Journal ArticleDOI
Investigation into the Structural and Electrical Properties of Silver-Intercalated Zirconium Diselenide
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TLDR
In this paper, the phase diagram of the AgxZrSe2 compound was determined in the temperature range 423 −523 K and at room temperature, which indicated a polaron nature of charge-carrier localization.Abstract:
Silver-intercalated zirconium diselenides of the general formula AgxZrSe2 are synthesized for the first time. The phase diagram of the AgxZrSe2 compound is determined in the temperature range 423–523 K and at room temperature. An analysis has revealed the coexistence of two compounds, namely, Ag0.125ZrSe2 and Ag0.25ZrSe2, of which only the latter compound is stable at room temperature. The structural and electrical properties of AgxZrSe2 diselenides are investigated. The results obtained indicate a polaron nature of charge-carrier localization. A comparison with isostructural intercalation compounds shows that free charge carriers play a dominant role in screening of the impurity potential.read more
Citations
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Journal ArticleDOI
Advances in Liquid-Phase and Intercalation Exfoliations of Transition Metal Dichalcogenides to Produce 2D Framework
Ali Raza,Jahan Zeb Hassan,Muhammad Ikram,Salamat Ali,Umer Farooq,Qasim Khan,Muhammad Maqbool +6 more
Journal ArticleDOI
Transport properties and polarization phenomena in intercalated Ag x HfSe 2 compounds
TL;DR: In this paper, the electrical properties of intercalated Ag and HfSe2 compounds have been investigated for the first time using various current electrodes, which make it possible to pass either the electron current or the ion current across the sample.
Journal ArticleDOI
Iron-Intercalated Zirconium Diselenide Thin Films from the Low-Pressure Chemical Vapor Deposition of [Fe(η5-C5H4Se)2Zr(η5-C5H5)2]2.
Clara Sanchez-Perez,Clara Sanchez-Perez,Caroline E. Knapp,R. H. Colman,Carlos Sotelo-Vazquez,Sanjayan Sathasivam,Raija Oilunkaniemi,Risto S. Laitinen,Claire J. Carmalt +8 more
TL;DR: The synthesis and characterization of Fe-intercalated ZrSe2 thin films on quartz substrates are demonstrated using the low-pressure chemical vapor deposition of the single-source precursor [Fe(η5-C5H4Se)2Zr(ε5- C5H5)2]2.
Journal ArticleDOI
Thermal stability of the Cu–ZrTe2 intercalation compounds
Alexey S. Shkvarin,A. A. Titov,M. S. Postnikov,M. S. Postnikov,Jasper R. Plaisier,Lara Gigli,Mattia Gaboardi,Alexander Titov,Alexander Titov,E. G. Shkvarina +9 more
Journal ArticleDOI
Influence of dopant concentration on the electronic band gap energy of Yb-ZrSe2 thin films for photovoltaic application via electrochemical deposition technique
Lucky I Ikhioya,Ugochi K. Chime,Chidimma F. Okoro,Chinedu Iroegbu,Malik Maaza,Malik Maaza,Fabian I. Ezema,Fabian I. Ezema,Fabian I. Ezema +8 more
TL;DR: In this paper, the influence of Dopant Concentration on polycrystalline Ytterbium-doped ZrSe (Yb-ZrSe) material for possible photovoltaic application using the electrochemical deposition method was investigated.
References
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Journal ArticleDOI
Electronic properties of intercalation complexes of the transition metal dichalcogenides
Richard H. Friend,A D Yoffe +1 more
TL;DR: In this paper, the effects of intercalation of the layer type transition metal dichalcogenides by a variety of organic molecules, alkali metals, or 3D transition metals are discussed.
Journal ArticleDOI
Electronic band structure and bonding in transition metal layered dichalcogenides by atomic orbital methods
TL;DR: In this article, the main features of the electronic structure of transition metal layered dichalcogenides can be calculated in a simple ab initio atomic orbital framework, based on the properties of groups IV, V and VI of the transition series.
Journal ArticleDOI
Investigations on Cuprous Sulfide
J. Bruce Wagner,Carl Wagner +1 more
TL;DR: In this paper, the activity of copper in cuprous sulfide as a function of the copper-to-sulfur ratio has been determined with the help of coulometric titrations.
Journal ArticleDOI
Electrical Resistivity and Thermoelectric Power of Intercalation Compounds MxTiS2 (M = Mn, Fe, Co, and Ni)
TL;DR: In this article, the effect of intercalation of 3D metals into TiS2 layers on the electronic properties is discussed, which can be explained by a simple model, which takes into account a temperatureindependent residual term and intra-and intervalley scattering by acoustic phonons.
Journal ArticleDOI
Semiconductor-metal transition upon intercalation in LixZrSe2
TL;DR: In this paper, the authors present a set of experimental data on the Li x ZrSe 2 system as a function of x, including X ray, electrochemical, conductivity, NMR and EPR measurements.
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