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Liquid-phase chemical hydrogen storage materials
Mahendra Yadav,Qiang Xu +1 more
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In this paper, the authors survey the research progress in hydrogen generation from liquid-phase chemical hydrogen storage materials and their regeneration, and present a review of these materials in hydrogen storage.Abstract:
In the search for future energy supplies, the application of hydrogen as an energy carrier is seen as a prospective issue. However, the implementation of a hydrogen economy is suffering from several unsolved problems. Particularly challenging is the storage of appropriate amounts of hydrogen. In this context one of the promising hydrogen storage techniques relies on liquid-phase chemical hydrogen storage materials, in particular, aqueous sodium borohydride, ammonia borane, hydrazine, hydrazine borane and formic acid. The use of these materials in hydrogen storage provides high gravimetric and volumetric hydrogen densities, low potential risk, and low capital investment because it is largely compatible with the current transport infrastructure. In this review, we survey the research progresses in hydrogen generation from these liquid-phase chemical hydrogen storage materials and their regeneration.read more
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Metal–organic framework composites
Qi-Long Zhu,Qiang Xu +1 more
TL;DR: This review provides an overview of the significant advances in the development of diverse MOF composites reported till now with special emphases on the synergistic effects and applications of the composites.
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Complex Hydrides for Hydrogen Storage
Yuko Nakamori,Orimo Shin-ichi +1 more
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Metal–organic frameworks as platforms for clean energy
Shun-Li Li,Qiang Xu +1 more
TL;DR: In this paper, a review of recent and significant advances in the development of metal-organic frameworks for clean energy applications are reviewed, and special emphases are shown to the applications of MOFs as platforms for hydrogen production and storage, fuel cells, Li-ion rechargeable batteries, supercapacitors and solar cells.
Journal ArticleDOI
Liquid organic and inorganic chemical hydrides for high-capacity hydrogen storage
Qi-Long Zhu,Qiang Xu +1 more
TL;DR: A review of the research progress in the development of diverse liquid-phase chemical hydrogen storage materials, including organic and inorganic chemical hydrides, with emphases on the syntheses of active catalysts for catalytic hydrogen generation and storage is presented in this paper.
Journal ArticleDOI
Immobilizing Metal Nanoparticles to Metal–Organic Frameworks with Size and Location Control for Optimizing Catalytic Performance
TL;DR: The uniform 3D distribution of the ultrafine AuNi nanoparticles encapsulated in the pores of MIL-101 was achieved, as demonstrated by TEM and electron tomographic measurements, which brings light to new opportunities in the fabrication of ultrafine non-noble metal-based NPs throughout the interior pores of MOFs.
References
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Journal ArticleDOI
Hydrogen-storage materials for mobile applications
TL;DR: Recent developments in the search for innovative materials with high hydrogen-storage capacity are presented.
Journal ArticleDOI
Hydrogen Storage in Microporous Metal-Organic Frameworks
Nathaniel L. Rosi,Juergen Eckert,Mohamed Eddaoudi,David T. Vodak,Jaheon Kim,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Inelastic neutron scattering spectroscopy of the rotational transitions of the adsorbed hydrogen molecules indicates the presence of two well-defined binding sites (termed I and II), which are associated with hydrogen binding to zinc and the BDC linker, respectively.
Journal ArticleDOI
Nanoalloys: From Theory to Applications of Alloy Clusters and Nanoparticles
TL;DR: Nanoalloys of Group 11 (Cu, Ag, Au) 865 5.1.5.2.
Journal ArticleDOI
Photoelectrocatalytic reduction of carbon dioxide in aqueous suspensions of semiconductor powders
TL;DR: In this paper, the photoelectrocatalytic reduction of carbon dioxide to form organic compounds such as formic acid, formaldeyde, methyl alcohol and methane, in the presence of photosensitive semiconductor powders suspended in water as catalysts, is described.
Journal ArticleDOI
Complex hydrides for hydrogen storage.
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