Molecular imprinting science and technology: a survey of the literature for the years 2004-2011.
TL;DR: A survey of the literature covering the development of molecular imprinting science and technology over the years 2004–2011 and efforts to apply these polymeric materials to a range of application areas is presented.
Abstract: Herein, we present a survey of the literature covering the development of molecular imprinting science and technology over the years 2004-2011. In total, 3779 references to the original papers, rev ...
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01 Jan 2007
TL;DR: The Third edition of the Kirk-Othmer encyclopedia of chemical technology as mentioned in this paper was published in 1989, with the title "Kirk's Encyclopedia of Chemical Technology: Chemical Technology".
Abstract: 介绍了Kirk—Othmer Encyclopedia of Chemical Technology（化工技术百科全书）（第五版）电子图书网络版数据库，并对该数据库使用方法和检索途径作出了说明，且结合实例简单地介绍了该数据库的检索方法。
2,666 citations
TL;DR: This work proposes to comprehensively review the recent advances in molecular imprinting including versatile perspectives and applications, concerning novel preparation technologies and strategies of MIT, and highlight the applications of MIPs.
Abstract: Molecular imprinting technology (MIT), often described as a method of making a molecular lock to match a molecular key, is a technique for the creation of molecularly imprinted polymers (MIPs) with tailor-made binding sites complementary to the template molecules in shape, size and functional groups. Owing to their unique features of structure predictability, recognition specificity and application universality, MIPs have found a wide range of applications in various fields. Herein, we propose to comprehensively review the recent advances in molecular imprinting including versatile perspectives and applications, concerning novel preparation technologies and strategies of MIT, and highlight the applications of MIPs. The fundamentals of MIPs involving essential elements, preparation procedures and characterization methods are briefly outlined. Smart MIT for MIPs is especially highlighted including ingenious MIT (surface imprinting, nanoimprinting, etc.), special strategies of MIT (dummy imprinting, segment imprinting, etc.) and stimuli-responsive MIT (single/dual/multi-responsive technology). By virtue of smart MIT, new formatted MIPs gain popularity for versatile applications, including sample pretreatment/chromatographic separation (solid phase extraction, monolithic column chromatography, etc.) and chemical/biological sensing (electrochemical sensing, fluorescence sensing, etc.). Finally, we propose the remaining challenges and future perspectives to accelerate the development of MIT, and to utilize it for further developing versatile MIPs with a wide range of applications (650 references).
1,647 citations
TL;DR: This work is reviewing the numerous applications of molecularly imprinted polymer (MIP) nanoparticles (NPs) and briefly discuss their synthesis, and critically discusses limitations and applications specific problems.
Abstract: Artificial receptors exhibit several advantages compared to their biological counterparts such as stability, robustness and handling. Additionally, nanostructured materials exhibit excellent properties such as high surfaceto-volume ratio, low cost and easy preparation and handling. Consequently, the approach of molecularly imprinting has been extended from bulk materials to nanomaterials. We are reviewing the numerous applications of molecularly imprinted polymer (MIP) nanoparticles (NPs) and briefly discuss their synthesis. Furthermore, we discuss how and for which applications industry starts to use MIP NPs and what the current limitations are. MIP NPs can be applied as antibody replicae economizing template molecules and facilitating storage. Moreover, nanocomposite materials possess additional functionalities such as magnetic and semi-conductive cores. Nanosized MIPs are widespread applied for analytical separation via solid phase extraction (SPE), but also improves sensitivity in capillary electrophoresis (CE). Furthermore, such nanomaterials are applied in the field of sensors, e.g. in combination with transducers such as surface-enhanced Raman scattering (SERS). MIP grafted optosensing materials, namely quantum dot (QD) composites, even allow for fluorescence detection of non-fluorescing analytes. Nevertheless, MIP NPs are also suitable for bio-applications such as drug delivery and pseudoimmunoassay. Finally, we critically discuss limitations and applications specific problems.
289 citations
TL;DR: This review summarizes recent advances in the synthesis, assembly, and applications of nanoengineered reporting and transducing components critical for efficient biosensing, and envision the exciting potential of high-performance nanomaterials that will cause disruptive improvements in the field of biosensing.
