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Journal ArticleDOI

Oxide semiconductor gas sensors

Noboru Yamazoe, +2 more
- 01 Apr 2003 - 
- Vol. 7, Iss: 1, pp 63-75
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TLDR
In this paper, the three key requirements of sensor design are determined by considering each of these three key factors: selection of a base oxide with high mobility of conduction electrons and satisfactory stability (transducer function), selection of foreign receptor which enhances surface reactions or adsorption of target gas (receptor function), and fabrication of a highly porous, thin sensing body (utility factor).
Abstract
Semiconductor gas sensors utilize porous polycrystalline resistors made of semiconducting oxides. The working principle involves the receptor function played by the surface of each oxide grain and the transducer function played by each grain boundary. In addition, the utility factor of the sensing body also takes part in determining the gas response. Therefore, the concepts of sensor design are determined by considering each of these three key factors. The requirements are selection of a base oxide with high mobility of conduction electrons and satisfactory stability (transducer function), selection of a foreign receptor which enhances surface reactions or adsorption of target gas (receptor function), and fabrication of a highly porous, thin sensing body (utility factor). Recent progress in sensor design based on these factors is described.

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Nanoscale metal oxide-based heterojunctions for gas sensing: A review

TL;DR: In this paper, the dominant electronic and chemical mechanisms that influence the performance of metal-oxide-based resistive-type gas sensors are discussed, including p-n and n-n potential barrier manipulation, n-p-n response type inversions, spillover effects, synergistic catalytic behavior, and microstructure enhancement.
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Metal and Metal Oxide Nanoparticles in Chemiresistors: Does the Nanoscale Matter?

TL;DR: This Review highlights the recent developments and reflects the impact of nanoscience on sensor technology, which can be improved and novel sensor concepts based on bottom-up approaches show that the sensor properties can be controlled by molecular design.
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Metal Oxide Semi-Conductor Gas Sensors in Environmental Monitoring

TL;DR: The nature of the gas response and how it is fundamentally linked to surface structure is explored and Synthetic routes to metal oxide semiconductor gas sensors are discussed and related to their affect on surface structure.
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Metal Oxide Nanostructures and Their Gas Sensing Properties: A Review

TL;DR: The gas sensing properties of metal oxide nanostructures assembled by nanoparticles are reviewed in this article and the effect of doping is summarized and the perspectives ofMetal oxide gas sensor are given.
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References
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Journal ArticleDOI

Grain size effects on gas sensitivity of porous SnO2-based elements

TL;DR: In this paper, the effects of grain size on gas sensitivity were investigated by using porous sintered SnO2 elements fabricated with pure and impurity-doped SnO 2 elements.
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Interactions of tin oxide surface with O2, H2O AND H2

TL;DR: In this paper, the authors investigated the interaction of tin oxide surface with oxygen, water vapor, and hydrogen using temperature-programmed desorption (TPD) chromatograms of oxygen.
Journal ArticleDOI

Theory of gas-diffusion controlled sensitivity for thin film semiconductor gas sensor

TL;DR: In this article, a diffusion equation was formulated by assuming that an inflammable gas (target gas) moves inside the film by Knudsen diffusion, while it reacts with the adsorbed oxygen following a first-order reaction kinetic.
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Electronic Interaction between Metal Additives and Tin Dioxide in Tin Dioxide-Based Gas Sensors

TL;DR: In this article, the electronic interaction of SnO2 with Ag and Pd particles dispersed on its surface was examined by means of X-ray photoelectron spectroscopy (XPS).
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