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Journal ArticleDOI

Pesticide management and their residues in sediments and surface and drinking water in the Mekong Delta, Vietnam.

TL;DR: It is shown that household level pesticide management remains suboptimal in the Mekong Delta and co-occurrence of several pesticides in the samples indicate a considerable chronic exposure of biota and humans to pesticides.
About: This article is published in Science of The Total Environment.The article was published on 2013-05-01. It has received 192 citations till now. The article focuses on the topics: Pesticide & Pesticide residue.
Citations
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Journal ArticleDOI
TL;DR: This review discussed classification, mechanisms, benefits and adverse effects of the pesticides on both human beings and the environment, and some remedial measures to mitigate their toxicity.

373 citations

Journal ArticleDOI
TL;DR: The structure of the UWC is researched in details and the routes by which the water cycle is increasingly contaminated with compounds generated from various anthropogenic activities are investigated.

339 citations

Journal ArticleDOI
TL;DR: This review summarized the available studies on pyrethroid residues since 1986 in different media at the global scale and indicated that pyrethroids have been widely detected in a range of environments (including soils, water, sediments, and indoors) and in organisms.

329 citations


Cites background from "Pesticide management and their resi..."

  • ...…et al., 2007; Liu 336 et al., 2015a), honeysuckle (Tian et al., 2015), and traditional Chinese medicine (Wang et al., 337 2007; Cheng et al., 2013; Tong et al., 2014), with respectiv maximum concentrations of 338 31.00 ng g-1 for cepermethrin, 930.00 ng g-1 for fenvalerate, 73.00 ng g-1 for…...

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  • ...Tong et al. (2014) 341 collected a total of 132 samples of Chinese herbal medicines from major markets in China 342 and found pesticide residues in 74 of them, with a frequency of detection of 4.6% for 343 cyhalothrin, 2.3% for bifenthrin, 1.5% for cepermethrin and permethrin, and 0.8% for…...

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Journal ArticleDOI
TL;DR: This work provides a detailed overview of ACs occurrence in water bodies along with their toxicological effect on living organisms and robust detection and removal strategies must be considered in the design of WWTPs and DWTPs.

161 citations


Cites background from "Pesticide management and their resi..."

  • ...The source of contamination by pesticides may be by direct contact with the pesticide or by infiltration (Toan et al., 2013)....

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Journal ArticleDOI
TL;DR: Overall, this study failed to identify a clean water source in the Mekong Delta with respect to pesticide pollution, and it is therefore urgent to understand further and address drinking water-related health risk issues in the region.
Abstract: Pollution of drinking water sources with agrochemicals is often a major threat to human and ecosystem health in some river deltas, where agricultural production must meet the requirements of national food security or export aspirations. This study was performed to survey the use of different drinking water sources and their pollution with pesticides in order to inform on potential exposure sources to pesticides in rural areas of the Mekong River delta, Vietnam. The field work comprised both household surveys and monitoring of 15 frequently used pesticide active ingredients in different water sources used for drinking (surface water, groundwater, water at public pumping stations, surface water chemically treated at household level, harvested rainwater, and bottled water). Our research also considered the surrounding land use systems as well as the cropping seasons. Improper pesticide storage and waste disposal as well as inadequate personal protection during pesticide handling and application were widespread amongst the interviewed households, with little overall risk awareness for human and environmental health. The results show that despite the local differences in the amount and frequency of pesticides applied, pesticide pollution was ubiquitous. Isoprothiolane (max. concentration 8.49 μg L−1), fenobucarb (max. 2.32 μg L−1), and fipronil (max. 0.41 μg L−1) were detected in almost all analyzed water samples (98 % of all surface samples contained isoprothiolane, for instance). Other pesticides quantified comprised butachlor, pretilachlor, propiconazole, hexaconazole, difenoconazole, cypermethrin, fenoxapro-p-ethyl, tebuconazole, trifloxystrobin, azoxystrobin, quinalphos, and thiamethoxam. Among the studied water sources, concentrations were highest in canal waters. Pesticide concentrations varied with cropping season but did not diminish through the year. Even in harvested rainwater or purchased bottled water, up to 12 different pesticides were detected at concentrations exceeding the European Commission’s parametric guideline values for individual or total pesticides in drinking water (0.1 and 0.5 μg L−1; respectively). The highest total pesticide concentration quantified in bottled water samples was 1.38 μg L−1. Overall, we failed to identify a clean water source in the Mekong Delta with respect to pesticide pollution. It is therefore urgent to understand further and address drinking water-related health risk issues in the region.

