Journal ArticleDOI
On the preparation of metalloporphyrins
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This article is published in Journal of Inorganic and Nuclear Chemistry.The article was published on 1970-07-01. It has received 1627 citations till now.read more
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The Catalytic Valorization of Lignin for the Production of Renewable Chemicals
TL;DR: Biomass is an important feedstock for the renewable production of fuels, chemicals, and energy, and it recently surpassed hydroelectric energy as the largest domestic source of renewable energy.
Journal ArticleDOI
A colorimetric sensor array for odour visualization
Neal A. Rakow,Kenneth S. Suslick +1 more
TL;DR: A simple optical chemical sensing method that utilizes the colour change induced in an array of metalloporphyrin dyes upon ligand binding while minimizing the need for extensive signal transduction hardware is reported.
Journal ArticleDOI
An optical method for measurement of dioxygen concentration based upon quenching of phosphorescence.
TL;DR: Binding of the molecules to bovine serum albumin decreased the quenching constant for oxygen by approximately an order of magnitude and inhibited probe self-quenching, indicating that at the protein binding site the probes are somewhat protected from collision with quenchers.
Journal ArticleDOI
Artificial Enzymes Formed through Directed Assembly of Molecular Square Encapsulated Epoxidation Catalysts
TL;DR: The "molecular square" takes on the functions of the protein superstructure in an enzyme: it spatially protects the catalytic core from decomposition and induces reaction selectivity.
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Factors Influencing Self-Aggregation Tendencies of Cationic Porphyrins in Aqueous Solution
TL;DR: In this article, the authors investigated the factors which most influence porphyrin self-aggregation in water and showed that the entropy change for aggregation increases with increasing concentrations of added KNO3, while enthalpy changes are almost constant.
References
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Journal ArticleDOI
A simplified synthesis for meso-tetraphenylporphine
Alan D. Adler,Frederick R. Longo,John D. Finarelli,Joel Goldmacher,Jacques Assour,Leonard Korsakoff +5 more
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Spectra of the Metallo-derivatives of α,β,γ,δ-Tetraphenylporphine
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Porphyrin studies; the metal complex salts of alpha, beta, gamma, delta-tetraphenylporphine.
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Metal Chelates of Tetraphenylporphine and of Some p-Substituted Derivatives1,2
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A mechanistic study of the synthesis of meso-tetraphenylporphin
TL;DR: The role of atmospheric oxygen in the condensation of pyrrole and benzaldehyde to ms-tetraphenylporphin in acidic media was studied in this article, where the effects of acidity, solvent, concentration, and other constraints on both the rate and yield of the reaction were investigated.