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Journal ArticleDOI

Partially disordered nano-porous metallic oxide engineering: surface morphology controllability and multiple scattering properties.

25 Sep 2020-Nanotechnology (IOP Publishing)-Vol. 31, Iss: 39, pp 395701
TL;DR: The research focuses on the disorder caused by one-step oxidation, which is distinct from previous studies that introducing disorder into periodic materials, and would open up new prospects for sensing, bionics and structural color.
Abstract: Random multiple light scattering in disordered photonics leads to interesting and unexpected physical phenomena. Here, we demonstrate two types of partially disordered nano-porous metallic oxide materials: disordered grating nano-pores and two-dimensional disordered nano-tubes, which are produced just with one-step anodic oxidation. The relations among the processing parameters, morphology properties and multiple scattering characteristics are investigated. The surface morphology controllability can be achieved by simply changing the processing direct voltages, leading to different scattering properties. The probabilistic model of partially disordered nano-porous metallic oxide is constructed according to the nano-structure characteristics of oxide, and the rigorous coupled wave analysis is utilized for optical field simulation to exhibit the theoretical multiple scattering properties. Futhermore, the experimental scattering fields are measured and are analysed by statistical method. The research focuses on the disorder caused by one-step oxidation, which is distinct from previous studies that introducing disorder into periodic materials, and would open up new prospects for sensing, bionics and structural color.
Citations
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Journal ArticleDOI
TL;DR: In this article , the authors investigate partially disordered MoSe2 nanospheres experimentally regarding their morphology and absorption spectrum in broadband wavelengths and propose an optical simulation with three-dimensional finite-difference time-domain method to explain the crucial impacts of morphological parameters on optical responses.
Abstract: It is important to clarify the role and possible applicability of partially disordered structures in photonics, but there is still a lack of an effective method for it. Here, we investigate partially disordered MoSe2 nanospheres experimentally regarding their morphology and absorption spectrum in broadband wavelengths and propose an optical simulation with three-dimensional finite-difference time-domain method to explain the crucial impacts of morphological parameters on optical responses. The experimental spectral absorbance of MoSe2 nanospheres reveals a strong light-absorbing character in broadband wavelengths. The simulated spectral curves coincide with the experimental results by adjusting morphological parameters, i.e. the statistics of size and the number of layer, and the linear correlation coefficient between the simulated and experimental spectral curves is up to 0.94. The disorder plays a key role in the high light-absorption feature, and the feature originates from anti-reflection, defective state absorption, multiple light scattering and coherent diffusion effects. The results not only deepen the understanding of disordered photonics in semiconductor nanostructures, but also provide a simulation approach to optimize experimental designs.
References
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Journal ArticleDOI
22 Oct 1992-Nature
TL;DR: In this paper, the synthesis of mesoporous inorganic solids from calcination of aluminosilicate gels in the presence of surfactants is described, in which the silicate material forms inorganic walls between ordered surfactant micelles.
Abstract: MICROPOROUS and mesoporous inorganic solids (with pore diameters of ≤20 A and ∼20–500 A respectively)1 have found great utility as catalysts and sorption media because of their large internal surface area. Typical microporous materials are the crystalline framework solids, such as zeolites2, but the largest pore dimensions found so far are ∼10–12 A for some metallophosphates3–5 and ∼14 A for the mineral cacoxenite6. Examples of mesoporous solids include silicas7 and modified layered materials8–11, but these are invariably amorphous or paracrystalline, with pores that are irregularly spaced and broadly distributed in size8,12. Pore size can be controlled by intercalation of layered silicates with a surfactant species9,13, but the final product retains, in part, the layered nature of the precursor material. Here we report the synthesis of mesoporous solids from the calcination of aluminosilicate gels in the presence of surfactants. The material14,15 possesses regular arrays of uniform channels, the dimensions of which can be tailored (in the range 16 A to 100 A or more) through the choice of surfactant, auxiliary chemicals and reaction conditions. We propose that the formation of these materials takes place by means of a liquid-crystal 'templating' mechanism, in which the silicate material forms inorganic walls between ordered surfactant micelles.

