Isothermal (vapour + liquid) equilibria of three binary mixtures at four temperatures
TL;DR: In this paper, the isothermal equilibria of (4-methylpentane-2-one + pyridine), (4methyl pentane-1-one+ 1,4-dioxane), and (pyridine + 1, 4-Dioxane) have been measured at 308.65, 313.15, 318.15 and 323.15 K using the total pressure method.
About: This article is published in The Journal of Chemical Thermodynamics.The article was published on 1989-02-01. It has received 2 citations till now. The article focuses on the topics: UNIQUAC & Non-random two-liquid model.
Citations
More filters
TL;DR: In this article, a headspace gas chromatographic method is used to measure infinite dilution activity coefficients of 20 liquid organic solutes dissolved in pyridine at 298.15 K.
26 citations
TL;DR: In this article, isothermal (vapor + liquid) equilibria of (4-methylpentan-2-one + pyridine + 1,4-dioxane) have been measured at (308.65, 313.15, 318.15 and 323.15) K using the total-pressure method.
References
More filters
Book•
01 Jan 1977
TL;DR: In this article, the authors estimate physical properties of pure components and Mixtures and show that the properties of these components and mixtures are similar to those of ideal gases and liquids.
Abstract: Chapter 1: The Estimation of Physical Properties. Chapter 2: Pure Component Constants. Chapter 3: Thermodynamic Properties of Ideal Gases. Chapter 4: Pressure-Volume-Temperature Relationships of Pure Gases and Liquids. Chapter 5: Pressure-Volume-Temperature Relationships of Mixtures. Chapter 6: Thermodynamic Properties of Pure Components and Mixtures. Chapter 7: Vapor Pressures and Enthalpies of Vaporization of Pure Fluids. Chapter 8: Fluid Phase Equilibria in Multicomponent Systems. Chapter 9: Viscosity. Chapter 10: Thermal Conductivity. Chapter 11: Diffusion Coefficients. Chapter 12: Surface Tension.
14,380 citations
TL;DR: In this paper, a new equation based on Scott's two-liquid model and on an assumption of nonrandomness similar to that used by Wilson is derived, which gives an excellent representation of many types of liquid mixtures.
Abstract: A critical discussion is given of the use of local compositions for representation of excess Gibbs energies of liquid mixtures. A new equation is derived, based on Scott's two-liquid model and on an assumption of nonrandomness similar to that used by Wilson. For the same activity coefficients at infinite dilution, the Gibbs energy of mixing is calculated with the new equation as well as the equations of van Laar, Wilson, and Heil; these four equations give similar results for mixtures of moderate nonideality but they differ appreciably for strongly nonideal systems, especially for those with limited miscibility. The new equation contains a nonrandomness parameter α12 which makes it applicable to a large variety of mixtures. By proper selection of α12, the new equation gives an excellent representation of many types of liquid mixtures while other local composition equations appear to be limited to specific types. Consideration is given to prediction of ternary vapor-liquid and ternary liquid-liquid equilibria based on binary data alone.
5,759 citations
TL;DR: The UNIQUAC equation as discussed by the authors is a semi-theoretical equation for the excess Gibbs energy of a liquid mixture, which is generalized through introduction of the local area fraction as the primary concentration variable.
Abstract: To obtain a semi-theoretical equation for the excess Gibbs energy of a liquid mixture, Guggenheim's quasi-chemical analysis is generalized through introduction of the local area fraction as the primary concentration variable. The resulting universal quasi-chemical (UNIQUAC) equation uses only two adjustable parameters per binary. Extension to multicomponent systems requires no ternary (or higher) parameters.
The UNIQUAC equation gives good representation of both vapor-liquid and liquid-liquid equilibria for binary and multicomponent mixtures containing a variety of nonelectrolyte components such as hydrocarbons, ketones, esters, amines, alcohols, nitriles, etc., and water. When well-defined simplifying assumptions are introduced into the generalized quasi-chemical treatment, the UNIQUAC equation reduces to any one of several well-known equations for the excess Gibbs energy, including the Wilson, Margules, van Laar, and NRTL equations.
The effects of molecular size and shape are introduced through structural parameters obtained from pure-component data and through use of Staverman's combinatorial entropy as a boundary condition for athermal mixtures. The UNIQUAC equation, therefore, is applicable also to polymer solutions.
4,130 citations
Esso1
TL;DR: In this paper, a new correlation of second virial coefficients of both polar and nonpolar systems is presented, which uses the Pitzer-Curl correlation for non-polar compounds, but in a modified form.
Abstract: A new correlation of second virial coefficients of both polar and nonpolar systems is presented. It uses the Pitzer-Curl correlation for nonpolar compounds, but in a modified form. The second virial coefficient of nonhydrogen bonding compounds (ketones, acetaldehyde, acetonitrile, ethers) and weakly hydrogen bonding compounds (phenol) is fitted satisfactorily with only one additional parameter per compound, which is shown to be a strong function of the reduced dipole moment. Two parameters are needed for hydrogen bonding compounds (alcohols, water), but for alcohols, one parameter has been kept constant and the other expressed as a function of the reduced dipole moment. The extension of the correlation to mixtures is satisfactory, direct, and involves only one coefficient per binary.
858 citations
220 citations