Journal ArticleDOI
Interconversion of bicyclooctadienes and cyclooctatrienes formed by intramolecular photocycloaddition of phenyl ketones containing remote double bonds
Peter J. Wagner,Keepyung Nahm +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1987-10-01. It has received 24 citations till now. The article focuses on the topics: Intramolecular reaction & Intramolecular force.read more
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Journal ArticleDOI
Arene–Alkene Cycloaddition
Richard Remy,Christian G. Bochet +1 more
TL;DR: This review will focus on cycloadditions, covering literature from early observations up to the present, and finds that aromatic rings show a rich photochemistry, ranging from isomerizations, substitutions, and additions to cycloadDitions.
Journal ArticleDOI
The arene–alkene photocycloaddition
TL;DR: This short review aims to demonstrate the synthetic power of three different modes of photocycloaddition with benzene derivatives withBenzene derivatives.
Journal ArticleDOI
Photoinduced ortho [2 + 2] cycloaddition of double bonds to triplet benzenes.
TL;DR: The triplet states of certain phenyl ketones and benzoic acid derivatives undergo regioselective and stereoselectives intramolecular ortho cycloaddition to remote double bonds, triggering an array of photochemical and thermal pericyclic rearrangements among various novel polycyclic products.
Journal ArticleDOI
A Photochemical Approach to the Gelsemine Skeleton
TL;DR: In this article, a silicon-tethered intramolecular meta photocycloaddition reaction was utilized to prepare a photoadduct, which was subsequently fragmented using m-CPBA to give a model for the skeleton of the alkaloid gelsemine.
Journal ArticleDOI
Development of an Alkyne Analogue of the de Mayo Reaction: Synthesis of Medium-Sized Carbacycles and Cyclohepta[b]indoles.
David Tymann,Dina Christina Tymann,Ulf Bednarzick,Ljuba Iovkova-Berends,Julia Rehbein,Martin Hiersemann +5 more
TL;DR: Key to the cascading ring-expansion process is an unprecedented intramolecular alkyne analogue of the de Mayo reaction.
Related Papers (5)
Regiospecific intramolecular reaction of an alkene group with the benzene ring of a triplet ketone
Peter J. Wagner,Keepyung Nahm +1 more