Morphological characterization and applications of phase change materials in thermal energy storage: A review
TL;DR: In this article, morphological characterization of the composite phase change material (CPCM) is presented from perspective of three kinds of morphologies (fiber, porosity and sphere).
Abstract: Phase change material (PCM), stores and releases heat at a particular required temperature as it undergoes phase change at that temperature. Because of their large latent heat and constant temperature during the phase change process, the PCMs are extensively used in latent thermal energy storage system (LTES) and thermal management system (TM). Due to its virtue of competitive performance, PCM has been used extensively in heat recovery, solar energy, aerospace industry, buildings, textile industry etc. However, the PCM has limitations like low thermal conductivity and low heat transfer rate, which decrease the performance of LTES and TM systems. In this work, ways of improving thermal conductivity and heat transfer rate of the composite PCMs (CPCMs) are summarized from perspective of three kinds of CPCMs’ morphologies (fiber, porosity and sphere). This review paper presents morphological characterization of the CPCMs, and several fabrication methods of the CPCMs with enhanced thermal properties.
Citations
More filters
TL;DR: In this article, the authors focus on the application of various phase change materials based on their thermophysical properties, in particular, the melting point, thermal energy storage density and thermal conductivity of the organic, inorganic and eutectic phases.
813 citations
TL;DR: In this article, the authors reviewed the methods for enhancing thermal conductivity of phase change materials (PCMs), which include adding additives with high thermal conductivities and encapsulating phase change material.
Abstract: In recent years, energy conservation and environmental protection have become most important issues for humanity. Phase change materials (PCMs) for thermal energy storage can solve the issues of energy and environment to a certain extent, as PCMs can increase the efficiency and sustainability of energy. PCMs possess large latent heat, and they store and release energy at a constant temperature during the phase change process. Thereby PCMs have gained a wide range of applications in various fields, such as buildings, solar energy systems, power systems and military industry. However, low thermal conductivity of PCMs leads to low heat transfer rate, thus, numerous studies have been carried out to improve thermal conductivity of PCMs. The main purpose of this paper is to review the methods for enhancing thermal conductivity of PCMs, which include adding additives with high thermal conductivity and encapsulating phase change materials. It is found that addition of thermal conductivity enhancement fillers is a more effective method to improve thermal conductivity of PCMs, where carbon-based material additives possess a more promising application prospect. Finally, the applications of PCMs in solar energy system, buildings, cooling system, textiles and heat recovery system are also analyzed.
538 citations
TL;DR: In this article, the authors assess the advantages/disadvantages of porous materials via summarizing the key research progress on the porous materials (e.g., metal foams, expanded graphite, graphene aerogels, carbon nanotubes, porous minerals, mesoporous silica, etc.) as ss-PCMs supports.
415 citations
TL;DR: In this article, a review of inorganic phase change materials (PCMs) in thermal energy storage has been presented, focusing on the thermal properties of the inorganic PCMs.
272 citations
TL;DR: In this paper, a review of nanoporous shape-stabilized composite phase change materials (PCMs) for thermal energy storage is presented, highlighting the recent progress in the research of nanorefinite element nanopores, fabrication and characterization techniques, and especially the nanoconfinement effects of the porous support on the thermal properties of the PCMs confined in the nanopores.
242 citations
References
More filters
[...]
TL;DR: Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed-matter physics, where quantum relativistic phenomena can now be mimicked and tested in table-top experiments.
Abstract: Graphene is a rapidly rising star on the horizon of materials science and condensed-matter physics. This strictly two-dimensional material exhibits exceptionally high crystal and electronic quality, and, despite its short history, has already revealed a cornucopia of new physics and potential applications, which are briefly discussed here. Whereas one can be certain of the realness of applications only when commercial products appear, graphene no longer requires any further proof of its importance in terms of fundamental physics. Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed-matter physics, where quantum relativistic phenomena, some of which are unobservable in high-energy physics, can now be mimicked and tested in table-top experiments. More generally, graphene represents a conceptually new class of materials that are only one atom thick, and, on this basis, offers new inroads into low-dimensional physics that has never ceased to surprise and continues to provide a fertile ground for applications.
