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Journal ArticleDOI

Photolysis of atmospheric ozone in the ultraviolet region.

Yutaka Matsumi, +1 more
- 06 Nov 2003 - 
- Vol. 103, Iss: 12, pp 4767-4781
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TLDR
The near-ultraviolet (UV) photochemistry of ozone remains a topic of great contemporary interest and research interests include chemical reaction processes in the atmosphere and development of instruments for atmospheric gases and particles.
Abstract
The near-ultraviolet (UV) photochemistry of ozone remains a topic of great contemporary interest. Figure 1 shows the absorption spectrum of ozone in the UV region between 195 and 345 nm at 295 K, which is plotted using the data measured by Malicet et al.1 The UV absorption spectrum of O3 consists of two bands. The wide bell-shaped absorption peaking at approximately 250 nm is called the Hartley band. The vibrational structure in the long wavelength edge of Hartley band in the 310-360 nm region is called the Huggins band. Table 1 lists the threshold wavelengths for the dissociation processes to various * To whom correspondence should be addressed. Fax: +81-53389-5593. E-mail: matsumi@stelab.nagoya-u.ac.jp. Yutaka Matsumi earned his doctorate degree in Chemistry at Tokyo Institute of Technology in 1981. After he spent several years in private companies, he was an associate professor at Hokkaido University for nine years. He has been at the Solar-Terrestrial Environment Laboratory at Nagoya University since 1997. His research interests include chemical reaction processes in the atmosphere and development of instruments for atmospheric gases and particles.

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Citations
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Real-time, local basis-set implementation of time-dependent density functional theory for excited state dynamics simulations.

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Ultraviolet Spectrum and Photochemistry of the Simplest Criegee Intermediate CH2OO

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Absolute Ultraviolet Absorption Spectrum of a Criegee Intermediate CH2OO

TL;DR: This work presents the time-resolved UV absorption spectrum of the B̃ ((1)A') ← X̃(A)') electronic transition of formaldehyde oxide,CH2OO, produced by the reaction of CH2I radicals with O2, and establishes the identity of the absorbing species as CH2OO.
Journal ArticleDOI

New theoretical investigations of the photodissociation of ozone in the Hartley, Huggins, Chappuis, and Wulf bands

TL;DR: This work reviews recent theoretical studies of the photodissociation of ozone in the wavelength region from 200 nm to 1100 nm comprising four major absorption bands and analysis of diffuse vibrational structures, which are prominent in all absorption bands.
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Ozonation in water treatment: the generation, basic properties of ozone and its practical application

TL;DR: In this paper, the authors present a summary concerning ozone generation mechanisms, the physicochemical properties of ozone, as well as the applications of ozone in water treatment, and future directions concerning the development of ozone generation, ozone reactivity, and industrial wastewater ozonation.
References
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Chemical kinetics and photochemical data for use in stratospheric modeling

TL;DR: As part of a series of evaluated sets, rate constants and photochemical cross sections compiled by the NASA Panel for Data Evaluation are provided in this article, with particular emphasis on the ozone layer and its possible perturbation by anthropogenic and natural phenomena.

Chemical kinetics and photochemical data for use in stratospheric modeling

TL;DR: As part of a series of evaluated sets, rate constants and photochemical cross sections compiled by the NASA Panel for Data Evaluation are provided in this paper, with particular emphasis on the ozone layer and its possible perturbation by anthropogenic and natural phenomena.
Journal ArticleDOI

Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry: Supplement VI. IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry

TL;DR: In this paper, the IUPAC Subcommittee on Gas Phase Kinetic Data Evaluation for Atmospheric Chemistry has published a data set for 151 thermal and photochemical reactions, containing summaries of the available experimental data with notes giving details of the experimental procedures.
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