15,125 citations

Journal ArticleDOI
04 Nov 2011-Science
TL;DR: In this article, a Co(II/III)tris(bipyridyl)-based redox electrolyte was used in conjunction with a custom synthesized donor-π-bridge-acceptor zinc porphyrin dye as sensitizer (designated YD2-o-C8).
Abstract: The iodide/triiodide redox shuttle has limited the efficiencies accessible in dye-sensitized solar cells. Here, we report mesoscopic solar cells that incorporate a Co(II/III)tris(bipyridyl)–based redox electrolyte in conjunction with a custom synthesized donor-π-bridge-acceptor zinc porphyrin dye as sensitizer (designated YD2-o-C8). The specific molecular design of YD2-o-C8 greatly retards the rate of interfacial back electron transfer from the conduction band of the nanocrystalline titanium dioxide film to the oxidized cobalt mediator, which enables attainment of strikingly high photovoltages approaching 1 volt. Because the YD2-o-C8 porphyrin harvests sunlight across the visible spectrum, large photocurrents are generated. Cosensitization of YD2-o-C8 with another organic dye further enhances the performance of the device, leading to a measured power conversion efficiency of 12.3% under simulated air mass 1.5 global sunlight.

5,462 citations

Journal Article
01 Jan 2011-Science
TL;DR: Mesoscopic solar cells that incorporate a Co(II/III)tris(bipyridyl)–based redox electrolyte in conjunction with a custom synthesized donor-π-bridge-acceptor zinc porphyrin dye as sensitizer are reported, enabling attainment of strikingly high photovoltages approaching 1 volt.
Abstract: Simultaneous modification of the dye and redox shuttle boosts the efficiency of a dye-sensitized solar cell. The iodide/triiodide redox shuttle has limited the efficiencies accessible in dye-sensitized solar cells. Here, we report mesoscopic solar cells that incorporate a Co(II/III)tris(bipyridyl)–based redox electrolyte in conjunction with a custom synthesized donor-π-bridge-acceptor zinc porphyrin dye as sensitizer (designated YD2-o-C8). The specific molecular design of YD2-o-C8 greatly retards the rate of interfacial back electron transfer from the conduction band of the nanocrystalline titanium dioxide film to the oxidized cobalt mediator, which enables attainment of strikingly high photovoltages approaching 1 volt. Because the YD2-o-C8 porphyrin harvests sunlight across the visible spectrum, large photocurrents are generated. Cosensitization of YD2-o-C8 with another organic dye further enhances the performance of the device, leading to a measured power conversion efficiency of 12.3% under simulated air mass 1.5 global sunlight.

5,385 citations

Journal ArticleDOI
TL;DR: It is shown that the capacitive charge-storage properties of mesoporous films of iso-oriented alpha-MoO(3) are superior to those of either Mesoporous amorphous material or non-porous crystalline MoO( 3).
Abstract: Capacitive energy storage is technologically attractive because of its short charging times and its ability to deliver more power than batteries. The capacitive charge-storage properties of mesoporous films of MoO3 with iso-oriented grains now lead to pseudocapacitive materials that offer increased energy density while still maintaining high power density.

2,643 citations

Journal ArticleDOI
TL;DR: In this article, the authors used spatial wavefront shaping to improve the focusing resolution of a lens by using wave front shaping to compensate for scattering in an inhomogeneous medium between the lens and the focal plane.
Abstract: Optical microscopy and manipulation methods rely on the ability to focus light to a small volume. However, in inhomogeneous media such as biological tissue, light is scattered out of the focusing beam. Disordered scattering is thought to fundamentally limit the resolution and penetration depth of optical methods1,2,3. Here we demonstrate, in an optical experiment, that scattering can be used to improve, rather than deteriorate, the sharpness of the focus. The resulting focus is even sharper than that in a transparent medium. By using scattering in the medium behind a lens, light was focused to a spot ten times smaller than the diffraction limit of that lens. Our method is the optical equivalent of highly successful methods for improving the resolution and communication bandwidth of ultrasound, radio waves and microwaves4,5,6. Our results, obtained using spatial wavefront shaping, apply to all coherent methods for focusing through scattering matter, including phase conjugation7 and time-reversal4. Light is scattered out of a focusing beam when an inhomogeneous medium is placed between the lens and the focal plane. Now, scientists experimentally demonstrate that scattering can be exploited to improve, rather than deteriorate, the focusing resolution of a lens by using wavefront shaping to compensate for scattering.

716 citations