are available at https://doi.org/10.6084/m9.figshare.c.4287506

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Cites background from "Integrated Ladinian bio-chronostrat..."

  • ...The first domain of Late Anisian to early Ladinian magmatic products is found as variably thick acidic volcaniclastic layers in basinal sediments throughout the entire Southern Alps (Brack & Rieber 1993; Brack et al. 2007; Stockar et al. 2012)....

    [...]

Journal ArticleDOI
TL;DR: A review of the proposed partial character ‘un-scoring’ using three published data matrices indicate that this approach is flawed and should be avoided, and that within the marine reptile ‘superclade’ E. dalsassoi potentially is the sister taxon of Sauropterygia.
Abstract: Recently it was suggested that the phylogenetic clustering of Mesozoic marine reptile lineages, such as thalattosaurs, the very successful fish-shaped ichthyosaurs and sauropterygians (including plesiosaurs), among others, in a so-called ‘superclade’ is an artefact linked to convergent evolution of morphological characters associated with a shared marine lifestyle. Accordingly, partial ‘un-scoring’ of the problematic phylogenetic characters was proposed. Here we report a new, exceptionally preserved and mostly articulated juvenile skeleton of the diapsid reptile, Eusaurosphargis dalsassoi, a species previously recovered within the marine reptile ‘superclade’, for which we now provide a revised diagnosis. Using micro-computed tomography, we show that besides having a deep skull with a short and broad rostrum, the most outstanding feature of the new specimen is extensive, complex body armour, mostly preserved in situ, along its vertebrae, ribs, and forelimbs, as well as a row of flat, keeled ventrolateral osteoderms associated with the gastralia. As a whole, the anatomical features support an essentially terrestrial lifestyle of the animal. A review of the proposed partial character ‘un-scoring’ using three published data matrices indicate that this approach is flawed and should be avoided, and that within the marine reptile ‘superclade’ E. dalsassoi potentially is the sister taxon of Sauropterygia.

33 citations

References
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TL;DR: The IUGS Subcommission on Geochronology (FOOTNOTE 4) as discussed by the authors recommended the adoption of a standard set of decay constants and isotopic abundances in isotope geology.

9,474 citations


"Integrated Ladinian bio-chronostrat..." refers methods in this paper

  • ...The consensus value of 238U/235U = 137.88 (Steiger and Jäger 1977) was used in the data reduction calculations....

    [...]

BookDOI
01 Jan 2004
TL;DR: Gradstein et al. as discussed by the authors proposed a chronostratigraphy approach for linking time and rock in the context of geologic time scales, including the geomagnetic polarity time scale and stable isotope geochronology.
Abstract: Part I. Introduction: 1. Introduction F. M. Gradstein 2. Chronostratigraphy - linking time and rock F. M. Gradstein, J. G. Ogg and A. G. Smith Part II. Concepts and Methods: 3. Biostratigraphy F. M. Gradstein, R. A. Cooper and P. M. Sadler 4. Earth's orbital parameters and cycle stratigraphy L. A. Hinnov 5. The geomagnetic polarity time scale J. G. Ogg and A. G. Smith 6. Radiogenic isotope geochronology M. Villeneuve 7. Stable isotopes J. M. McArthur and R. J. Howarth 8. Geomathematics F. P. Agterberg Part III. Geologic Periods: 9. The Precambrian: the Archaen and Proterozoic eons L. J. Robb, A. H. Knoll, K. A. Plumb, G. A. Shields, H. Strauss and J. Veizer 10. Toward a 'natural' Precambrian time scale W. Bleeker 11. The Cambrian period J. H. Shergold and R. A. Cooper 12. The Ordovician period R. A. Cooper and P. M. Sadler 13. The Silurian period M. J. Melchin, R. A. Cooper and P. M. Sadler 14. The Devonian period M. R. House and F. M. Gradstein 15. The Carboniferous period V. Davydov, B. R. Wardlaw and F. M. Gradstein 16. The Permian period B. R. Wardlaw, V. Davydov and F. M. Gradstein 17. The Triassic period J. G. Ogg 18. The Jurassic period J. G. Ogg 19. The Cretaceous Period J. G. Ogg, F. P. Agterberg and F. M. Gradstein 20. The Paleogene period H. P. Luterbacher, J. R. Ali, H. Brinkhuis, F. M. Gradstein, J. J. Hooker, S. Monechi, J. G. Ogg, J. Powell, U. Rohl, A. Sanfilippo, and B. Schmitz 21. The Neogene period L. Lourens, F. Hilgen, N. J. Shackleton, J. Laskar and D. Wilson 22. The Pleistocene and Holocene epochs P. Gibbard and T. van Kolfschoten Part IV. Summary: 23. Construction and summary of the geologic time scale F. M.. Gradstein, J. G. Ogg and A. G. Smith Appendices Bibliography Stratigraphic index General index.

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Journal ArticleDOI
TL;DR: New determinations of the half-lives of half-life values of $ −235 and −238 have been made improved techniques have allowed the halflife values to be measured with greater accuracy than has been heretofore achieved as discussed by the authors.
Abstract: New determinations of the half-lives of $^{235}\mathrm{U}$ and $^{238}\mathrm{U}$ have been made Improved techniques have allowed the half-life values to be measured with greater accuracy than has been heretofore achieved Samples were prepared by molecular plating and counted in a intermediate-geometry $\ensuremath{\alpha}$-proportional counter with an extremely flat pulse-height plateau The small amount of residual nonplated uranium was counted in a $2\ensuremath{\pi}$ counter Energy analysis with a silicon-junction detector was used to measure the presence of "foreign" activities For $^{235}\mathrm{U}$, the measured specific activity was (47981\ifmmode\pm\else\textpm\fi{}33) (dis/min)/(mg $^{235}\mathrm{U}$), corresponding to a half-life of (70381\ifmmode\pm\else\textpm\fi{}00048) \ifmmode\times\else\texttimes\fi{} ${10}^{8}$ yr For $^{238}\mathrm{U}$, the specific activity was measured as (74619\ifmmode\pm\else\textpm\fi{}041) (dis/min)/(mg $^{238}\mathrm{U}$), corresponding to a half-life of (44683\ifmmode\pm\else\textpm\fi{}00024) \ifmmode\times\else\texttimes\fi{} ${10}^{9}$ yr Errors quoted are statistical (standard error of the mean), based upon the observed scatter of the data This scatter exceeds that expected from counting statistics alone We believe that systematic errors, if present, will no more than double the quoted errors

