Intrinsic rates and activation free energies from single-molecule pulling experiments.
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...This mapping follows directly from the quasi-adiabatic assumption (22, 26) and is independent of the nature of the underlying free-energy surface....
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...Indeed, the same functional relation, with a numerical coefficient that differs by <10%, can be derived from the highly non-Gaussian rupture-force distributions (22) that correspond to τ (F) in Eq....
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...For several simple one-dimensional free-energy profiles, the lifetime τ (F) calculated from Kramers theory can then be written as (22):...
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...Explicit expressions for the rupture-force distributions enable the use of powerful maximum-likelihood or Bayesian inference methods in the analysis of experiments (22)....
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...Recently (22), we have made the phenomenological model, based on Bell’s assumption, more realistic while retaining its mathematical simplicity....
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