Journal ArticleDOI
Photochemistry of the gaseous hydrogen peroxide—carbon monoxide system. II: Rate constants for hydroxyl radical reactions with hydrocarbons and for hydrogen atom reactions with hydrogen peroxide
R.A. Gorse,David H. Volman +1 more
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In this article, the rate constants for the reaction of hydroxyl with isobutane with other aliphatic hydrocarbons and with other radical rates have been obtained.About:
This article is published in Journal of Photochemistry.The article was published on 1974-01-01. It has received 52 citations till now. The article focuses on the topics: Hydrogen atom abstraction & Hydroxyl radical.read more
Citations
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Journal ArticleDOI
A comprehensive modeling study of hydrogen oxidation
TL;DR: A detailed kinetic mechanism has been developed to simulate the combustion of H2/O2 mixtures, over a wide range of temperatures, pressures, and equivalence ratios as discussed by the authors.
Book ChapterDOI
Rate Coefficients in the C/H/O System
TL;DR: In this article, a critical survey of reaction rate coefficient data important in describing high-temperature combustion of H2, CO, and small hydrocarbons up to C4 is presented.
Journal ArticleDOI
Kinetics of the gas-phase reactions of OH radicals with alkanes and cycloalkanes
TL;DR: In this article, the available database concerning rate constants for gas phase reactions of the hydroxyl (OH) radical with alkanes through early 2003 is presented over the entire temperature range for which measurements have been made.
Journal ArticleDOI
Stratospheric Ozone: An Introduction to Its Study
TL;DR: In this paper, an analysis is made of the various reactions in which ozone and atomic oxygen are involved in the stratosphere, and the predicted effects of these reactions are determined based on the vertical distribution of the H2O, CH4, and H2 dissociation by reaction of these molecules with electronically excited oxygen atom O(¹D).
Journal ArticleDOI
The use of transition-state theory to extrapolate rate coefficients for reactions of H atoms with alkanes
TL;DR: In this paper, the authors developed expressions for estimating structural properties of the activated complex necessary for calculating enthalpies and entropies of activation, which are consistent with the experimental data and with the calculations.
References
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Journal ArticleDOI
Hydroxyl Radical Kinetics by Kinetic Spectroscopy. VI. Reactions with Alkanes in the Range 300–500°K
TL;DR: In this paper, the reactivity of OH radicals toward a representative set of alkanes was studied and the following formula was found to reproduce accurately all of the observed abstraction rate constants for the 10 model alkanes: ktot is the total rate constant for the abstraction of H atoms from the alkane.
Journal ArticleDOI
Mass-spectrometric study of the reactions of the hydroxyl radical with ethylene, propylene, and acetaldehyde in a discharge-flow system
Journal ArticleDOI
Photochemistry of the gaseous hydrogen peroxide-carbon monoxide system: Rate constants for hydroxyl radical reactions with hydrogen peroxide and isobutane by competitive kinetics
R.A. Gorse,David H. Volman +1 more
TL;DR: In this article, the reaction between hydrogen peroxide and carbon monoxide initiated by absorption of 254 nm light at 298 K in a static system has been studied and the rate constant ratio was found to be kH2O/kH2 = 3.0 ± 1.0.
Related Papers (5)
Hydroxyl Radical Kinetics by Kinetic Spectroscopy. VI. Reactions with Alkanes in the Range 300–500°K
Mass-spectrometric study of the reactions of the hydroxyl radical with ethylene, propylene, and acetaldehyde in a discharge-flow system
Rate constants for the reaction of OH radicals with propylene and the butenes over the temperature range 297–425 °K
R. Atkinson,J. N. Pitts +1 more