149 citations


Cites background or methods or result from "Pesticide management and their resi..."

  • ...Similarly, canal water after flocculation by aluminium and disinfection by boiling was perceived as being safe for use (Toan et al. 2013), confirmed by household survey of this study)....

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  • ...Analytical method A multi-residue pesticide analytical method was adapted from Laabs et al. (2007) and Toan et al. (2013): 500 mL water sample were adjusted to pH 4, 10 g NaCl was added, then filtered through glass fiber filter (pore size 1 μm)....

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  • ...For drinking and cooking purposes in rural areas, every available natural water source including rivers, canals, groundwater, and rainwater are utilized (GSO 2008; Ozdemir et al. 2011; Reis and Mollinga 2012; Toan et al. 2013; Wilbers et al. 2013, 2014)....

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  • ...However, Toan et al. (2013) also conducted a preliminarily screening of drinking water extracted from surface water systems and found 7 out of the 15 studied pesticides in some samples, with average concentrations ranging from 0.01 to 0.47 μg L−1....

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  • ...Recently, Toan et al. (2013) monitored 15 currently used pesticides (buprofezin, butachlor, cypermethrin, difenozonazole, α-endosulfan, β-endosulfan, endosulfan-sulfate, fenobucarb, fipronil, hexaconazole, isoprothiolane, pretilachlor, profenofos, propanil, and propiconazole) in irrigation canals…...

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References
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26 Dec 2003

3,302 citations


"Pesticide management and their resi..." refers background in this paper

  • ...The relatively fast breakdown of fenobucarb (DT50 6–14 days under paddy conditions; Tomlin, 2003) might account for these differences....

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Journal ArticleDOI
David I. Gustafson1
TL;DR: In this article, an index is derived based entirely on the physical properties of those pesticides that have been found either leachable or essentially immobile, and the index is based on graphical examination of a plot formed by two widely available pesticide properties: half life in soil (tsoil 1/2) and partition coefficient between soil organic carbon and water (Koc).
Abstract: Government agencies at both the state and federal levels now face increasing pressures to assess the likelihood of pesticide occurrence in well‒water supplies. Screening methodologies are required in order to determine which pesticides now in use should receive the greatest attention with respect to groundwater, and in order to determine whether elaborate and expensive groundwater testing should be required in order to register a new pesticide. Several screening techniques have been proposed recently, some based on threshold values for critical physical properties of the pesticide, and others based on mathematical models of the leaching process. A different approach is taken in this paper, whereby an index is derived based entirely on the physical properties of those pesticides that have been found either leachable or essentially immobile. The index is based on graphical examination of a plot formed by two widely available pesticide properties: half‒life in soil (tsoil1/2) and partition coefficient between soil organic carbon and water (Koc). Other physical properties, such as water solubility, octanol/water partition coefficient, and volatility from soil, have often been invoked as indicators of leachability, but they are found in this paper to have no useful power in discriminating between “leachers” and “nonleachers.” Scores assigned with the new screening index agree with the results of several recent well‒water monitoring programs, even though point‒source events are thought to be responsible for some of the observed contamination. A nomogram is given that reduces the task of calculating the index to simply placing a straight edge on a diagram.

732 citations

Journal Article
TL;DR: In this article, the authors present a discussion on Log Kow Predictive Methods for Partitioning and its application in thermodynamics and extrathermodynamics of partitioning, as well as experimental methods of Measurement Methods.

