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Phosphorus ligand exchange equilibriums on zerovalent nickel. Dominant role for steric effects
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This article is published in Journal of the American Chemical Society.The article was published on 1970-05-01. It has received 645 citations till now. The article focuses on the topics: Ligand & Phosphorus.read more
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Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize
TL;DR: This Review attempts to trace the historical origin of these powerful reactions, and outline the developments from the seminal discoveries leading to their eminent position as appreciated and applied today.
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Ligand Bite Angle Effects in Metal-catalyzed C−C Bond Formation
TL;DR: The history of “ligand effects” in catalysis, a range of reactions for which a notable effect has been observed, and some of the established examples of bite angle effects involve diphosphine ligands.
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Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations
TL;DR: The fundamental principles that govern the reactivity of intermediates containing metal-boron bonds are emphasized and how an understanding of the effects of the ligands on this reactivity led us to broaden the scope of main group reagents that react under mild conditions to generate synthetically useful organosilanes is described.
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London Dispersion in Molecular Chemistry—Reconsidering Steric Effects
TL;DR: This Review collects and emphasizes the importance of inter- and intramolecular dispersion for molecules consisting mostly of first row atoms and forces us to reconsider the authors' perception of steric hindrance and stereoelectronic effects.
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Palladiumkatalysierte Kreuzkupplungen: eine historische Perspektive im Kontext der Nobel-Preise 2010
TL;DR: In 2010, Heck, Ei-ichi Negishi and Akira Suzuki were aufgenommen in den illustren Kreis der Chemie-Nobelpreistrager (C-C-Bindungsbildung).