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Organic and solution-processed tandem solar cells with 17.3% efficiency

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TLDR
In this article, a semi-empirical model analysis and using the tandem cell strategy to overcome the low charge mobility of organic materials, leading to a limit on the active-layer thickness and efficient light absorption was performed.
Abstract
Although organic photovoltaic (OPV) cells have many advantages, their performance still lags far behind that of other photovoltaic platforms. A fundamental reason for their low performance is the low charge mobility of organic materials, leading to a limit on the active-layer thickness and efficient light absorption. In this work, guided by a semi-empirical model analysis and using the tandem cell strategy to overcome such issues, and taking advantage of the high diversity and easily tunable band structure of organic materials, a record and certified 17.29% power conversion efficiency for a two-terminal monolithic solution-processed tandem OPV is achieved.

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Journal ArticleDOI

Over 16% efficiency organic photovoltaic cells enabled by a chlorinated acceptor with increased open-circuit voltages

TL;DR: This study demonstrates that finely tuning the OPV materials to reduce the bandgap-voltage offset has great potential for boosting the efficiency and unexpectedly obtain higher open-circuit voltages and achieve a record high PCE of 16.5% by chlorination.
Journal ArticleDOI

Achieving over 16% efficiency for single-junction organic solar cells

TL;DR: In this paper, two non-fullerene acceptors were matched with a wide-bandgap polymer donor P2F-EHp consisting of an imide-functionalized benzotriazole moiety, as these materials presented complementary absorption and well-matched energy levels.
Journal ArticleDOI

Alkyl Chain Tuning of Small Molecule Acceptors for Efficient Organic Solar Cells

TL;DR: In this paper, a small molecule acceptor (SMA) with 3rd position branched alkyl chains was designed and synthesized to investigate the influence of alkyls on the properties and performance of the SMAs.
References
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Journal ArticleDOI

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells

TL;DR: In this article, an upper theoretical limit for the efficiency of p−n junction solar energy converters, called the detailed balance limit of efficiency, has been calculated for an ideal case in which the only recombination mechanism of holeelectron pairs is radiative as required by the principle of detailed balance.
Journal ArticleDOI

High-performance photovoltaic perovskite layers fabricated through intramolecular exchange

TL;DR: An approach for depositing high-quality FAPbI3 films, involving FAP bI3 crystallization by the direct intramolecular exchange of dimethylsulfoxide (DMSO) molecules intercalated in PbI2 with formamidinium iodide is reported.
Journal ArticleDOI

Design Rules for Donors in Bulk‐Heterojunction Solar Cells—Towards 10 % Energy‐Conversion Efficiency

TL;DR: In this article, the authors presented a review of several organic photovoltaics (OPV) technologies, including conjugated polymers with high-electron-affinity molecules like C60 (as in the bulk-heterojunction solar cell).
Journal ArticleDOI

Bulk heterojunction solar cells with internal quantum efficiency approaching 100

TL;DR: In this paper, a polymer solar cell based on a bulk hetereojunction design with an internal quantum efficiency of over 90% across the visible spectrum (425 nm to 575 nm) is reported.
Journal ArticleDOI

Synthesis of Conjugated Polymers for Organic Solar Cell Applications

TL;DR: Fluorene-Based Copolymers ContainingPhosphorescent Complexes and Carbazole-Based Conjugated Polymers R5.1.3.
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