618 citations

Journal ArticleDOI
Susmita Dasgupta1, Craig Meisner1, David Wheeler1, Khuc Xuyen, Nhan Thi Lam 
TL;DR: It is found that farmers' self-reported symptoms have very weak associations with actual poisoning, and significant provincial differences in poisoning incidence are found, which highlight the potential importance of negative externalities.

222 citations


"Pesticide management and their resi..." refers background in this paper

  • ...This increasing use of pesticides coupled with their widespread mismanagement (Thuy et al., 2012b) lead to considerable concerns with regard to environmental pollution and human health in the last decades (Dasgupta et al., 2005; Hoai et al., 2011)....

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Journal ArticleDOI
TL;DR: Taking a long-term perspective integrated rice–fish farming with IPM practices provides a sustainable alternative to intensive rice mono-cropping, both from an economic as well as an ecological point of view.

178 citations


"Pesticide management and their resi..." refers background in this paper

  • ...Nevertheless, household surveys and environmental monitoring data show continuous evidence of further use of some of these compounds (Berg, 2001; Dung and Dung, 2003; Hoai et al., 2011; Meisner, 2005; Minh et al., 2007; Thuy et al., 2012b). Berg and Tam (2012) recently reported only marginal changes in the top ten list of the a.i. that were most frequently used in 1999 and 2007 in the Mekong Delta. Themost commonly used pesticides in both yearswere the insecticide fenobucarb, the fungicides hexaconazole and propiconazole and the herbicide pretilachlor. According to the study, the average number of applications of insecticides per rice field and crop has decreased significantly from 1999 to 2007 (3.1 vs 1.4 applications on average for the first crop), while the amount applied per crop decreased less rapidly (0.93 vs 0.77 kg a.i. ha−1) (Berg and Tam, 2012), implying that the treatment frequency decreased by increasing the amount sprayed per treatment. Once released in the environment, pesticides may harm non-target plants and animals as well as human beings (Ohkawa et al., 2007). Although pesticide concentrations in surface water are routinely monitored and assessed in many countries (Azevedo et al., 2004; Ebbert and Embrey, 2002; Müller et al., 2002; Nakano et al., 2004), pesticide monitoring is cost intensive and requires skilled laboratory staff and sophisticated equipment causing large differences between countries with regard to the extent and reliability of monitoring results. In Vietnam, regular state-organized surface water monitoring programs are still focusing on organochlorines and organophosphates. Monitoring is very limited in terms of spatial coverage, sampling frequency and compounds considered (authors' observations and discussions with officers of the Department of Natural Resources and Environment (DONRE) of Can Tho and Dong Thap). Pesticides that are currently in use are not monitored at all or are monitored at very low frequencies. In addition to regularmonitoring programs, several scientific studies have been conducted on pesticide occurrence. For example, DDT was shown to still occur frequently in the environment. DDT concentrations reported for soils and sediments in agricultural areas in North Vietnam ranged from 5 to 28 ng g−1 dry weight (Viet et al., 2000). In the Mekong Delta, DDT was detected in sediment with concentrations ranging from 0.01 to 110 ng g−1 dry weight (Minh et al., 2007). Again in the Mekong Delta among more than 70 monitored pesticides, diazinon, fenitrothion and endosulfan were detected in the water, while DDT, HCH, endosulfan and chlordane occurred in sediment and biota (Carvalho et al., 2008). Since the concentration of DDT was higher close to settlements, Carvalho et al. (2008) attributed this to vector control activities rather than to agricultural use. In contrast, endosulfanwas detected in highest concentrations in rural areaswhere it has been used for agricultural purposes (Carvalho et al., 2008). The studies of Hoai et al. (2011) and Lamers et al. (2011) are among the few in Vietnam which monitored recently used pesticides as opposed to the large amount of studies focusing on organochlorines and organophosphates. Hoai et al. (2011)monitored the occurrence of fenobucarb, trichlorfon, cyfluthrin, and cypermethrin and detected them in environmental samples as well as in vegetable and fish....

