Journal ArticleDOI
Interconnected Porous Polymers with Tunable Pore Throat Size Prepared via Pickering High Internal Phase Emulsions.
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TLDR
Poly-Pickering HIPEs with high permeability and well-defined pore structure can be achieved by tuning the MA content, the internal phase fraction, and the content of modified silica particles.Abstract:
Interconnected macroporous polymers were prepared by copolymerizing methyl acrylate (MA) via Pickering high internal phase emulsion (HIPE) templates with modified silica particles. The pore structure of the obtained polymer foams was observed by field-emission scanning electron microscopy (FE-SEM). Gas permeability was characterized to evaluate the interconnectivity of macroporous polymers. The polymerization shrinkage of continuous phase tends to form open pores while the solid particles surrounding the droplets act as barriers to produce closed pores. These two conflicting factors are crucial in determining the interconnectivity of macroporous polymers. Thus, poly-Pickering HIPEs with high permeability and well-defined pore structure can be achieved by tuning the MA content, the internal phase fraction, and the content of modified silica particles.read more
Citations
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Journal ArticleDOI
Emulsion Templating: Porous Polymers and Beyond
TL;DR: In this paper, the original hydrophobic porous polymers were synthesized within surfactant-stabilized water-in-oil high internal phase emulsions (HIPEs) by us.
Journal ArticleDOI
Emulsion-templated polymers: Contemporary contemplations
TL;DR: The field of emulsion-templated porous polymers (polyHIPEs) as mentioned in this paper has been a promising area of research in the field of porous materials and has been widely studied.
Journal ArticleDOI
Preparation of porous adsorbent via Pickering emulsion template for water treatment: A review.
TL;DR: This paper reviewed comprehensively the latest research progress on the preparation of porous materials from various Pickering emulsions and their applications in the decontamination of pollutants and in the oil/water separation.
Journal ArticleDOI
Water-in-oil Pickering emulsions stabilized by stearoylated microcrystalline cellulose.
TL;DR: Stearoylated microcrystalline cellulose (SMCC) was prepared by modifying MCC with stearoyl chloride under heterogeneous conditions and could efficiently stabilize W/O Pickering emulsions and HIPEs and could only be prepared via the two-step method.
Journal ArticleDOI
Synthesis of Emulsion-Templated Magnetic Porous Hydrogel Beads and Their Application for Catalyst of Fenton Reaction.
TL;DR: The results showed that these FeNPs loaded porous hydrogel beads were reusable and highly efficient supporter for catalysis of Fenton reaction for decomposing organic pollutants in water.
References
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Journal ArticleDOI
Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications
Hiroyasu Furukawa,Omar M. Yaghi +1 more
TL;DR: Findings place COFs among the most porous and the best adsorbents for hydrogen, methane, and carbon dioxide.
Journal ArticleDOI
Design and Preparation of Porous Polymers
TL;DR: This work presents a new mesoporous composite material suitable for high-performance liquid chromatography and shows good chiral recognition ability and high uniformity in various racemates.
Journal ArticleDOI
High internal phase emulsion templating as a route to well-defined porous polymers
TL;DR: The use of high internal phase emulsions as templates to create highly porous materials (PolyHIPEs) is described in this article, where the void fraction is very high and can reach levels of 0.99.
Journal ArticleDOI
Synergistic Interaction in Emulsions Stabilized by a Mixture of Silica Nanoparticles and Cationic Surfactant
TL;DR: A detailed investigation into the behavior of dodecane-water emulsions stabilized by a mixture of silica nanoparticles and pure cationic surfactant has been made, showing that both emulsifiers prefer to stabilize o/w emulsion phase inversion and synergism is displayed in these mixtures.
Journal ArticleDOI
Foams and foam films stabilised by solid particles
TL;DR: In this paper, the authors reviewed recent developments in the field of particle-stabilised aqueous foams and foam films and discussed the link between the film stability and that of particlestabilized foams.