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Journal ArticleDOI

Molybdenum complexes with noninert-gas configuration

01 Nov 1970-Inorganic Chemistry (American Chemical Society)-Vol. 9, Iss: 11, pp 2493-2499
About: This article is published in Inorganic Chemistry.The article was published on 1970-11-01. It has received 79 citations till now. The article focuses on the topics: Molybdenum.
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TL;DR: In this article, it was shown that carbon-hydrogen bonds may act as ligands to transition metal centers forming covalent CH⇀M systems in which the H group donates two electrons to the metal.

1,098 citations

Journal ArticleDOI
TL;DR: The impact of agostic interactions (i.e., 3-center–2-electron MHC bonds) on the structures and reactivity of organotransition metal compounds is reviewed.
Abstract: The impact of agostic interactions (i.e., 3-center-2-electron M-H-C bonds) on the structures and reactivity of organotransition metal compounds is reviewed.

878 citations