Journal ArticleDOI
Late transition metal-catalyzed hydroamination and hydroamidation.
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This article is published in Chemical Reviews.The article was published on 2015-02-27. It has received 775 citations till now. The article focuses on the topics: Hydroamination.read more
Citations
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Electrochemical strategies for C-H functionalization and C-N bond formation.
TL;DR: This review provides an overview on the use of anodic electrochemical methods for expediting the development of carbon-hydrogen functionalization and carbon-nitrogen bond formation strategies and aims to provide inspiration for future synthetic applications in the field of electrosynthesis.
Journal ArticleDOI
Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes.
Saravanakumar Elangovan,Jacob Neumann,Jean-Baptiste Sortais,Kathrin Junge,Christophe Darcel,Matthias Beller +5 more
TL;DR: It is shown that the selective N-alkylation of amines with alcohols can be catalysed by defined PNP manganese pincer complexes and the chemoselective monomethylations of primary amines using methanol under mild conditions are reported.
Journal ArticleDOI
Copper Hydride Catalyzed Hydroamination of Alkenes and Alkynes
TL;DR: The background, advances, and mechanistic investigations in CuH-catalyzed hydroamination are detailed.
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New Strategies for the Transition-Metal Catalyzed Synthesis of Aliphatic Amines.
TL;DR: This review aims to provide a concise overview of modern transition-metal catalyzed approaches to alkylamine synthesis and their functionalization.
Journal ArticleDOI
Homogeneous Catalysis by Cobalt and Manganese Pincer Complexes
Arup Mukherjee,David Milstein +1 more
TL;DR: In this paper, a review of recent progress in the field of homogeneously catalyzed reactions using pincer-type complexes of cobalt and manganese is presented, including acceptorless dehydrogenation, hydrogenation, dehydrogenative coupling, hydrogen borrowing, hydrogen transfer, H-X additions, C-C coupling, alkene polymerization and N2 fixation.
References
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Equilibrium Acidities in Dimethyl Sulfoxide Solution
TL;DR: The first acidity scale to be established in a pure solvent other than water was the result of the pioneering work of Conant, Wheland, and McEwen in ether or ben~ene.
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New Chiral Phosphorus Ligands for Enantioselective Hydrogenation
Wenjun Tang,Xumu Zhang +1 more
TL;DR: The increasing demand to produce enantiomerically pure pharmaceuticals, agrochemicals, flavors, and other fine chemicals has advanced the field of asymmetric catalytic technologies, and asymmetric hydrogenation utilizing molecular hydrogen to reduce prochiral olefins, ketones, and imines has become one of the most efficient methods for constructing chiral compounds.
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C–C, C–O and C–N bond formation via rhodium(III)-catalyzed oxidative C–H activation
Guoyong Song,Fen Wang,Xingwei Li +2 more
TL;DR: The facile construction of C-E (E = C, N, S, or O) bonds makes Rh(III) catalysis an attractive step-economic approach to value-added molecules from readily available starting materials.
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Practical methodologies for the synthesis of indoles.
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Hydroamination: direct addition of amines to alkenes and alkynes.
TL;DR: Hydroamination of Alkenes and Alkynes under Microwave Irradiation and Nitromercuration Reactions 3878 9.8.4.5.