Abstract: The robust, sensitive, and selective detection of targeted biomolecules in their native environment by prospective nanostructures holds much promise for real-time, accurate, and high throughput biosensing. However, in order to be competitive, current biosensor nanotechnologies need significant improvements, especially in specificity, integration, throughput rate, and long-term stability in complex bioenvironments. Advancing biosensing nanotechnologies in chemically “noisy” bioenvironments require careful engineering of nanoscale components that are highly sensitive, biorecognition ligands that are capable of exquisite selective binding, and seamless integration at a level current devices have yet to achieve. This review summarizes recent advances in the synthesis, assembly, and applications of nanoengineered reporting and transducing components critical for efficient biosensing. First, major classes of nanostructured components, both inorganic reporters and organic transducers, are discussed in the contex...
242 citations
TL;DR: Ion imprinting technology (IIT) aims to recognize ions while retaining the unique virtues of molecular imprinting (MIT), namely structure predictability, recognition specificity and application universality as mentioned in this paper.
Abstract: Ion imprinting technology (IIT) aims to recognize ions while retaining the unique virtues of molecular imprinting technology (MIT), namely structure predictability, recognition specificity and application universality. Owing to special coordination or electrostatic interactions, ion imprinted polymers (IIPs) are generally compatible with aqueous media and have advantages over most molecularly imprinted polymers (MIPs). IIPs can achieve effective identification of water-soluble ions, especially heavy metals and radioactive elements that cause increasing concerns. The purpose of this review is to summarize recent advances of ion imprinting, focusing on the current status and challenges in fundamentals and applications that involve almost all types of ions and ion-related molecular imprinting. In addition, various smart strategies are highlighted, such as surface imprinting, stimuli-responsive imprinting, dual/multiple components imprinting, click chemistry, and microwave-assisted heating. In this review, the elemental periodic table is first utilized as a template to introduce ion classification standards for various IIPs, including main groups, transition elements, actinides, rare earths, metalloids, anion imprinting and secondary imprinting. Finally, the challenges and possible solution strategies plus future trends are also proposed (302 references).
223 citations
References
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01 Jan 2007
TL;DR: The Third edition of the Kirk-Othmer encyclopedia of chemical technology as mentioned in this paper was published in 1989, with the title "Kirk's Encyclopedia of Chemical Technology: Chemical Technology".
Abstract: 介绍了Kirk—Othmer Encyclopedia of Chemical Technology（化工技术百科全书）（第五版）电子图书网络版数据库，并对该数据库使用方法和检索途径作出了说明，且结合实例简单地介绍了该数据库的检索方法。
2,666 citations
TL;DR: The diverse examples show that in recent years organocatalysis has developed within organic chemistry into its own subdiscipline, whose "Golden Age" has already dawned.
Abstract: The term "organocatalysis" describes the acceleration of chemical reactions through the addition of a substoichiometric quantity of an organic compound. The interest in this field has increased spectacularly in the last few years as result of both the novelty of the concept and, more importantly, the fact that the efficiency and selectivity of many organocatalytic reactions meet the standards of established organic reactions. Organocatalytic reactions are becoming powerful tools in the construction of complex molecular skeletons. The diverse examples show that in recent years organocatalysis has developed within organic chemistry into its own subdiscipline, whose "Golden Age" has already dawned.
2,279 citations
"Molecular imprinting science and te..." refers background in this paper
...The increasing incidence of molecular imprinting related material in reviews from other fields indicates that molecular imprinting science and technology has established itself within the broader scientific community.(215-501) Similar trends are observed in the cases of multi-authored monographs and general scientific reference works....
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TL;DR: A comprehensive overview on the development of polymeric membranes having advanced or novel functions in the various membrane sepn processes for liq. and gaseous mixts can be found in this paper.
1,841 citations
"Molecular imprinting science and te..." refers background in this paper
...The increasing incidence of molecular imprinting related material in reviews from other fields indicates that molecular imprinting science and technology has established itself within the broader scientific community.(215-501) Similar trends are observed in the cases of multi-authored monographs and general scientific reference works....
[...]
TL;DR: This paper provides a summary of background information and methodologies used for the analysis of phenolics in foods and nutraceuticals.
1,490 citations