    [...]

  • ...Nevertheless, household surveys and environmental monitoring data show continuous evidence of further use of some of these compounds (Berg, 2001; Dung and Dung, 2003; Hoai et al., 2011; Meisner, 2005; Minh et al., 2007; Thuy et al., 2012b). Berg and Tam (2012) recently reported only marginal changes in the top ten list of the a.i. that were most frequently used in 1999 and 2007 in the Mekong Delta. Themost commonly used pesticides in both yearswere the insecticide fenobucarb, the fungicides hexaconazole and propiconazole and the herbicide pretilachlor. According to the study, the average number of applications of insecticides per rice field and crop has decreased significantly from 1999 to 2007 (3.1 vs 1.4 applications on average for the first crop), while the amount applied per crop decreased less rapidly (0.93 vs 0.77 kg a.i. ha−1) (Berg and Tam, 2012), implying that the treatment frequency decreased by increasing the amount sprayed per treatment. Once released in the environment, pesticides may harm non-target plants and animals as well as human beings (Ohkawa et al., 2007). Although pesticide concentrations in surface water are routinely monitored and assessed in many countries (Azevedo et al., 2004; Ebbert and Embrey, 2002; Müller et al., 2002; Nakano et al., 2004), pesticide monitoring is cost intensive and requires skilled laboratory staff and sophisticated equipment causing large differences between countries with regard to the extent and reliability of monitoring results. In Vietnam, regular state-organized surface water monitoring programs are still focusing on organochlorines and organophosphates. Monitoring is very limited in terms of spatial coverage, sampling frequency and compounds considered (authors' observations and discussions with officers of the Department of Natural Resources and Environment (DONRE) of Can Tho and Dong Thap). Pesticides that are currently in use are not monitored at all or are monitored at very low frequencies. In addition to regularmonitoring programs, several scientific studies have been conducted on pesticide occurrence. For example, DDT was shown to still occur frequently in the environment. DDT concentrations reported for soils and sediments in agricultural areas in North Vietnam ranged from 5 to 28 ng g−1 dry weight (Viet et al., 2000). In the Mekong Delta, DDT was detected in sediment with concentrations ranging from 0.01 to 110 ng g−1 dry weight (Minh et al., 2007). Again in the Mekong Delta among more than 70 monitored pesticides, diazinon, fenitrothion and endosulfan were detected in the water, while DDT, HCH, endosulfan and chlordane occurred in sediment and biota (Carvalho et al., 2008). Since the concentration of DDT was higher close to settlements, Carvalho et al. (2008) attributed this to vector control activities rather than to agricultural use. In contrast, endosulfanwas detected in highest concentrations in rural areaswhere it has been used for agricultural purposes (Carvalho et al., 2008). The studies of Hoai et al. (2011) and Lamers et al....

    [...]

