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Photopolymerization in 3D Printing

Ali Bagheri, +1 more
- Vol. 1, Iss: 4, pp 593-611
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TLDR
The field of 3D printing is continuing its rapid development in both academic and industrial research environments as mentioned in this paper, which offers flexibility over the final properties of the 3D printed materials (such as optical, chemical and mechanical properties) using versatile polymer chemistry.
Abstract
The field of 3D printing is continuing its rapid development in both academic and industrial research environments. The development of 3D printing technologies has opened new implementations in rapid prototyping, tooling, dentistry, microfluidics, biomedical devices, tissue engineering, drug delivery, etc. Among different 3D printing techniques, photopolymerization-based process (such as stereolithography and digital light processing) offers flexibility over the final properties of the 3D printed materials (such as optical, chemical, and mechanical properties) using versatile polymer chemistry. The strategy behind the 3D photopolymerization is based on using monomers/oligomers in liquid state (in the presence of photoinitiators) that can be photopolymerized (via radical or cationic mechanism) upon exposure to light source of different wavelengths (depending on the photoinitiator system). An overview of recent evolutions in the field of photopolymerization-based 3D printing and highlights of novel 3D print...

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Citations
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Journal ArticleDOI

Recent advances on photobleachable visible light photoinitiators of polymerization

TL;DR: An overview of the recent advances on photobleachable photoinitiators is provided in this article , where a wide range of structures have been explored and an overview of different structures is given.
Journal ArticleDOI

Stereochemistry-Controlled Mechanical Properties and Degradation in 3D-Printable Photosets.

TL;DR: In this article, the authors exploit cis and trans stereochemistry in pre-resin oligomers to create photoset materials with mechanical properties and degradation rates that are controlled by their stereochemistry and molecular weight.
Journal ArticleDOI

Reconfigurable Polymer Networks for Digital Light Processing 3D Printing.

TL;DR: In this paper, a reconfigurable polymer network that is compatible with digital light processing (DLP) 3D printing is presented, which decouples the printing process and the final material properties, providing an efficient approach to print various functional objects.
Journal ArticleDOI

New horizons for carbon dots: quantum nano-photoinitiating catalysts for cationic photopolymerization and three-dimensional (3D) printing under visible light

TL;DR: In this paper, the application of various citric acid-based carbon dots (CDs) as efficient photosensitizers of iodonium salts in initiating the light-induced cationic polymerization process was investigated.
Journal ArticleDOI

Integrated lab-on-a-chip devices: Fabrication methodologies, transduction system for sensing purposes.

TL;DR: In this paper , a review of different types of fabrication methods and techniques such as photolithography, soft lithography, screen printing, inkjet printing, laser micromachining, nanoimprinting, and nano-printing are discussed.
References
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Journal ArticleDOI

Thiol–Ene Click Chemistry

TL;DR: The radical-mediated thiol-ene reaction has all the desirable features of a click reaction, being highly efficient, simple to execute with no side products and proceeding rapidly to high yield.
Journal ArticleDOI

Hydrogels as Extracellular Matrix Mimics for 3D Cell Culture

TL;DR: The use of both synthetic and natural hydrogels as scaffolds for three-dimensional cell culture as well as synthetic hydrogel hybrids that incorporate sophisticated biochemical and mechanical cues as mimics of the native extracellular matrix are discussed.
Journal ArticleDOI

Polymers for 3D Printing and Customized Additive Manufacturing

TL;DR: Polymers are by far the most utilized class of materials for AM and their design, additives, and processing parameters as they relate to enhancing build speed and improving accuracy, functionality, surface finish, stability, mechanical properties, and porosity are addressed.
Journal ArticleDOI

3D printing of polymer matrix composites: A review and prospective

TL;DR: In this paper, the authors give an overview on 3D printing techniques of polymer composite materials and the properties and performance of 3D printed composite parts as well as their potential applications in the fields of biomedical, electronics and aerospace engineering.
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