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Journal ArticleDOI

Natural Feedstock in Catalysis: A Sustainable Route Towards Organic Transformations

U. P. Patil, +1 more
- 13 Aug 2021 - 
- Vol. 379, Iss: 5, pp 1-42
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TLDR
In this paper, a review outlines the decisive organic transformations for which feedstock-derived catalysts have been employed effectively and successfully, along with their economic and environmental benefits over traditional catalytic systems.
Abstract
Catalysts are the jewel in the crown of the chemical industry, accelerating reaction kinetics and augmenting the efficiency of desired reaction paths. Natural feedstock is a renewable resource capable of providing valuable functional products; in addition, it confers an opportunity to create catalysts. As an alternative to stoichiometric reagents, and as a part of a sustainable approach, the implications of using natural feedstocks as a source of new catalysts has attracted considerable interest. Natural feedstock-derived catalysts can promote chemical transformations more efficiently. Recent reports have highlighted the significant role of these biogenic, cost-effective, innocuous, biodegradable materials as catalysts in many biologically and pharmacologically important protocols. This review outlines the decisive organic transformations for which feedstock-derived catalysts have been employed effectively and successfully, along with their economic and environmental benefits over traditional catalytic systems.

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Journal ArticleDOI

Nickel-Catalyzed Enantioselective Arylative Activation of Aromatic C-O Bond

TL;DR: In this article, the first enantioselective activation of an aromatic C-O bond was demonstrated via the catalytic arylative ring-opening cross-coupling of diarylfurans.
References
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Journal ArticleDOI

A new stereospecific cross-coupling by the palladium-catalyzed reaction of 1-alkenylboranes with 1-alkenyl or 1-alkynyl halides

TL;DR: In this article, the representative (E)-1-alkenyldisiamylboranes and 1-alkenyl-1,3,2-benzodioxaboroles readily obtainable via hydroboration of 1 -alkynes react with (1) halides or (1)-alkynyl halides in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium and base to give corresponding conjugated (E-dienes or (E-)enynes with high regio-and
Journal ArticleDOI

Heavy metal hyperaccumulating plants: how and why do they do it? And what makes them so interesting?

TL;DR: An overview of literature discussing the phytoremediation capacity of hyperaccumulators to clean up soils contaminated with heavy metals and the possibility of using these plants in phytomining is presented.
Journal ArticleDOI

Biodiesel from algae: challenges and prospects

TL;DR: An overview of a potential algal biofuel pipeline is presented, and recent work that tackles optimization of algal biomass production and the content of fuel molecules within the algal cell is focused on.
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What is the role of feedstock for sustainable petrochemical production?

The provided paper does not specifically discuss the role of feedstock for sustainable petrochemical production.