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Journal ArticleDOI

MOFs-Derived Hollow Co/C Microspheres with Enhanced Microwave Absorption Performance

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TLDR
In this paper, the pyrolysis temperature plays an important role in determining the electromagnetic properties of these hollow Co/C microspheres, where high pyrolysis temperature will increase relative complex permittivity and decrease relative complex permeability.
Abstract
Rational construction of a profitable microstructure in carbon-based electromagnetic composites is becoming a promising strategy to reinforce their microwave absorption performance. Herein, the microstructure design is innovatively coupled with a metal–organic frameworks (MOFs)-derived method to produce hollow Co/C microspheres (Co/C-HS). The resultant composites combine the advantages of hollow microstructures and good chemical homogeneity. It is found that the pyrolysis temperature plays an important role in determining the electromagnetic properties of these hollow Co/C microspheres, where high pyrolysis temperature will increase relative complex permittivity and decrease relative complex permeability. When the pyrolysis temperature is 600 °C, the sample (Co/C-HS-600) will show improved impedance matching and good attenuation ability, and thus an excellent microwave absorption performance with strong reflection loss (−66.5 dB at 17.6 GHz) and wide response bandwidth (over −10 dB, 3.7–18.0 GHz) can be a...

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Citations
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Journal ArticleDOI

Achieving superior electromagnetic wave absorbers through the novel metal-organic frameworks derived magnetic porous carbon nanorods

TL;DR: In this article, a rod-shape composites with Fe-containing magnetic nanoparticles (Fe3O4, Fe3C and Fe NPs) embedded into nano-porous carbon (NPC) through pyrolysis of Fe-based metal-organic frameworks (MOFs).
Journal ArticleDOI

Review on the electromagnetic interference shielding properties of carbon based materials and their novel composites: Recent progress, challenges and prospects

TL;DR: In this paper, a review of recent achievements for carbon materials with different microstructures as electromagnetic interference shielding materials (ESMs) and microwave absorption materials (MAMs) during the past five years is presented.
Journal ArticleDOI

Hollow porous CoNi/C composite nanomaterials derived from MOFs for efficient and lightweight electromagnetic wave absorber

TL;DR: In this article, a novel lightweight electromagnetic wave absorption material with the combination of hollow structure and bimetallic constituents by the thermal decomposition of metal−organic framework (MOF) ZIF-67 was designed and prepared.
Journal ArticleDOI

Core-shell FeCo@carbon nanoparticles encapsulated in polydopamine-derived carbon nanocages for efficient microwave absorption

TL;DR: In this paper, the authors used dopamine (DA) on their surface and then converted the precursor into desirable FeCo alloy/carbon composites to suppress the microstructure collapse of FeCo PBAs during high-temperature pyrolysis, resulting in a unique hierarchical configuration of coreshell FeCo@C nanoparticles encapsulated in PDA-derived carbon nanocages.
References
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Journal ArticleDOI

Interpretation of Raman spectra of disordered and amorphous carbon

TL;DR: In this paper, a model and theoretical understanding of the Raman spectra in disordered and amorphous carbon is given, and the nature of the G and D vibration modes in graphite is analyzed in terms of the resonant excitation of \ensuremath{\pi} states and the long-range polarizability of the long range bonding.
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First- and second-order Raman scattering from finite-size crystals of graphite

TL;DR: In this article, the second-order Raman spectrum of pyrolytic graphite has been studied and the dependence of the first-order graphite Raman spectra on crystallite size has been shown.
Journal ArticleDOI

Broadband and Tunable High‐Performance Microwave Absorption of an Ultralight and Highly Compressible Graphene Foam

TL;DR: The broadband and tunable high-performance microwave absorption properties of an ultralight and highly compressible graphene foam (GF) are investigated and it is shown that via physical compression, the microwave absorption performance can be tuned.
Journal ArticleDOI

Magnetic Properties of Nanostructured Materials

TL;DR: In this paper, a classification of nanostructure morphology according to the mechanism responsible for the magnetic properties is presented, followed by a brief discussion of some promising experimental techniques in synthesis and measurements.
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