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Journal ArticleDOI

Phd by thesis

01 Apr 1988-Nature (Nature Publishing Group)-Vol. 332, Iss: 6166, pp 676-676
TL;DR: In this paper, a sedimentological core and petrographic characterisation of samples from eleven boreholes from the Lower Carboniferous of Bowland Basin (Northwest England) is presented.
Abstract: Deposits of clastic carbonate-dominated (calciclastic) sedimentary slope systems in the rock record have been identified mostly as linearly-consistent carbonate apron deposits, even though most ancient clastic carbonate slope deposits fit the submarine fan systems better. Calciclastic submarine fans are consequently rarely described and are poorly understood. Subsequently, very little is known especially in mud-dominated calciclastic submarine fan systems. Presented in this study are a sedimentological core and petrographic characterisation of samples from eleven boreholes from the Lower Carboniferous of Bowland Basin (Northwest England) that reveals a >250 m thick calciturbidite complex deposited in a calciclastic submarine fan setting. Seven facies are recognised from core and thin section characterisation and are grouped into three carbonate turbidite sequences. They include: 1) Calciturbidites, comprising mostly of highto low-density, wavy-laminated bioclast-rich facies; 2) low-density densite mudstones which are characterised by planar laminated and unlaminated muddominated facies; and 3) Calcidebrites which are muddy or hyper-concentrated debrisflow deposits occurring as poorly-sorted, chaotic, mud-supported floatstones. These

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Citations
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Journal ArticleDOI
TL;DR: In this paper, the authors investigated the pickup velocity required to pick up particles from rest in a pile in the size range of 5-35 μm and found that pickup velocities varied from 3.9 to 16.9 m/s for the range of particle sizes investigated.

71 citations


Cites background or result from "Phd by thesis"

  • ...Although Cabrejos [7] showed that horizontal movement occurs before vertical lift-off, pickup velocity is considered to be the velocity at which the particle becomes entrained in the moving fluid, which implies vertical movement....

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  • ...Cabrejos concluded that pickup velocity is proportional to the square root of particle diameter and particle density to the three-fourths power....

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  • ...Previous research by Cabrejos [7,9],and Cabrejos and Klinzing [10,11] has investigated the effects of certain parameters on the pickup velocity of a pile of particles larger than 100 Am....

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  • ...These results agree with those found by previous research groups [7,9]....

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  • ...Investigation of pickup velocity as a function of particle size shows a minimum in the pickup velocity curve, which agrees with results from previous work [7,9]....

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Journal ArticleDOI
TL;DR: The Genius Test-Facility at the Laboratori Nazionali del Gran Sasso (GENIUS-TF) as discussed by the authors is a large scale detector of rare events that can exclude or directly confirm the DAMA annual modulation seasonal modulation signature within about 2 yr of measurement using both, signal and signature of the claimed WIMP Dark Matter.
Abstract: GENIUS is a proposal for a large scale detector of rare events. As a first step of the experiment, a small test version, the Genius Test-Facility will be built at the Laboratori Nazionali del Gran Sasso. With about 40 kg of natural Ge detectors operated in liquid nitrogen, GENIUS-TF could exclude (or directly confirm) the DAMA annual modulation seasonal modulation signature within about 2 yr of measurement using both, signal and signature of the claimed WIMP Dark Matter. The construction of the experiment has already been started, and four 2.5 kg germanium detectors with an extreme low threshold of 500 eV have been produced.

71 citations


Cites background or methods from "Phd by thesis"

  • ...The signal and high voltage contacts of the individual crystals are established using a minimized amount of ultra pure stainless steel (about 3 g) as already demonstrated in previous experiments [2,12,13]....

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  • ...The background of 6×10−3events/kg yr keV is about a factor of 30 lower than the (raw) background of the Heidelberg-Moscow experiment in the energy region between 2000-2080 keV [12] and can be further reduced by a factor of 3 with pulse shape analysis [8]....

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  • ...Secondary neutron induced interactions in the liquid nitrogen, as well as negative muon capture and inelastic muon scattering reactions generate only a negligible contribution to the overall expected background rate (for details see [2,3,12])....

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Journal ArticleDOI
TL;DR: An equilibrium model is reported that explicitly includes ion pair dissociation and is based upon activities rather than molar concentrations for study of such processes in non-aqueous media, and a method for precise determination of relative binding constants, K(a5), for multiple hosts with a given guest is described.
Abstract: Complexation of anions, cations and even ion pairs is now an active area of investigation in supramolecular chemistry; unfortunately it is an area fraught with complications when these processes are examined in low polarity organic media. Using a pseudorotaxane complex as an example, apparent K(a2) values (=[complex]/{[salt](o)-[complex]}{[host](o)-[complex]}) for pseudorotaxane formation from dibenzylammonium salts (2-X) and dibenzo-[24]crown-8 (1, DB24C8) in CDCl(3)/CD(3)CN 3:2 vary with concentration. This is attributable to the fact that the salt is ion paired, but the complex is not. We report an equilibrium model that explicitly includes ion pair dissociation and is based upon activities rather than molar concentrations for study of such processes in non-aqueous media. Proper analysis requires both a dissociation constant, K(ipd), for the salt and a binding constant for interaction of the free cation 2(+) with the host, K(a5); K(a5) for pseudorotaxane complexation is independent of the counterion (500 M(-1)), a result of the complex existing in solution as a free cation, but K(ipd) values for the salts vary by nearly two orders of magnitude from trifluoroacetate to tosylate to tetrafluoroborate to hexafluorophosphate anions. The activity coefficients depend on the nature of the predominant ions present, whether the pseudorotaxane or the ions from the salt, and also strongly on the molar concentrations; activity coefficients as low as 0.2 are observed, emphasizing the magnitude of their effect. Based on this type of analysis, a method for precise determination of relative binding constants, K(a5), for multiple hosts with a given guest is described. However, while the incorporation of activity coefficients is clearly necessary, it removes the ability to predict from the equilibrium constants the effects of concentration on the extent of binding, which can only be determined experimentally. This has serious implications for study of all such complexation processes in low polarity media.

