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Issues and challenges facing rechargeable lithium batteries
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TLDR
A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.Abstract:
Technological improvements in rechargeable solid-state batteries are being driven by an ever-increasing demand for portable electronic devices. Lithium-ion batteries are the systems of choice, offering high energy density, flexible and lightweight design, and longer lifespan than comparable battery technologies. We present a brief historical review of the development of lithium-based rechargeable batteries, highlight ongoing research strategies, and discuss the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems.read more
Citations
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Materials for electrochemical capacitors
TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
Journal ArticleDOI
Electrical Energy Storage for the Grid: A Battery of Choices
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
Journal ArticleDOI
Nanostructured materials for advanced energy conversion and storage devices
Antonino S. Aricò,Peter G. Bruce,Bruno Scrosati,Jean-Marie Tarascon,Jean-Marie Tarascon,Walter van Schalkwijk +5 more
TL;DR: This review describes some recent developments in the discovery of nanoelectrolytes and nanoeLECTrodes for lithium batteries, fuel cells and supercapacitors and the advantages and disadvantages of the nanoscale in materials design for such devices.
Journal ArticleDOI
Li-O2 and Li-S batteries with high energy storage.
Peter G. Bruce,Stefan Freunberger,Laurence J. Hardwick,Laurence J. Hardwick,Jean-Marie Tarascon +4 more
TL;DR: The energy that can be stored in Li-air and Li-S cells is compared with Li-ion; the operation of the cells is discussed, as are the significant hurdles that will have to be overcome if such batteries are to succeed.
Journal ArticleDOI
Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
References
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Li{sub x}Cu{sub 6}Sn{sub 5} (0
TL;DR: In this article, it was shown that lithium can be inserted into the intermetallic compound Cu{sub 6}Sn{sub 5} in a two-phase reaction to yield the product Li{sub x}Cu³ 6µSnµµ·sub 5µ (x{approx}13) with a capacity of 358 mAh/g for x{sub max}=13.
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Novel LiNi1 − x Ti x / 2Mg x / 2 O 2 Compounds as Cathode Materials for Safer Lithium‐Ion Batteries
TL;DR: In this paper, a new class of materials has been synthesized, which showed a reversible capacity of and stable cycling, and differential scanning calorimetry studies showed much improved thermal stability of these materials in their totally charged states in contact with electrolyte.
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Topochemical reactions of rutile related structures with lithium
TL;DR: In this paper, the topochemical lithiation of rutile related MO 2 with n-BuLi and in nonaqueous lithium electrochemical cells is reported, which illustrates the importance of electronic conductivity and cell volume to substantial lithium incorporation.
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The elevated temperature performance of the LiMn2O4/C system: Failure and solutions
TL;DR: In this paper, a review of chemical approaches that have participated in the improvement of the high temperature performance of the LiMn2O4/C Li-ion system is presented.