35,293 citations
TL;DR: The extremely high value of the thermal conductivity suggests that graphene can outperform carbon nanotubes in heat conduction and establishes graphene as an excellent material for thermal management.
Abstract: We report the measurement of the thermal conductivity of a suspended single-layer graphene. The room temperature values of the thermal conductivity in the range ∼(4.84 ± 0.44) × 103 to (5.30 ± 0.48) × 103 W/mK were extracted for a single-layer graphene from the dependence of the Raman G peak frequency on the excitation laser power and independently measured G peak temperature coefficient. The extremely high value of the thermal conductivity suggests that graphene can outperform carbon nanotubes in heat conduction. The superb thermal conduction property of graphene is beneficial for the proposed electronic applications and establishes graphene as an excellent material for thermal management.
11,878 citations
TL;DR: It is shown that the opacity of suspended graphene is defined solely by the fine structure constant, a = e2/hc � 1/137 (where c is the speed of light), the parameter that describes coupling between light and relativistic electrons and that is traditionally associated with quantum electrodynamics rather than materials science.
Abstract: There are few phenomena in condensed matter physics that are defined only by the fundamental constants and do not depend on material parameters. Examples are the resistivity quantum, h/e2 (h is Planck's constant and e the electron charge), that appears in a variety of transport experiments and the magnetic flux quantum, h/e, playing an important role in the physics of superconductivity. By and large, sophisticated facilities and special measurement conditions are required to observe any of these phenomena. We show that the opacity of suspended graphene is defined solely by the fine structure constant, a = e2/hc feminine 1/137 (where c is the speed of light), the parameter that describes coupling between light and relativistic electrons and that is traditionally associated with quantum electrodynamics rather than materials science. Despite being only one atom thick, graphene is found to absorb a significant (pa = 2.3%) fraction of incident white light, a consequence of graphene's unique electronic structure.
7,952 citations
TL;DR: The thermal properties of carbon materials are reviewed, focusing on recent results for graphene, carbon nanotubes and nanostructured carbon materials with different degrees of disorder, with special attention given to the unusual size dependence of heat conduction in two-dimensional crystals.
Abstract: Recent years have seen a rapid growth of interest by the scientific and engineering communities in the thermal properties of materials. Heat removal has become a crucial issue for continuing progress in the electronic industry, and thermal conduction in low-dimensional structures has revealed truly intriguing features. Carbon allotropes and their derivatives occupy a unique place in terms of their ability to conduct heat. The room-temperature thermal conductivity of carbon materials span an extraordinary large range--of over five orders of magnitude--from the lowest in amorphous carbons to the highest in graphene and carbon nanotubes. Here, I review the thermal properties of carbon materials focusing on recent results for graphene, carbon nanotubes and nanostructured carbon materials with different degrees of disorder. Special attention is given to the unusual size dependence of heat conduction in two-dimensional crystals and, specifically, in graphene. I also describe the prospects of applications of graphene and carbon materials for thermal management of electronics.
5,189 citations
TL;DR: The use of a latent heat storage system using phase change materials (PCMs) is an effective way of storing thermal energy and has the advantages of high energy storage density and the isothermal nature of the storage process.
Abstract: The use of a latent heat storage system using phase change materials (PCMs) is an effective way of storing thermal energy and has the advantages of high-energy storage density and the isothermal nature of the storage process. PCMs have been widely used in latent heat thermal-storage systems for heat pumps, solar engineering, and spacecraft thermal control applications. The uses of PCMs for heating and cooling applications for buildings have been investigated within the past decade. There are large numbers of PCMs that melt and solidify at a wide range of temperatures, making them attractive in a number of applications. This paper also summarizes the investigation and analysis of the available thermal energy storage systems incorporating PCMs for use in different applications.
4,482 citations