Isotopic standards for carbon and oxygen and correction factors for mass-spectrometric analysis of carbon dioxide
TL;DR: In this paper, Niee's and Solenhofen standards were compared to the Chicago PDB standard for carbon and oxygen isotope ratios, and the correction factors for instrumental effects and for the nature of the mass spectra were derived.
About: This article is published in Geochimica et Cosmochimica Acta.The article was published on 1957-01-01. It has received 4071 citations till now. The article focuses on the topics: Carbon & Carbon dioxide.
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01 Jan 1989
TL;DR: In this article, the physical and enzymatic bases of carbone isotope discrimination during photosynthesis were discussed, noting how knowledge of discrimination can be used to provide additional insight into photosynthetic metabolism and the environmental influences on that process.
Abstract: We discuss the physical and enzymatic bases of carbone isotope discrimination during photosynthesis, noting how knowledge of discrimination can be used to provide additional insight into photosynthetic metabolism and the environmental influences on that process
6,246 citations
TL;DR: The use of stable isotopes to solve biogeochemical problems in ecosystem analysis is increasing rapidly because stable isotope data can contribute both source-sink (tracer) and process information: the elements C, N, S, H, and all have more than one isotope, and isotopic compositions of natural materials can be measured with great precision with a mass spectrometer as mentioned in this paper.
Abstract: The use of stable isotopes to solve biogeochemical problems in ecosystem analysis is increasing rapidly because stable isotope data can contribute both source-sink (tracer) and process information: The elements C, N, S, H, and all have more than one isotope, and isotopic compositions of natural materials can be measured with great precision with a mass spectrometer. Isotopic compositions change in predictable ways as elements cycle through the biosphere. These changes have been exploited by geochemists to understand the global elemental cycles. Ecologists have not until quite recently employed these techniques. The reasons for this are, first, that most ecologists do not have the background in chemistry and geochemistry to be fully aware of the possibilities for exploiting the natural variations in stable isotopic compositions, and second, that stable isotope ratio measurements require equipment not normally available to ecologists. This is unfortunate because some of the more intractable problems in ecology can be profitably addressed using stable isotope measurements. Stable isotopes are ideally suited to increase our understanding of element cycles in ecosystems. This review is written for ecologists who would like to learn more about how stable isotope analyses have been and can be used in ecosystem studies. We begin with an explanation of isotope terminology and fractionation, then summarize isotopic distributions in the C, N, and S biogeochemical cycles, and conclude with five case studies that show how stable isotope measurements can provide crucial information for ecosystem analysis. We restrict this review to studies of natural variations in C, N, and S isotopic abundances, cxcluding from consideration ~5N enrichment studies and hydrogen and oxygen isotope studies. Our focus on C, N, and S derives in part from our
5,234 citations
TL;DR: In this paper, a technique was developed in which bromine pentafluoride was used as a reagent for quantitative liberation of oxygen from oxides and silicates, and the results of isotopic analyses were compared with measurements made in other laboratories by other procedures.
2,636 citations
TL;DR: It is suggested that carbon-isotope analysis may be a useful tool in selection for improved water-use efficiency in breeding programmes for C3 species.
Abstract: Variation in carbon-isotope composition among and between wheat genotypes was correlated with variation in water-use efficiency in separate pot experiments conducted in spring-summer and in winter. In the main, winter experiment, the water-use efficiencies ranged from 2.0 to 3.7 mmolC/mol H2O (means of four replicates) while the corresponding isotope effects for leaf material ranged from 1.0225 to 1.0194. 13C was more abundant in grain than in leaves and stems. It is suggested that carbon-isotope analysis may be a useful tool in selection for improved water-use efficiency in breeding programmes for C3 species.
2,068 citations
TL;DR: In this paper, the authors present a mathematical model to predict the overall isotope discrimination in terms of diffusion, interconversion, incorporation, and respiration in C 3, C 4 and crassulacean acid metabolism (CAM) photosynthetic pathways.
2,065 citations
References
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TL;DR: In this paper, the temperature variation of the fractionation of oxygen in exchange reactions between dissolved carbonate and water and between calcite and water was calculated on theoretical grounds, and checked experimentally.
Abstract: The temperature variation of the fractionation of oxygen in exchange reactions between dissolved carbonate and water and between calcite and water and calculated on theoretical grounds, and checked experimentally. In the course of the experiments it was necessary to investigate several methods of decomposing calcium carbonate to carbon dioxide for mass spectrometer analysis. A method was developed for growing calcium carbonate from solution with the same isotopic composition as the carbonate shells of organisms produced at the same temperature from water of the same isotopic composition, and the results of these experiments at various temperatures are expressed in an equation relating the temperature of formation with the isotopic composition of the calcium carbonate and of the water.
3,579 citations
TL;DR: A number of marine water and fresh water samples were examined for the relative O18O16 ratio, and the variation of this ratio was determined to a precision of ± 1% as mentioned in this paper.
3,113 citations
2,181 citations
TL;DR: The relationship between temperature and O(18) content relative to that for a Cretaceous belemnite of the Pee Dee formation previously reported (Epstein, Buchsbaum, Lowenstam, and Urey, 1951) has been re-determined using modified procedures for removing organic matter from shells, and is found to be 16.5 - 4.3 δ + 0.14 δ^2
Abstract: The relationship between temperature and O^(18) content relative to that for a Cretaceous belemnite of the Pee Dee formation previously reported (Epstein, Buchsbaum, Lowenstam, and Urey, 1951) has been re-determined using modified procedures for removing organic matter from shells, and is found to be
t(°C) = 16.5 - 4.3δ + 0.14δ^2
where δ is the difference in per mil of the O^(18) to O^(16) ratio between the sample and reference gas. The new relationship agrees with that determined by McCrea (1950) for inorganically precipitated calcium carbonate. Carbonate-carbon dioxide exchange experiments were done to determine the direct and indirect effects of organic matter in the shell on the mass spectrometer analyses.
2,109 citations
TL;DR: A survey of the variation of the ratio C13/C12 in nature can be found in this paper, where Urey and his co-workers used two complete feed systems with magnetic switching to determine small differences in isotope ratios between samples and a standard gas.
1,779 citations