Journal ArticleDOI
Investigation of potential inversion in the reduction of 9,10-dinitroanthracene and 3,6-dinitrodurene
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TLDR
In the case of two-electron reduction of a compound, potential inversion refers to the situation where introduction of the second electron occurs with greater ease than the first as mentioned in this paper, that is E01−E02About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 2004-04-01. It has received 27 citations till now.read more
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One-electron and two-electron transfers in electrochemistry and homogeneous solution reactions.
TL;DR: For a majority of electrode reactions of organic and organometallic species, only a single oxidation or reduction is encountered within the accessible potential range of the solvent/electrolyte medium that is chosen.
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Study of the Effects of Ion Pairing and Activity Coefficients on the Separation in Standard Potentials for Two-Step Reduction of Dinitroaromatics
TL;DR: It is concluded that structural changes accompanying the reduction, rather than activity and ion pairing effects, are the dominant factors underlying potential inversion.
Journal ArticleDOI
Studies of the electrochemical reduction of some dinitroaromatics
TL;DR: In this article, the electrochemical reduction of a series of dinitroaromatics, along with one trinitro compound, has been investigated at a glassy carbon electrode in N, N -dimethylformamide.
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Nonequilibrium charge-Kondo transport through negative- U molecules
TL;DR: In this paper, an exact mapping between the negative $U$ and the positive$U$ Anderson models was established, which is suitable for the description of nonequilibrium transport and employed this mapping to demonstrate the intimate relation between spin flips and pair-tunneling processes.
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Thiolated π-Extended Tetrathiafulvalenes: Versatile Multifunctional π-Systems
TL;DR: In this article, direct phosphite-mediated cross-couplings of anthraquinone with 1,3-dithiole-2-thione derivatives have been used to synthesize 9,10-bis(1,3dithiol-2,ylidene)-9, 10-dihydroanthracene (ex-TTF) derivatives.
References
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Journal ArticleDOI
Comparison of voltammetric steady states at hemispherical and disc microelectrodes
Keith B. Oldham,Cynthia G. Zoski +1 more
TL;DR: In this paper, the shapes of steady-state voltammograms at inlaid disc and at shrouded hemispherical microelectrodes are presented. But the shape of voltamograms is not identical if the electron transfer occurs irreversibly.
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Study of Steric Effects by Electron Spin Resonance Spectroscopy and Polarography. Substituted Nitrobenzenes and Nitroanilines
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Inverted potentials in two-electron processes in organic electrochemistry
Dennis H. Evans,Kai Hu +1 more
TL;DR: In this paper, the authors used AM1 to compute disproportionation energies for a variety of aromatic hydrocarbons and the results were found to be remarkably similar to those calculated for charging spheres in vacuum.
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Two-Electron Reactions in Organic and Organometallic Electrochemistry.
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Heterogeneous electron transfer kinetics for a variety of organic electrode reactions at the mercury-acetonitrile interface using either tetraethylammonium perchlorate or tetraheptylammonium perchlorate electrolyte
TL;DR: In this paper, the electrode reactions of 26 compounds have been studied by cyclic voltammetry at mercury electrodes using acetonitrile as solvent and either TEAP or THpAP as supporting electrolyte.