71 citations


Additional excerpts

  • ...: 192–193 8C, 207– 209 8C([32])); (1)H NMR (CD3CN, 400 MHz): d = 7....

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Journal ArticleDOI
TL;DR: In this paper, the authors describe the application of ESEM to three situations involving aggregating latices, including fractal structures grown from aggregating acrylic latices and the behavior of vinyl latices.

71 citations


Cites background from "Phd by thesis"

  • ...Depth of field is good, as with conventional SEM, so that there is little difficulty associated with imaging a rough surface, but it is not possible to see through a significant layer of water, [27,28]....

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Journal ArticleDOI
TL;DR: In this article, an induced backreaction effect emerges, in general, from correlated fluctuations in the luminosity distance and covariant integration measure, and it is shown that the induced back-reaction is larger than naively expected.
Abstract: Using a recently proposed gauge invariant formulation of light-cone averaging, together with adapted "geodesic light-cone" coordinates, we show how an "induced backreaction" effect emerges, in general, from correlated fluctuations in the luminosity distance and covariant integration measure. Considering a realistic stochastic spectrum of inhomogeneities of primordial (inflationary) origin we find that both the induced backreaction on the luminosity-redshift relation and the dispersion are larger than naively expected. On the other hand the former, at least to leading order and in the linear perturbative regime, cannot account by itself for the observed effects of dark energy at large-redshifts. A full second-order calculation, or even better a reliable estimate of contributions from the non-linear regime, appears to be necessary before firm conclusions on the correct interpretation of the data can be drawn.

71 citations

References
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Journal ArticleDOI
TL;DR: A new family of highly fluorescent indicators has been synthesized for biochemical studies of the physiological role of cytosolic free Ca2+ using an 8-coordinate tetracarboxylate chelating site with stilbene chromophores that offer up to 30-fold brighter fluorescence.

21,582 citations


"Phd by thesis" refers background in this paper

  • ...members of this group were produced by Tsien and colleagues [1, 10, 11]....

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  • ...The introduction of Ca 2+ -sensitive fluorescent dyes more than twenty years ago and their permanent improvement [10] enabled investigators to gain unprecedented insights into the mechanisms of cellular signalling....

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ReportDOI
01 Nov 1990
TL;DR: This report will establish methods for performing a domain analysis and describe the products of the domain analysis process to illustrate the application of domain analysis to a representative class of software systems.
Abstract: : Successful Software reuse requires the systematic discovery and exploitation of commonality across related software systems. By examining related software systems and the underlying theory of the class of systems they represent, domain analysis can provide a generic description of the requirements of that class of systems and a set of approaches for their implementation. This report will establish methods for performing a domain analysis and describe the products of the domain analysis process. To illustrate the application of domain analysis to a representative class of software systems, this report will provide a domain analysis of window management system software.

4,420 citations

Journal ArticleDOI
TL;DR: The straw person model (SPM) as mentioned in this paper has been proposed to explain the orientation effects of active galactic nuclei (AGN) and quasars in the line of sight (LOS) images.
Abstract: Because the critical central regions of Active Galactic Nuclei (AGN) and quasars are strongly nonspherical but spatially unresolved, orientation effects have been the source of much confusion. In fact, it now appears that much of the variety in AGN types is just the result of varying orientation relative to the line of sight. We can define an extreme hypothesis,, the straw person model (SPM), in which there are two basic types of AGN: the radio quiets and the radio louds. For each type there is a range in intrinsic luminosity, and the luminosity controls some properties such as the Fanaroff and Riley classes. However, at a given intrinsic luminosity, all other properties such as spectroscopic classification and VLBI component speeds are ascribed to orientation. This model is only a caricature of the unification idea, and is already ruled out on many grounds, but it will be useful for organizing the discussion. I’ll describe what I consider to be convincing evidence that orientation effects are important and widespread. The true situation may be in some sense half way between the SPM and the hypothesis that orientation doesn’t affect classification at aIl. To us optimists, the orienration cup is half full rather than half empty. Although it is too soon to say for sure, the hypothesis that most objects’ classifications would be different if seen from other directions is a tenable one today.

4,005 citations

Journal ArticleDOI
TL;DR: This Review assembles the current knowledge on the isolation of microfibrillated cellulose from wood and its application in nanocomposites; the preparation of nanocrystalline cellulose and its use as a reinforcing agent; and the biofabrication of bacterial nanocellulose, as well as its evaluation as a biomaterial for medical implants.
Abstract: Cellulose fibrils with widths in the nanometer range are nature-based materials with unique and potentially useful features. Most importantly, these novel nanocelluloses open up the strongly expanding fields of sustainable materials and nanocomposites, as well as medical and life-science devices, to the natural polymer cellulose. The nanodimensions of the structural elements result in a high surface area and hence the powerful interaction of these celluloses with surrounding species, such as water, organic and polymeric compounds, nanoparticles, and living cells. This Review assembles the current knowledge on the isolation of microfibrillated cellulose from wood and its application in nanocomposites; the preparation of nanocrystalline cellulose and its use as a reinforcing agent; and the biofabrication of bacterial nanocellulose, as well as its evaluation as a biomaterial for medical implants.

3,452 citations

Journal ArticleDOI
TL;DR: The solid electrolyte interphase (SEI) is a protecting layer formed on the negative electrode of Li-ion batteries as a result of electrolyte decomposition, mainly during the first cycle as discussed by the authors.

2,386 citations