2,543 citations


"Integrated Ladinian bio-chronostrat..." refers background or methods in this paper

  • ...The magnitude of these two sources of error is estimated at 0.1 and 0.11 % respectively (Jaffey et al. 1971; Condon et al. 2007)....

    [...]

  • ...All 206Pb/238U dates are calculated using the 238U and 235U decay constants of Jaffey et al. (1971) and corrected for initial U/Th disequilibrium using an assumed Th/U magma ratio of 4, typical for magmatic systems....

    [...]

Journal ArticleDOI
TL;DR: In this article, a plate tectonic model for the Paleozoic and Mesozoic (Ordovician to Cretaceous) integrating dynamic plate boundaries, plate buoyancy, ocean spreading rates and major Tectonic and magmatic events was developed.

2,310 citations


"Integrated Ladinian bio-chronostrat..." refers background in this paper

  • ...In Middle Triassic times, the South-Alpine domain was situated on a passive continental margin open to the tropical western Neo-Tethys (e.g. Stampfli and Borel 2002), which was progressively submerged by a long-term transgression from the east....

    [...]

Journal ArticleDOI
TL;DR: CA-TIMS as discussed by the authors uses high-temperature treatment to anneal zircon lattice radiation damage from natural alpha, alpha recoil, and spontaneous fission processes; this annealing eliminates elemental and isotopic leaching effects that have limited earlier efforts at chemical leaching or multi-step step-wise dissolution or partial dissolution analysis (PDA)

1,200 citations


"Integrated Ladinian bio-chronostrat..." refers methods in this paper

  • ...We apply this technique, coupled with the annealing/chemical abrasion (CA) pre-treatment procedure of Mattinson (2005), to the Ladinian sequence of Monte San Giorgio, which, in addition, has been constrained by new biostratigraphic data....

    [...]

  • ...All the zircons analysed have undergone the (CA, thermal annealing and subsequent leaching) pretreatment technique (Mattinson 2005) for the effective elimination of Pb-loss....

    [...]

  • ...…refinement was achieved by Mundil et al. (2010) who obtained for the sample MSG.09 a U–Pb zircon age of 242.1 ± 0.6 Ma using annealing followed by chemical abrasion (CA–TIMS), a pre-treatment technique effectively resulting in zircon crystals having a closed isotopic system (Mattinson 2005)....

    [...]

Frequently Asked Questions (11)
Q1. What are the contributions mentioned in the paper "Integrated ladinian bio-chronostratigraphy and geochrononology of monte san giorgio (southern alps, switzerland)" ?

In this paper, a single-zircon U-Pb dating was performed using ID-TIMS and chemical abrasion ( CA ) pre-treatment technique on volcanic ash layers intercalated in the biostratigraphically defined intervals of the Meride Limestone. 

Since the fossiliferous interval is around 10 m thick (mostly extending above, i.e. younger than the dated layer), the fauna of the Cava superiore beds reasonably represents a time interval of about 0.3 Myr. 

Assemblage III is assigned to the secatus-dimorphus phase of Van der Eem (1983), mainly based on the distribution of Echinitosporites iliacoides, an important marker restricted to this phase (Van der Eem 1983; Brühwiler et al. 2007). 

The fossil assemblage from the Lower Kalkschieferzone (Val Mara, Site D) is dated to the 206Pb/238U age of 239.51 ± 0.15 Ma and it is assigned to the early Longobardian (early late Ladinian, P. archelaus Amm. Zone). 

Assemblage II is assigned to the plurianulatus-secatus phase of Van der Eem (1983) and conforms to the Assemblage D of Hochuli and Roghi (2002) on the basis of the distinct increase of the Ovalipollis group (from[2 % to [20 % in the Seceda section) and of the FO of Camerosporites secatus and Duplicisporites granulatus. 

Sedimentologic and petrographic features indicate an air-borne origin of the sand- to silt-sized particles of these so-called ‘‘Pietra Verde’’ layers, which Brack et al. (2005) suggested to have probably originated from eruption centres mainly located outside the present Southern Alps. 

The newly defined biostratigraphic and geochronologic constraints for the Ladinian sequence of Monte San Giorgio allow to resolve to the zone level the age of the classic fossil-bearing horizons of the Meride Limestone, which are assigned to the P. gredleri Amm. 

conclusions on topics, which are crucial for this Lagerstätte, such as the assessment of evolutionary rates of its fossil vertebrate faunas, remain highly speculative. 

The sampled bed is the thickest bentonite horizon in the Monte San Giorgio section and the most reliable marker horizon of the Kalkschieferzone. 

the range of this assemblage (and consequently of the P. gredleri Amm. Zone) is poorly constrained due to outcrop conditions and lithologies unsuitable for yielding reliable palynological data. 

Its absence is regarded as a primary feature by Müller et al. (1964), who consider the acid tuff layers of Monte San Giorgio as restricted to the Lake of Lugano region.