  • ...Nevertheless, household surveys and environmental monitoring data show continuous evidence of further use of some of these compounds (Berg, 2001; Dung and Dung, 2003; Hoai et al., 2011; Meisner, 2005; Minh et al., 2007; Thuy et al., 2012b). Berg and Tam (2012) recently reported only marginal changes in the top ten list of the a.i. that were most frequently used in 1999 and 2007 in the Mekong Delta. Themost commonly used pesticides in both yearswere the insecticide fenobucarb, the fungicides hexaconazole and propiconazole and the herbicide pretilachlor. According to the study, the average number of applications of insecticides per rice field and crop has decreased significantly from 1999 to 2007 (3.1 vs 1.4 applications on average for the first crop), while the amount applied per crop decreased less rapidly (0.93 vs 0.77 kg a.i. ha−1) (Berg and Tam, 2012), implying that the treatment frequency decreased by increasing the amount sprayed per treatment. Once released in the environment, pesticides may harm non-target plants and animals as well as human beings (Ohkawa et al., 2007). Although pesticide concentrations in surface water are routinely monitored and assessed in many countries (Azevedo et al., 2004; Ebbert and Embrey, 2002; Müller et al., 2002; Nakano et al., 2004), pesticide monitoring is cost intensive and requires skilled laboratory staff and sophisticated equipment causing large differences between countries with regard to the extent and reliability of monitoring results. In Vietnam, regular state-organized surface water monitoring programs are still focusing on organochlorines and organophosphates. Monitoring is very limited in terms of spatial coverage, sampling frequency and compounds considered (authors' observations and discussions with officers of the Department of Natural Resources and Environment (DONRE) of Can Tho and Dong Thap). Pesticides that are currently in use are not monitored at all or are monitored at very low frequencies. In addition to regularmonitoring programs, several scientific studies have been conducted on pesticide occurrence. For example, DDT was shown to still occur frequently in the environment. DDT concentrations reported for soils and sediments in agricultural areas in North Vietnam ranged from 5 to 28 ng g−1 dry weight (Viet et al., 2000). In the Mekong Delta, DDT was detected in sediment with concentrations ranging from 0.01 to 110 ng g−1 dry weight (Minh et al., 2007). Again in the Mekong Delta among more than 70 monitored pesticides, diazinon, fenitrothion and endosulfan were detected in the water, while DDT, HCH, endosulfan and chlordane occurred in sediment and biota (Carvalho et al., 2008). Since the concentration of DDT was higher close to settlements, Carvalho et al. (2008) attributed this to vector control activities rather than to agricultural use....

    [...]

  • ...Nevertheless, household surveys and environmental monitoring data show continuous evidence of further use of some of these compounds (Berg, 2001; Dung and Dung, 2003; Hoai et al., 2011; Meisner, 2005; Minh et al., 2007; Thuy et al., 2012b). Berg and Tam (2012) recently reported only marginal changes in the top ten list of the a.i. that were most frequently used in 1999 and 2007 in the Mekong Delta. Themost commonly used pesticides in both yearswere the insecticide fenobucarb, the fungicides hexaconazole and propiconazole and the herbicide pretilachlor. According to the study, the average number of applications of insecticides per rice field and crop has decreased significantly from 1999 to 2007 (3.1 vs 1.4 applications on average for the first crop), while the amount applied per crop decreased less rapidly (0.93 vs 0.77 kg a.i. ha−1) (Berg and Tam, 2012), implying that the treatment frequency decreased by increasing the amount sprayed per treatment. Once released in the environment, pesticides may harm non-target plants and animals as well as human beings (Ohkawa et al., 2007). Although pesticide concentrations in surface water are routinely monitored and assessed in many countries (Azevedo et al., 2004; Ebbert and Embrey, 2002; Müller et al., 2002; Nakano et al., 2004), pesticide monitoring is cost intensive and requires skilled laboratory staff and sophisticated equipment causing large differences between countries with regard to the extent and reliability of monitoring results. In Vietnam, regular state-organized surface water monitoring programs are still focusing on organochlorines and organophosphates. Monitoring is very limited in terms of spatial coverage, sampling frequency and compounds considered (authors' observations and discussions with officers of the Department of Natural Resources and Environment (DONRE) of Can Tho and Dong Thap). Pesticides that are currently in use are not monitored at all or are monitored at very low frequencies. In addition to regularmonitoring programs, several scientific studies have been conducted on pesticide occurrence. For example, DDT was shown to still occur frequently in the environment. DDT concentrations reported for soils and sediments in agricultural areas in North Vietnam ranged from 5 to 28 ng g−1 dry weight (Viet et al., 2000). In the Mekong Delta, DDT was detected in sediment with concentrations ranging from 0.01 to 110 ng g−1 dry weight (Minh et al., 2007). Again in the Mekong Delta among more than 70 monitored pesticides, diazinon, fenitrothion and endosulfan were detected in the water, while DDT, HCH, endosulfan and chlordane occurred in sediment and biota (Carvalho et al., 2008). Since the concentration of DDT was higher close to settlements, Carvalho et al. (2008) attributed this to vector control activities rather than to agricultural use. In contrast, endosulfanwas detected in highest concentrations in rural areaswhere it has been used for agricultural purposes (Carvalho et al., 2008). The studies of Hoai et al. (2011) and Lamers et al. (2011) are among the few in Vietnam which monitored recently used pesticides as opposed to the large amount of studies focusing on organochlorines and organophosphates. Hoai et al. (2011)monitored the occurrence of fenobucarb, trichlorfon, cyfluthrin, and cypermethrin and detected them in environmental samples as well as in vegetable and fish. Lamers et al. (2011)monitored the loss of imidacloprid, fenitrothion, fenobucarb, and dichlorvos frompaddy ricefields at thewatershed scale inmountainous regions of North Vietnam and reported runoff losses in the range of 0....

