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Open AccessJournal ArticleDOI

Photopolymerization in 3D Printing

Ali Bagheri, +1 more
- Vol. 1, Iss: 4, pp 593-611
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TLDR
The field of 3D printing is continuing its rapid development in both academic and industrial research environments as mentioned in this paper, which offers flexibility over the final properties of the 3D printed materials (such as optical, chemical and mechanical properties) using versatile polymer chemistry.
Abstract
The field of 3D printing is continuing its rapid development in both academic and industrial research environments. The development of 3D printing technologies has opened new implementations in rapid prototyping, tooling, dentistry, microfluidics, biomedical devices, tissue engineering, drug delivery, etc. Among different 3D printing techniques, photopolymerization-based process (such as stereolithography and digital light processing) offers flexibility over the final properties of the 3D printed materials (such as optical, chemical, and mechanical properties) using versatile polymer chemistry. The strategy behind the 3D photopolymerization is based on using monomers/oligomers in liquid state (in the presence of photoinitiators) that can be photopolymerized (via radical or cationic mechanism) upon exposure to light source of different wavelengths (depending on the photoinitiator system). An overview of recent evolutions in the field of photopolymerization-based 3D printing and highlights of novel 3D print...

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Citations
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Journal ArticleDOI

UV-Resistant Self-Healing Emulsion Glass as a New Liquid-like Solid Material for 3D Printing.

TL;DR: The emulsion glass has been repeatedly used at least 6 times upon exposure to UV irradiation and heat, implying it can expand the applications of supporting medium to the writing process involving UV- and thermal-curable inks simultaneously.
Journal ArticleDOI

Recent Advances on Visible Light Coumarin-based Oxime Esters as Initiators of Polymerization

TL;DR: An overview of the recent development concerning coumarin-based oxime esters is presented in this article , where a comparison with reference compounds is made to evidence the interest of coumarins as light absorbing materials for the design of oxime ensembles.
Journal ArticleDOI

Recent Trends in Advanced Photoinitiators for Vat Photopolymerization 3D Printing.

TL;DR: A review of the development and application of advanced photoinitiators and photo-initiating systems for vat photopolymerization 3D printing, with a wide range of small molecules, polymers and nanoassemblies involved, can be found in this paper .
Journal ArticleDOI

Xanthate-Based Photoiniferter RAFT Polymerization toward Oxygen-Tolerant and Rapid Living 3D Printing

- 15 Feb 2022 - 
TL;DR: In this paper , a photoiniferter RAFT polymerization-based living 3D printing method was also successfully applied to a commercial digital light processing technique-based 3D printer, offering a facile method to fabricate living objects with different shapes.
Journal ArticleDOI

Photoinduced ring-opening polymerizations

TL;DR: In this article, the authors present an overview of the spectrum of cyclic monomers that have been polymerized by light-induced polymerization processes, with an emphasis on the properties of resulting materials.
References
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Journal ArticleDOI

Thiol–Ene Click Chemistry

TL;DR: The radical-mediated thiol-ene reaction has all the desirable features of a click reaction, being highly efficient, simple to execute with no side products and proceeding rapidly to high yield.
Journal ArticleDOI

Hydrogels as Extracellular Matrix Mimics for 3D Cell Culture

TL;DR: The use of both synthetic and natural hydrogels as scaffolds for three-dimensional cell culture as well as synthetic hydrogel hybrids that incorporate sophisticated biochemical and mechanical cues as mimics of the native extracellular matrix are discussed.
Journal ArticleDOI

Polymers for 3D Printing and Customized Additive Manufacturing

TL;DR: Polymers are by far the most utilized class of materials for AM and their design, additives, and processing parameters as they relate to enhancing build speed and improving accuracy, functionality, surface finish, stability, mechanical properties, and porosity are addressed.
Journal ArticleDOI

3D printing of polymer matrix composites: A review and prospective

TL;DR: In this paper, the authors give an overview on 3D printing techniques of polymer composite materials and the properties and performance of 3D printed composite parts as well as their potential applications in the fields of biomedical, electronics and aerospace engineering.
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