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Metal–biomolecule frameworks (MBioFs)

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TLDR
This feature article highlights the advances in the synthesis of Metal-Biomolecule Frameworks (MBioFs), with special emphasis on the crystal structures of these materials, their miniaturization to the submicron length scale, and their new potential storage, catalytic, and biomedical applications.
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This article is published in Chemical Communications.The article was published on 2011-06-21. It has received 351 citations till now.

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Journal ArticleDOI

Metal-organic frameworks in biomedicine.

TL;DR: Metal Organic Frameworks in Biomedicine Patricia Horcajada, Ruxandra Gref, Tarek Baati, Phoebe K. Allan, Guillaume Maurin, Patrick Couvreur, G erard F erey, Russell E. Morris, and Christian Serre.
Journal ArticleDOI

Metal–organic frameworks based on flexible ligands (FL-MOFs): structures and applications

TL;DR: In this review, emphasis has been placed on the design and the structural diversity of FL-MOFs and dynamic frameworks induced by flexible ligands are briefly outlined.
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Metal–organic framework growth at functional interfaces: thin films and composites for diverse applications

TL;DR: This review provides an overview of the diverse MOF composite materials prepared up to now, organised by interface type and while the overall emphasis is on applications of the composites, coatings and MOF-based devices, the most widely-used and successful synthetic strategies for composite formation are presented.
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Proton-conducting crystalline porous materials

TL;DR: This review summarizes the emerging studies of metal-organic frameworks, coordination polymers, polyoxometalates and covalent organic frameworks and their unique proton conductivities.
References
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Journal ArticleDOI

Reticular synthesis and the design of new materials

TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
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Selective gas adsorption and separation in metal–organic frameworks

TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Hybrid porous solids: past, present, future

TL;DR: The state-of-the-art on hybrid porous solids, their advantages, their new routes of synthesis, the structural concepts useful for their 'design', aiming at reaching very large pores are presented.
Journal ArticleDOI

Luminescent Metal–Organic Frameworks

TL;DR: This critical review discusses the origins of MOF luminosity, which include the linker, the coordinated metal ions, antenna effects, excimer and exciplex formation, and guest molecules.
Journal ArticleDOI

Porous metal–organic-framework nanoscale carriers as a potential platform for drug delivery and imaging

TL;DR: It is shown that specific non-toxic porous iron(III)-based metal-organic frameworks with engineered cores and surfaces, as well as imaging properties, function as superior nanocarriers for efficient controlled delivery of challenging antitumoural and retroviral drugs against cancer and AIDS.
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