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Journal ArticleDOI

Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene

Changgu Lee, +4 more
- 18 Jul 2008 - 
- Vol. 321, Iss: 5887, pp 385-388
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TLDR
Graphene is established as the strongest material ever measured, and atomically perfect nanoscale materials can be mechanically tested to deformations well beyond the linear regime.
Abstract
We measured the elastic properties and intrinsic breaking strength of free-standing monolayer graphene membranes by nanoindentation in an atomic force microscope. The force-displacement behavior is interpreted within a framework of nonlinear elastic stress-strain response, and yields second- and third-order elastic stiffnesses of 340 newtons per meter (N m(-1)) and -690 Nm(-1), respectively. The breaking strength is 42 N m(-1) and represents the intrinsic strength of a defect-free sheet. These quantities correspond to a Young's modulus of E = 1.0 terapascals, third-order elastic stiffness of D = -2.0 terapascals, and intrinsic strength of sigma(int) = 130 gigapascals for bulk graphite. These experiments establish graphene as the strongest material ever measured, and show that atomically perfect nanoscale materials can be mechanically tested to deformations well beyond the linear regime.

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Journal ArticleDOI

Infrared Imaging and Spectroscopy Beyond the Diffraction Limit

TL;DR: This review presents some basics of infrared spectroscopy and microscopy, followed by detailed descriptions of s-SNOM and PTIR working principles, and compares far-field macroscale spectra, which are widely used for chemical identification.
Journal Article

The macroscopic delamination of thin films from elastic substrates

TL;DR: In this paper, the authors performed well-controlled experiments at macroscopic scales to study what sets the dimensions of these blisters in terms of the material properties and explain their results by using a combination of scaling and analytical methods.
Journal ArticleDOI

Layer‐Number Dependent Optical Properties of 2D Materials and Their Application for Thickness Determination

TL;DR: In this article, the authors reviewed how optical properties of typical 2D materials (e.g., monolayer and multilayer graphenes, transition metal dichalcogenides) probed by these optical techniques significantly depend on the layer number (N).
Journal ArticleDOI

Preparation and tribological properties of TiAl matrix composites reinforced by multilayer graphene

TL;DR: In this paper, the authors report on preparation technique and tribological properties of multilayer graphene reinforced TiAl matrix composites (GTMC). GTMC are successfully prepared by spark plasma sintering (SPS) using Raman spectroscopy and field emission scanning electron microscopy, which indicates that MLG homogeneously distributes in GTMC.
Journal ArticleDOI

Popgraphene: a new 2D planar carbon allotrope composed of 5–8–5 carbon rings for high-performance lithium-ion battery anodes from bottom-up programming

TL;DR: In this article, a 2D planar carbon allotrope, popgraphene, was constructed via the formation of atomically precise 5-8-5 line defects in graphene by simultaneous electron irradiation.
References
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Journal ArticleDOI

Raman spectrum of graphene and graphene layers.

TL;DR: This work shows that graphene's electronic structure is captured in its Raman spectrum that clearly evolves with the number of layers, and allows unambiguous, high-throughput, nondestructive identification of graphene layers, which is critically lacking in this emerging research area.
Journal ArticleDOI

Two-dimensional atomic crystals

TL;DR: By using micromechanical cleavage, a variety of 2D crystals including single layers of boron nitride, graphite, several dichalcogenides, and complex oxides are prepared and studied.
Journal ArticleDOI

The Phenomena of Rupture and Flow in Solids

TL;DR: In this article, the authors investigated the effect of surface scratches on the mechanical strength of solids, and some general conclusions were reached which appear to have a direct bearing on the problem of rupture, from an engineering standpoint, and also on the larger question of the nature of intermolecular cohesion.
Book

Physical properties of crystals

John F. Nye
TL;DR: In this paper, the physical properties of crystals systematically in tensor notation are presented, presenting tensor properties in terms of their common mathematical basis and the thermodynamic relations between them.
Journal ArticleDOI

Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load

TL;DR: The tensile strengths of individual multiwalled carbon nanotubes (MWCNTs) were measured with a "nanostressing stage" located within a scanning electron microscope and a variety of structures were revealed, such as a nanotube ribbon, a wave pattern, and partial radial collapse.
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