Journal ArticleDOI
Kinetics of oxidation of dimethyl sulphoxide by tervalent manganese
N. Ganga Devi,V. Mahadevan +1 more
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In this paper, the reversible formation of a radical ion from Me2SO on oxidation by Mn3+, which initiates polymerisation of acrylonitrile that is terminated by the oxidant, is presented.Abstract:
Kinetic evidence is presented for the reversible formation of a radical ion from Me2SO on oxidation by Mn3+, which initiates polymerisation of acrylonitrile that is terminated by the oxidant.read more
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Book ChapterDOI
The Coordination Chemistry of Sulfoxides with Transition Metals
TL;DR: A review of the inorganic chemistry of sulfoxides can be found in this paper, with a focus on the chemistry of dimethyl sulfoxide and its coordination with soft metals.
Journal ArticleDOI
Sulfur-organic Initiators Applied to Radical Polymerization
Yu. I. Puzin,G. V. Leplyanin +1 more
TL;DR: The involvement of different sulfur-organic compounds in the initiation of radical polymerizations has been considered in this article, where various sulfur-containing peroxides as well as thioacetals and thioketals have been chosen to illustrate the effect of sulfur upon the homolytic fission of different bonds such as C-O, O-O and C-C. Numerous examples have been considered for the application of sulfur-Organic compounds as components in redox systems, wherein the radicals initiating the polymerization are generated by oxidation or reduction of the sulfurcontaining compounds
Journal ArticleDOI
Polymerization of Methyl Methacrylate by Mn(lll) Acetate/Ethylene Glycol Redox System in Acetic-Sulfuric Acid Mixture
TL;DR: A kinetic study of the thermal polymerization of methyl methacrylate initiated by the Mn(III) acetate/ethylene glycol redox system in sulfuric acid and acetic acid was made in the temperature range of 40 to 50°C under nitrogen atmosphere as discussed by the authors.
Book ChapterDOI
Complexes with Ligands Containing Sulfur
TL;DR: For correlation purposes, several complexes with sulfur ligands have already been described in the “Manganese” D series, e.g., complexes with thiosemicarbazones, thiocarbazates, or Thiocarbazones in this article.
Journal ArticleDOI
Vinyl polymerization with metal ion redox systems as initiators, manganic laurate—thiol system
TL;DR: In this article, the authors studied the polymerization of methyl methacrylate using manganic laurate in the presence of organic thiols as initiators and suggested a reaction scheme.
Related Papers (5)
Redox polymerization of acrylonitrile‐kinetics of the reaction initiated by the redox system dimethyl sulfoxide–Mn(III)
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