Journal ArticleDOI
Light-Converting Molecular Devices: Energy-Transfer Processes in Lanthanide Dinuclear Complexes
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In this paper, the design of efficient light-converting molecular devices containing a lanthanide ion is discussed, and two series of model dinuclear complexes are studied: coordination compounds with calixarenes and self-assembled triple helical complexes based on aromatics polyanimes.Abstract:
The design of efficient light-converting molecular devices containing a lanthanide ion is discussed. In order to unravel the energy transfer processes taking place in such a device, two series of model dinuclear complexes are studied : coordination compounds with calixarenes and self-assembled triple helical complexes based on aromatics polyanimes.read more
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Journal ArticleDOI
Thermodynamics, Structure and Properties of Polynuclear Lanthanide Complexes with a Tripodal Ligand: Insight into their Self‐Assembly
TL;DR: Self-assembly processes between a tripodal ligand and Ln(III) cations have been investigated by means of supramolecular analytical methods and these rather complicated equilibria were successfully characterised with the thermodynamic stability constants.
Journal ArticleDOI
Towards materials with planned properties: dinuclear f-f helicates and d-f non-covalent podates based on benzimidazole-pyridine binding units
TL;DR: In this paper, the influence of various substituents on the stability and quantum yield of the non-covalent edifices is discussed, and it is demonstrated that replacement of one benzimidazole moiety by a carboxamide group enhances considerably the luminescent properties of the supramolecular light-converting devices.
Journal ArticleDOI
Evidencing a reaction intermediate in the formation of the EuIII bimetallic complex with p-tert-butylcalix[8]arene
TL;DR: Several spectroscopic and conductometric techniques are combined with variable-temperature and variable-pressure experiments to demonstrate that in absence of base, intermediate A is the cationic species [Eu(b-LH6)(dmf)4]+.
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