Journal ArticleDOI
Palladium‐Catalyzed Oxidative Carbonylation Reactions
Reads0
Chats0
TLDR
The oxidative addition step could be potentially avoided in oxidative reactions, but only few reviews exist in this area, and the recent development in the oxidative carbonylation reactions are summarized.Abstract:
Palladium-catalyzed coupling reactions have become a powerful tool for advanced organic synthesis. This type of reaction is of significant value for the preparation of pharmaceuticals, agrochemicals, as well as advanced materials. Both, academic as well as industrial laboratories continuously investigate new applications of the different methodologies. Clearly, this area constitutes one of the major topics in homogeneous catalysis and organic synthesis. Among the different palladium-catalyzed coupling reactions, several carbonylations have been developed and widely used in organic syntheses and are even applied in the pharmaceutical industry on ton-scale. Furthermore, methodologies such as the carbonylative Suzuki and Sonogashira reactions allow for the preparation of interesting building blocks, which can be easily refined further on. Although carbonylative coupling reactions of aryl halides have been well established, palladium-catalyzed oxidative carbonylation reactions are also interesting. Compared with the reactions of aryl halides, oxidative carbonylation reactions offer an interesting pathway. The oxidative addition step could be potentially avoided in oxidative reactions, but only few reviews exist in this area. In this Minireview, we summarize the recent development in the oxidative carbonylation reactions.read more
Citations
More filters
Journal ArticleDOI
Chemicals from Alkynes with Palladium Catalysts
Rafael Chinchilla,Carmen Nájera +1 more
Journal ArticleDOI
Transition-Metal-Catalyzed Direct Addition of Unactivated C–H Bonds to Polar Unsaturated Bonds
Lei Yang,Hanmin Huang +1 more
Journal ArticleDOI
Transition-Metal-Catalyzed C–H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds
TL;DR: The transition-metal-catalyzed addition of C-H bonds to carbonyls, imines, and related polarized π bonds has emerged as a particularly efficient and powerful approach for the construction of an incredibly diverse array of heteroatom-substituted products.
Journal ArticleDOI
Recent developments in palladium catalysed carbonylation reactions
TL;DR: In this article, the authors summarized the recent trends in carbonylative transformations, which have undergone a rapid development, and summarized the various aspects of these reactions, including catalyst-product separation, and catalyst recoverability and reusability.
Journal ArticleDOI
Fixation of sulfur dioxide into small molecules
TL;DR: In this review, recent advances in the insertion of sulfur dioxide are presented and the most promising and attractive approach using sulfur dioxide is presented.
References
More filters
BookDOI
Metal-catalyzed cross-coupling reactions
TL;DR: In this paper, the authors present an approach to the formation of C-X (X = N, O, S) bonds in metal-catalyzed cross-coupling reactions.
Journal ArticleDOI
Catalytic functionalization of arenes and alkanes via C-H bond activation.
TL;DR: Several novel synthetic reactions of arenes and alkanes discovered and investigated in the laboratory are summarized here.
Journal ArticleDOI
Palladium-catalyzed carbonylation reactions of aryl halides and related compounds.
TL;DR: The recent academic developments in palladium-catalyzed carbonylation reactions of aromatic halides in the presence of various nucleophiles are summarized and the first industrial processes are summarized.
Related Papers (5)
Synthesis of Heterocycles via Palladium-Catalyzed Carbonylations
Oxidative carbonylation reactions: organometallic compounds (R-M) or hydrocarbons (R-H) as nucleophiles.
Qiang Liu,Hua Zhang,Aiwen Lei +2 more