    [...]

  • ...Nevertheless, household surveys and environmental monitoring data show continuous evidence of further use of some of these compounds (Berg, 2001; Dung and Dung, 2003; Hoai et al., 2011; Meisner, 2005; Minh et al., 2007; Thuy et al., 2012b). Berg and Tam (2012) recently reported only marginal changes in the top ten list of the a.i. that were most frequently used in 1999 and 2007 in the Mekong Delta. Themost commonly used pesticides in both yearswere the insecticide fenobucarb, the fungicides hexaconazole and propiconazole and the herbicide pretilachlor. According to the study, the average number of applications of insecticides per rice field and crop has decreased significantly from 1999 to 2007 (3.1 vs 1.4 applications on average for the first crop), while the amount applied per crop decreased less rapidly (0.93 vs 0.77 kg a.i. ha−1) (Berg and Tam, 2012), implying that the treatment frequency decreased by increasing the amount sprayed per treatment. Once released in the environment, pesticides may harm non-target plants and animals as well as human beings (Ohkawa et al., 2007). Although pesticide concentrations in surface water are routinely monitored and assessed in many countries (Azevedo et al., 2004; Ebbert and Embrey, 2002; Müller et al., 2002; Nakano et al., 2004), pesticide monitoring is cost intensive and requires skilled laboratory staff and sophisticated equipment causing large differences between countries with regard to the extent and reliability of monitoring results. In Vietnam, regular state-organized surface water monitoring programs are still focusing on organochlorines and organophosphates. Monitoring is very limited in terms of spatial coverage, sampling frequency and compounds considered (authors' observations and discussions with officers of the Department of Natural Resources and Environment (DONRE) of Can Tho and Dong Thap). Pesticides that are currently in use are not monitored at all or are monitored at very low frequencies. In addition to regularmonitoring programs, several scientific studies have been conducted on pesticide occurrence. For example, DDT was shown to still occur frequently in the environment. DDT concentrations reported for soils and sediments in agricultural areas in North Vietnam ranged from 5 to 28 ng g−1 dry weight (Viet et al., 2000). In the Mekong Delta, DDT was detected in sediment with concentrations ranging from 0.01 to 110 ng g−1 dry weight (Minh et al., 2007). Again in the Mekong Delta among more than 70 monitored pesticides, diazinon, fenitrothion and endosulfan were detected in the water, while DDT, HCH, endosulfan and chlordane occurred in sediment and biota (Carvalho et al., 2008). Since the concentration of DDT was higher close to settlements, Carvalho et al. (2008) attributed this to vector control activities rather than to agricultural use. In contrast, endosulfanwas detected in highest concentrations in rural areaswhere it has been used for agricultural purposes (Carvalho et al., 2008). The studies of Hoai et al. (2011) and Lamers et al. (2011) are among the few in Vietnam which monitored recently used pesticides as opposed to the large amount of studies focusing on organochlorines and organophosphates....

    [...]