Journal ArticleDOI
Organoaluminum-promoted Claisen rearrangement of allyl vinyl ethers
Reads0
Chats0
TLDR
Le (bis-[(bromo-4 di-t-butyl-2,6)phenoxy methyl) aluminium peut etre utilise pour obtenir l'isomere (Z) alors que l'sisomeres (E) est produit avec le (bis-(diphenyl 2,6 phenoxy] methyl) aluminum as discussed by the authors.Abstract:
Le (bis-[(bromo-4 di-t-butyl-2,6)phenoxy methyl) aluminium peut etre utilise pour obtenir l'isomere (Z) alors que l'isomere (E) est produit avec le (bis-[diphenyl-2,6 phenoxy] methyl) aluminiumread more
Citations
More filters
Journal ArticleDOI
Tandem [4+2]/[3+2] Cycloadditions of Nitroalkenes.
TL;DR: Denmark et al. as mentioned in this paper proposed a method to match the change in molecular complexity at each step with reactions of comparable synthetic complexity, which is a necessary condition for high synthetic efficiency.
Journal ArticleDOI
Gold(I)-Catalyzed Propargyl Claisen Rearrangement
Benjamin D. Sherry,F. Dean Toste +1 more
TL;DR: Homoallenic alcohols are prepared from propargyl vinyl ethers using a trinuclear gold(I)-oxo complex, [(Ph3PAu)3O]BF4, as a catalyst for Propargyl Claisen rearrangement at room temperature with excellent diastereoselectivity and excellent chirality transfer.
Journal ArticleDOI
Propargyl Claisen rearrangement: allene synthesis and beyond
TL;DR: The correct use of appropriate propargyl vinyl ethers as starting materials coupled with suitable reaction conditions can aid in the development of new domino methodologies in which the allenes are valuable intermediates in route to a wide range of important classes of organic compounds.