Journal ArticleDOI
IR-und Raman-untersuchungen zur struktur des di-benzol-chroms, seines kations sowie verwandter verbindungen
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In this paper, the infra-red spectra of Cr(C6H6)2, Cr(c6D6) 2, [Cr(C 6H6]2]I, Mo(C7H6), [Mo(C5H6)-2], W 6H 6]I and V 6D 6]2 have been measured.About:
This article is published in Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy.The article was published on 1961-01-01. It has received 47 citations till now. The article focuses on the topics: Raman spectroscopy.read more
Citations
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Journal ArticleDOI
Possible importance of a “metal-surface selection rule” in the interpretation of the infrared spectra of molecules adsorbed on particulate metals; infrared spectra from ethylene chemisorbed on silica-supported metal catalysts
H.A Pearce,Norman Sheppard +1 more
TL;DR: In this paper, a metal-surface selection rule has been used in interpreting infrared spectra from molecules adsorbed on finely-divided metals, which has been shown to be applicable to the case of catalysts with supported etal catalysts.
Journal ArticleDOI
A Novel Network Structure of Organometallic Clusters in the Gas Phase
Atsushi Nakajima,Koji Kaya +1 more
TL;DR: In this article, a beam source with laser vaporization of metal rods and time-of-flight mass spectrometry was used to produce and detect the gas-phase organometallic clusters.
Book ChapterDOI
Infrared and Raman Spectral Studies of π Complexes Formed Between Metals and CnHnRings
TL;DR: In this paper, the analysis of vibrational spectra of organometallic compounds formed by the metals and hydrocarbons of general formula (CH)n is discussed, and theoretical and experimental results for four, six, seven, and eight CH groups with suitable metals are presented.
Journal ArticleDOI
A soft-landing experiment on organometallic cluster ions: infrared spectroscopy of V(benzene)2 in Ar matrix
Ken Judai,Kentaro Sera,Shin Ichi Amatsutsumi,Keiichi Yagi,Tomokazu Yasuike,Satoshi Yabushita,Atsushi Nakajima,Koji Kaya +7 more
TL;DR: In this article, the authors measured the infrared spectrum of V 1 (benzene) 2 in the Ar matrix after one-hour deposition with the deposition energy of 20 eV. The spectrum was in agreement with both the reported spectrum and theoretical calculations.
Journal ArticleDOI
Symmetry coordinates, harmonic force field, and mean amplitudes for light and heavy dibenzene chromium.
TL;DR: In this article, the molecular vibrations of dibenzene chromium were analyzed in terms of the eclipsed 25 atomic model of symmetry D6h with planar ligands, and a complete set of symmetry coordinates was constructed and based almost entirely on conventional types of valence coordinates.
References
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Journal ArticleDOI
The vibrational spectra and structure of ferrocene and ruthenocene
TL;DR: In this article, the infrared and Raman spectra of ferrocene, ruthenocene and cyclopentadienyl rings have been reported and a detailed assignment of frequencies to the fundamental modes of vibration has been made for these compounds.
Journal ArticleDOI
Infra-red summation bands of the out-of-plane C-H bending vibrations of substituted benzene compounds
TL;DR: In this paper, it was shown that the stronger infra-red absorption bands from 1650 to 2000 cm −1 in benzene derivatives normally arise from summation tones of the out-of-plane C-H bending vibrations.
Journal ArticleDOI
The vibrational spectrum of the dichromate ion
TL;DR: In this article, the infra-red and Raman spectra of the dichromate ion were described and the observed spectra were consistent with a C2v-structure of the ion containing one bridging oxygen atom bound to the two chromium atoms.
Journal ArticleDOI
Über Aromatenkomplexe von Metallen, XXVI. IR‐Untersuchungen an Cyclopentadienyl‐Metall‐Komplexen
TL;DR: In this article, die C5H5-Liganden werden 5 Frequenzbereiche angegeben und Abweichungen von der D5h-Symmetrie diskutiert.
Journal ArticleDOI
Über Aromatenkomplexe von Metallen. II. Zur Kristallstruktur und Molekelgestalt des Di‐benzol‐chrom(0)
Erwin Weiss,Ernst Otto Fischer +1 more
TL;DR: The Cr(C6H6)2 as discussed by the authors is a type einer neuen Reihe von Komplexen aus ungeladenen aromatischen Systemen and geeigneten Ubergangsmetallen, die schon fur die Metall-dicyclopentadienyle Me(C5H5)2 nachgewiesene Doppelkegel-Struktur aufweist.
Related Papers (5)
Symmetry coordinates, harmonic force field, and mean amplitudes for light and heavy dibenzene chromium.
Spektroskopische untersuchungen an organometallischen verbindungen—X1: Infrarot-spektren von benzol-chrom-tricarbonyl-h6 und -d6
H.P. Fritz,J. Manchot +1 more