MoS2‐Based Nanomaterials for Room‐Temperature Gas Sensors
About: This article is published in Advanced materials and technologies.The article was published on 2020-05-01. It has received 105 citations till now. The article focuses on the topics: Nanomaterials.
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TL;DR: In this paper, the authors demonstrate a novel technology for constructing large-scale electronic systems based on graphene/molybdenum disulfide (MoS2) heterostructures grown by chemical vapor deposition.
Abstract: Two-dimensional (2D) materials have generated great interest in the past few years as a new toolbox for electronics. This family of materials includes, among others, metallic graphene, semiconducting transition metal dichalcogenides (such as MoS2), and insulating boron nitride. These materials and their heterostructures offer excellent mechanical flexibility, optical transparency, and favorable transport properties for realizing electronic, sensing, and optical systems on arbitrary surfaces. In this paper, we demonstrate a novel technology for constructing large-scale electronic systems based on graphene/molybdenum disulfide (MoS2) heterostructures grown by chemical vapor deposition. We have fabricated high-performance devices and circuits based on this heterostructure, where MoS2 is used as the transistor channel and graphene as contact electrodes and circuit interconnects. We provide a systematic comparison of the graphene/MoS2 heterojunction contact to more traditional MoS2-metal junctions, as well as a theoretical investigation, using density functional theory, of the origin of the Schottky barrier height. The tunability of the graphene work function with electrostatic doping significantly improves the ohmic contact to MoS2. These high-performance large-scale devices and circuits based on this 2D heterostructure pave the way for practical flexible transparent electronics.
439 citations
TL;DR: This review provides an overview of the utilization of photoactivated nanomaterials in gas sensing field and excellent gas sensing performance of emerging two-dimensional materials-based sensors under light illumination is discussed in details with proposed gas sensing mechanism.
Abstract: Room-temperature gas sensors have aroused great attention in current gas sensor technology because of deemed demand of cheap, low power consumption and portable sensors for rapidly growing Internet of things applications. As an important approach, light illumination has been exploited for room-temperature operation with improving gas sensor’s attributes including sensitivity, speed and selectivity. This review provides an overview of the utilization of photoactivated nanomaterials in gas sensing field. First, recent advances in gas sensing of some exciting different nanostructures and hybrids of metal oxide semiconductors under light illumination are highlighted. Later, excellent gas sensing performance of emerging two-dimensional materials-based sensors under light illumination is discussed in details with proposed gas sensing mechanism. Originated impressive features from the interaction of photons with sensing materials are elucidated in the context of modulating sensing characteristics. Finally, the review concludes with key and constructive insights into current and future perspectives in the light-activated nanomaterials for optoelectronic gas sensor applications.
Highlights:
1 Operations of metal oxide semiconductors gas sensors at room temperature under photoactivation are discussed.2 Emerging two-dimensional (2D) materials-based gas sensors under light illumination are summarized.3 The advantages and limitations of metal oxides and 2D-materials-based sensors in gas sensing at room temperature under photoactivation are highlighted.
164 citations
TL;DR: In this article, the synthesis, structure, surface chemistry and properties of MXenes have been discussed and a review mainly focuses on the state of the art recent advancements in gas sensing, biosensing and piezoresistive sensing applications.
139 citations
TL;DR: In this article, a review of WO3 thin films and their promising utilization as the sensing layers are overviewed to highlight their potential in gas sensors, and strategies to improve the sensor properties such as sensitivity, response recovery speed and selectivity are also discussed.
Abstract: Thin film technology shows high promise in fabrication of electronic devices such as gas sensors. Tungsten trioxide (WO3), as one of the best-known metal oxide semiconductors (MOS) sensing materials, has attracted significant interest for application in gas sensors. In this review, WO3 thin films and their promising utilization as the sensing layers are overviewed to highlight their potential in gas sensors. First, the sensing mechanism for WO3 materials is briefly discussed. Then, several methods for WO3 film preparation are summarized. Following we discuss the specific gas sensing performances of WO3 film sensors to NO2, H2, NH3, and H2S. Strategies to improve the sensor properties such as sensitivity, response-recovery speed and selectivity are also discussed. Finally, the future perspectives and challenges of WO3 thin film sensors are addressed.
84 citations
TL;DR: Organohydrogels can inherit and carry forward the merits of hydrogels, but also have some unique advantageous features such as anti-freezing and water retention abilities, solvent resistance, adjustable surface wettability, and shape memory effect, which are conducive to the wide environmental adaptability and intelligent applications as discussed by the authors .
