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Journal ArticleDOI

Measurement of forces between two mica surfaces in aqueous electrolyte solutions in the range 0–100 nm

01 Jan 1978-Journal of the Chemical Society, Faraday Transactions (The Royal Society of Chemistry)-Vol. 74, pp 975-1001
TL;DR: The main results and conclusions of experimental measurements of the forces between molecularly smooth mica surfaces in aqueous electrolyte solutions are as follows: as mentioned in this paper, and they are based on the following assumptions:
Abstract: The main results and conclusions of experimental measurements of the forces between molecularly smooth mica surfaces in aqueous electrolyte solutions are as follows:
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Journal ArticleDOI
01 Sep 1991-Nature
TL;DR: In this article, the authors used the atomic force microscope to measure the forces between a planar surface and an individual colloid particle, a silica sphere of radius 3.5 µm, attached to the force sensor in the microscope and measured in solutions of sodium chloride.
Abstract: THE forces between colloidal particles dominate the behaviour of a great variety of materials, including paints, paper, soil, clays and (in some circumstances) cells. Here we describe the use of the atomic force microscope to measure directly the force between a planar surface and an individual colloid particle. The particle, a silica sphere of radius 3.5 µm, was attached to the force sensor in the microscope and the force between the particle and the surface was measured in solutions of sodium chloride. The measurements are consistent with the double-layer theory1,2 of colloidal forces, although at very short distances there are deviations that may be attributed to hydration forces3–6 or surface roughness, and with previous studies on macroscopic systems4–6. Similar measurements should be possible for a wide range of the particulate and fibrous materials that are often encountered in industrial contexts, provided that they can be attached to the microscope probe.

1,900 citations

Journal ArticleDOI
TL;DR: The spring constant of microfabricated cantilevers used in scanning force microscopy (SFM) can be determined by measuring their resonant frequencies before and after adding small end masses as mentioned in this paper.
Abstract: The spring constant of microfabricated cantilevers used in scanning force microscopy (SFM) can be determined by measuring their resonant frequencies before and after adding small end masses These masses adhere naturally and can be easily removed before using the cantilever for SFM, making the method nondestructive The observed variability in spring constant—almost an order of magnitude for a single type of cantilever—necessitates calibration of individual cantilevers in work where precise knowledge of forces is required Measurements also revealed that the spring constant scales with the cube of the unloaded resonant frequency, providing a simple way to estimate the spring constant for less precise work

1,635 citations

Journal ArticleDOI
TL;DR: It is found that solvent properties of water within the interphase separating a solid surface from bulk water solution vary with contacting surface chemistry, and this interphase can extend tens of nanometers from a water-contacting surface due to a propagation of differences in self association between vicinal water and bulk-phase water.

1,396 citations

Journal ArticleDOI
TL;DR: In this article, a review of colloidal processing of ceramics is presented with an emphasis on interparticle forces, suspension rheology, consolidation techniques, and drying behavior.
Abstract: Colloidal processing of ceramics is reviewed with an emphasis on interparticle forces, suspension rheology, consolidation techniques, and drying behavior. Particular attention is given to the scientific concepts that underpin the fabrication of particulate-derived ceramic components. The complex interplay between suspension stability and its structural evolution during colloidal processing is highlighted.

1,211 citations

Journal ArticleDOI
TL;DR: In this paper, the authors present theories describing colloid mobilization, deposition, and transport, laboratory experiments in model systems designed to test these theories, and applications of these theories to colloid-facilitated transport experiments in natural groundwater systems.

1,145 citations