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Journal ArticleDOI

Performance characterization and steady-state modelling of spinning basket membrane module

TL;DR: In this paper, the performance of this module has been reported in the ultra-filtration operation and it is a special type of shear-enhanced device with inbuilt cleaning facility.
Abstract: Spinning basket membrane module is a special type of shear-enhanced device with inbuilt cleaning facility. In this article, the performance of this module has been reported in the ultrafiltration o...
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Journal ArticleDOI
18 May 2021
TL;DR: In this paper, a review of different phenomenological and non-phenomenological models for permeate flux prediction in UF, and a comparison, between selected models, of the predictive capacity.
Abstract: In any membrane filtration, the prediction of permeate flux is critical to calculate the membrane surface required, which is an essential parameter for scaling-up, equipment sizing, and cost determination. For this reason, several models based on phenomenological or theoretical derivation (such as gel-polarization, osmotic pressure, resistance-in-series, and fouling models) and non-phenomenological models have been developed and widely used to describe the limiting phenomena as well as to predict the permeate flux. In general, the development of models or their modifications is done for a particular synthetic model solution and membrane system that shows a good capacity of prediction. However, in more complex matrices, such as fruit juices, those models might not have the same performance. In this context, the present work shows a review of different phenomenological and non-phenomenological models for permeate flux prediction in UF, and a comparison, between selected models, of the permeate flux predictive capacity. Selected models were tested with data from our previous work reported for three fruit juices (bergamot, kiwi, and pomegranate) processed in a cross-flow system for 10 h. The validation of each selected model’s capacity of prediction was performed through a robust statistical examination, including a residual analysis. The results obtained, within the statistically validated models, showed that phenomenological models present a high variability of prediction (values of R-square in the range of 75.91–99.78%), Mean Absolute Percentage Error (MAPE) in the range of 3.14–51.69, and Root Mean Square Error (RMSE) in the range of 0.22–2.01 among the investigated juices. The non-phenomenological models showed a great capacity to predict permeate flux with R-squares higher than 97% and lower MAPE (0.25–2.03) and RMSE (3.74–28.91). Even though the estimated parameters have no physical meaning and do not shed light into the fundamental mechanistic principles that govern these processes, these results suggest that non-phenomenological models are a useful tool from a practical point of view to predict the permeate flux, under defined operating conditions, in membrane separation processes. However, the phenomenological models are still a proper tool for scaling-up and for an understanding the UF process.

14 citations

Journal ArticleDOI
TL;DR: In this article, the authors presented the modeling, simulation, and characterization studies of a dynamic shear-enhanced (DSE) filtration system with an inbuilt cleaning facility.
Abstract: Membrane-based low-cost recovery of nutritional and therapeutic proteins from wastewater is regarded as a leap towards sustainability. However, membranes are heavily fouled by proteins, and thus, frequent chemical or hydrodynamic cleaning is needed even in the advanced dynamic shear-enhanced (DSE) filtration devices. This article presents the modeling, simulation, and characterization studies of a DSE system, namely the ‘Spinning Basket membrane’ (SBM) module with an inbuilt cleaning facility. The device has been established to be specifically suitable for the recovery of proteins from synthetic wastewater. It can perpetually regenerate the flux with its simple and, moreover, online cleaning facility. A two-parameter transient model, purely based on an analytical approach, has been developed to simulate the device. Moderately low deviation (±12 %) of the simulated flux from the corresponding experimental data obtained from ultrafiltration of synthetic wastewater unambiguously validates the proposed model. The present modeling strategy demonstrates how a DSE filtration system with highly complex modes of mass and momentum transfer could be easily simulated.

1 citations

References
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Journal ArticleDOI
TL;DR: In this paper, a theory of hyperfiltration based on non-equilibrium thermodynamics is presented, in which authors combine elements of their own previous work with important contributions of other investigators.

974 citations


"Performance characterization and st..." refers background in this paper

  • ...Kedem black box models.([33,34]) In order to formulate...

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  • ...The model itself is an application of Onsager reciprocal relationship among different fluxes and driving forces considering entropy generation.([34]) The final form of the model equation is represented as:...

    [...]

Book
01 Oct 1987
TL;DR: The Nature and Organization of Optimization Problems are discussed in this article, where the authors develop models for optimisation problems and develop methods for optimization problems in the context of large scale plant design and operation.
Abstract: I Problem Formulation 1 The Nature and Organization of Optimization Problems 2 Developing Models for Optimization 3 Formulation of the Objective Function II Optimization Theory and Methods 4 Basic Concepts of Optimization 5 Optimization for Unconstrained Functions: One- Dimensional Search 6 Unconstrained Multivariable Optimization 7 Linear Programming and Applications 8 Nonlinear Programming with Constraints 9 Mixed-Integer Programming 10 Global Optimization for Problems Containing Continuous and Discrete Variables IIIApplications of Optimization 11 Heat Transfer and Energy Conservation 12 Separation Processes 13 Fluid Flow Systems 14 Chemical Reactor Design and Operation 15 Optimization in Large-Scale Plant Design and Operations 16 Integrated Planning, Scheduling, and Control in the Process Industries Appendixes

967 citations

Journal ArticleDOI
TL;DR: In this article, a review of the literature on concentration polarization in ultrafiltration and reverse osmosis is presented, with specific models such as surface renewal, and experimental methods such as laser-based refractometry, for quantification of the problem.

474 citations


"Performance characterization and st..." refers background in this paper

  • ...), which reduces the effective life span of the membrane.([7,8]) Fouling can be minimized by a number of standard techniques, such as pretreatment of the feed solution,([9]) physicochemical modification of the membrane,([10]) back-pulsing, back-washing or back-flushing,([11,12]) chemical cleaning,([13]) using external force fields (electric, sonic and centrifugal fields) and many others....

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Journal ArticleDOI
TL;DR: In this paper, the authors reviewed the literature on the fouling phenomena in reverse osmosis (RO) membrane systems, the analytical techniques used to quantify fouling, preventive methods, and membrane cleaning strategies and made specific recommendations on how scientists, engineers, and technical staff can assist in improving the performance of these systems through fundamental and applied research.
Abstract: Desalination by using reverse osmosis (RO) membranes has become very popular for producing freshwater from brackish water and seawater. Membrane lifetime and permeate flux, however, are primarily affected by the phenomena of concentration polarization and fouling at the membrane surface. The scope of the current paper was to critically review the literature on the fouling phenomena in RO and ultrafiltration (UF) membrane systems, the analytical techniques used to quantify fouling, preventive methods, and membrane cleaning strategies. The paper also makes specific recommendations on how scientists, engineers, and technical staff can assist in improving the performance of these systems through fundamental and applied research.

468 citations


"Performance characterization and st..." refers background in this paper

  • ...Fouling can be minimized by a number of standard techniques, such as pretreatment of the feed solution,([9]) physicochemical modification of the membrane,([10]) back-pulsing, back-washing or back-flushing,([11,12]) chemical cleaning,([13]) using external force fields (electric, sonic and centrifugal fields) and many others....

    [...]

Journal ArticleDOI
TL;DR: In this paper, the authors describe the rise in transmembrane pressure (TMP) as a three-stage process, which occurs in a period of a few hours and involves abrupt TMP rise due to pore blockage and closure.

413 citations