Abstract: Multiple stretchable materials have been successively developed and applied to wearable devices, soft robotics, and tissue engineering. Organohydrogels are currently being widely studied and formed by dispersing immiscible hydrophilic/hydrophobic polymer networks or only hydrophilic polymer networks in an organic/water solvent system. In particular, they can not only inherit and carry forward the merits of hydrogels, but also have some unique advantageous features, such as anti-freezing and water retention abilities, solvent resistance, adjustable surface wettability, and shape memory effect, which are conducive to the wide environmental adaptability and intelligent applications. This review first summarizes the structure, preparation strategy, and unique advantages of the reported organohydrogels. Furthermore, organohydrogels can be optimized for electro-mechanical properties or endowed with various functionalities by adding or modifying various functional components owing to their modifiability. Correspondingly, different optimization strategies, mechanisms, and advanced developments are described in detail, mainly involving the mechanical properties, conductivity, adhesion, self-healing properties, and antibacterial properties of organohydrogels. Moreover, the applications of organohydrogels in flexible sensors, energy storage devices, nanogenerators, and biomedicine have been summarized, confirming their unlimited potential in future development. Finally, the existing challenges and future prospects of organohydrogels are provided.
55 citations
References
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TL;DR: Monocrystalline graphitic films are found to be a two-dimensional semimetal with a tiny overlap between valence and conductance bands and they exhibit a strong ambipolar electric field effect.
Abstract: We describe monocrystalline graphitic films, which are a few atoms thick but are nonetheless stable under ambient conditions, metallic, and of remarkably high quality. The films are found to be a two-dimensional semimetal with a tiny overlap between valence and conductance bands, and they exhibit a strong ambipolar electric field effect such that electrons and holes in concentrations up to 10 13 per square centimeter and with room-temperature mobilities of ∼10,000 square centimeters per volt-second can be induced by applying gate voltage.
55,532 citations
TL;DR: This work reviews the historical development of Transition metal dichalcogenides, methods for preparing atomically thin layers, their electronic and optical properties, and prospects for future advances in electronics and optoelectronics.
Abstract: Single-layer metal dichalcogenides are two-dimensional semiconductors that present strong potential for electronic and sensing applications complementary to that of graphene.
13,348 citations
TL;DR: By using micromechanical cleavage, a variety of 2D crystals including single layers of boron nitride, graphite, several dichalcogenides, and complex oxides are prepared and studied.
Abstract: We report free-standing atomic crystals that are strictly 2D and can be viewed as individual atomic planes pulled out of bulk crystals or as unrolled single-wall nanotubes. By using micromechanical cleavage, we have prepared and studied a variety of 2D crystals including single layers of boron nitride, graphite, several dichalcogenides, and complex oxides. These atomically thin sheets (essentially gigantic 2D molecules unprotected from the immediate environment) are stable under ambient conditions, exhibit high crystal quality, and are continuous on a macroscopic scale.
10,586 citations
TL;DR: This Review describes how the tunable electronic structure of TMDs makes them attractive for a variety of applications, as well as electrically active materials in opto-electronics.
Abstract: Ultrathin two-dimensional nanosheets of layered transition metal dichalcogenides (TMDs) are fundamentally and technologically intriguing. In contrast to the graphene sheet, they are chemically versatile. Mono- or few-layered TMDs - obtained either through exfoliation of bulk materials or bottom-up syntheses - are direct-gap semiconductors whose bandgap energy, as well as carrier type (n- or p-type), varies between compounds depending on their composition, structure and dimensionality. In this Review, we describe how the tunable electronic structure of TMDs makes them attractive for a variety of applications. They have been investigated as chemically active electrocatalysts for hydrogen evolution and hydrosulfurization, as well as electrically active materials in opto-electronics. Their morphologies and properties are also useful for energy storage applications such as electrodes for Li-ion batteries and supercapacitors.
7,903 citations
TL;DR: In this paper, it was shown that micrometre-size sensors made from graphene are capable of detecting individual events when a gas molecule attaches to or detaches from graphene's surface.
Abstract: The ultimate aim of any detection method is to achieve such a level of sensitivity that individual quanta of a measured entity can be resolved. In the case of chemical sensors, the quantum is one atom or molecule. Such resolution has so far been beyond the reach of any detection technique, including solid-state gas sensors hailed for their exceptional sensitivity1, 2, 3, 4. The fundamental reason limiting the resolution of such sensors is fluctuations due to thermal motion of charges and defects5, which lead to intrinsic noise exceeding the sought-after signal from individual molecules, usually by many orders of magnitude. Here, we show that micrometre-size sensors made from graphene are capable of detecting individual events when a gas molecule attaches to or detaches from graphene's surface. The adsorbed molecules change the local carrier concentration in graphene one by one electron, which leads to step-like changes in resistance. The achieved sensitivity is due to the fact that graphene is an exceptionally low-noise material electronically, which makes it a promising candidate not only for chemical detectors but also for other applications where local probes sensitive to external charge, magnetic field or mechanical strain are required.
7,318 citations