Photopolymerization in 3D Printing
20 Feb 2019-Vol. 1, Iss: 4, pp 593-611
TL;DR: The field of 3D printing is continuing its rapid development in both academic and industrial research environments as mentioned in this paper, which offers flexibility over the final properties of the 3D printed materials (such as optical, chemical and mechanical properties) using versatile polymer chemistry.
Abstract: The field of 3D printing is continuing its rapid development in both academic and industrial research environments. The development of 3D printing technologies has opened new implementations in rapid prototyping, tooling, dentistry, microfluidics, biomedical devices, tissue engineering, drug delivery, etc. Among different 3D printing techniques, photopolymerization-based process (such as stereolithography and digital light processing) offers flexibility over the final properties of the 3D printed materials (such as optical, chemical, and mechanical properties) using versatile polymer chemistry. The strategy behind the 3D photopolymerization is based on using monomers/oligomers in liquid state (in the presence of photoinitiators) that can be photopolymerized (via radical or cationic mechanism) upon exposure to light source of different wavelengths (depending on the photoinitiator system). An overview of recent evolutions in the field of photopolymerization-based 3D printing and highlights of novel 3D print...
Citations
More filters
TL;DR: In this paper, the upconversion nanoparticles (UCNPs) represent a class of optical nanomaterials that are able to convert low-energy near-infrared (NIR) light into high-energy ultraviolet (or visible light) emissions.
Abstract: Photopolymerization refers to a type of polymerization process in which light is utilized as excitation source to initiate polymerization of monomers and oligomers. Despite great progress, photopolymerization is typically induced by ultraviolet or visible light, which still greatly restrains its applications. Upconversion nanoparticles (UCNPs) represent a class of optical nanomaterials that are able to convert low-energy near-infrared (NIR) light into high-energy ultraviolet (or visible light) emissions. In this context, UCNP-assisted photopolymerization has recently attracted extensive attentions due to its unique advantages. In this account, recent advances in the fundamentals, optimization and emerging applications of UCNP-based photopolymerization are reviewed. Fundamental theories of upconversion luminescence and photopolymerization will be introduced first. Various optimization approaches to improve UCNP-assisted photopolymerization are then summarized, followed by diverse emerging applications. Challenges and future perspectives in this area will be provided as a conclusion.
11 citations
TL;DR: In this article, the synthesis of new visible-light photosensitizers derived from purpurin (mono-allyl- and trially l-purpurin), and their use as type II photoinitiating systems when associated with N-methyldiethanolamine, bis(4-methylphenyl) iodonium hexafluorophosphate or tri-functionalized thiol (trimethylolpropane tris(3-mercaptopropionate)) for cationic and free-radical photopolymerization
11 citations
TL;DR: In this article , a photo-polymerizable resin material for 3D printing dental applications and compare it with three commercially available resins, Die and Model Tan (SprintRay), Formlabs Grey (FormLabs), and LCD Grey (Roxel 3D) were evaluated and tested for volumetric shrinkage, accuracy, and flexural and tensile properties.
11 citations
TL;DR: In this paper, the 3D inkjet printing process was investigated as a technique for the fabrication of microlenses and identified the key components and methodologies which can be used to control the properties of the resultant microlens.
Abstract: The demand for optical components such as microlenses has been growing at a rapid rate in recent years. While conventional methods for manufacturing these components are well known, they are often time-consuming, detrimental for the environment and unable to keep up with the increasing demand. To overcome these issues, the technique of three-dimensional (3D) inkjet printing has attracted much attention. The aim of this review was to investigate the 3D inkjet printing process as a technique for the fabrication of microlenses and identify the key components and methodologies which can be used to control the properties of the resultant microlenses. 3D Inkjet printing was identified as a viable alternative for the production of microlenses owing to its high flexibility, scalability and efficiency as well as its ability to produce good quality products. Substrate modification was shown as a key method by which the geometric and optical properties of microlenses can be controlled. Organic materials such as acrylates and epoxies, and hybrid materials such as siloxanes were shown to be the most common base materials in photo-crosslinkable inkjet formulations and the effects of incorporation of organic compounds and inorganic nanoparticles on the material refractive index were studied.
10 citations
24 Jun 2020
TL;DR: In this article, high functional bio-based methacrylate and acrylate resins were synthesized from epoxidized sucrose soyate (ESS) and incorporated into formulations for stereolithographic (SLA) printing.
Abstract: Highly functional bio-based methacrylate and acrylate resins were synthesized from epoxidized sucrose soyate (ESS) and incorporated into formulations for stereolithographic (SLA) printing. These fo...
10 citations
References
More filters
TL;DR: The radical-mediated thiol-ene reaction has all the desirable features of a click reaction, being highly efficient, simple to execute with no side products and proceeding rapidly to high yield.
Abstract: Following Sharpless' visionary characterization of several idealized reactions as click reactions, the materials science and synthetic chemistry communities have pursued numerous routes toward the identification and implementation of these click reactions. Herein, we review the radical-mediated thiol-ene reaction as one such click reaction. This reaction has all the desirable features of a click reaction, being highly efficient, simple to execute with no side products and proceeding rapidly to high yield. Further, the thiol-ene reaction is most frequently photoinitiated, particularly for photopolymerizations resulting in highly uniform polymer networks, promoting unique capabilities related to spatial and temporal control of the click reaction. The reaction mechanism and its implementation in various synthetic methodologies, biofunctionalization, surface and polymer modification, and polymerization are all reviewed.
3,229 citations
TL;DR: The use of both synthetic and natural hydrogels as scaffolds for three-dimensional cell culture as well as synthetic hydrogel hybrids that incorporate sophisticated biochemical and mechanical cues as mimics of the native extracellular matrix are discussed.
Abstract: Methods for culturing mammalian cells ex vivo are increasingly needed to study cell and tissue physiology and to grow replacement tissue for regenerative medicine. Two-dimensional culture has been the paradigm for typical in vitro cell culture; however, it has been demonstrated that cells behave more natively when cultured in three-dimensional environments. Permissive, synthetic hydrogels and promoting, natural hydrogels have become popular as three-dimensional cell culture platforms; yet, both of these systems possess limitations. In this perspective, we discuss the use of both synthetic and natural hydrogels as scaffolds for three-dimensional cell culture as well as synthetic hydrogels that incorporate sophisticated biochemical and mechanical cues as mimics of the native extracellular matrix. Ultimately, advances in synthetic-biologic hydrogel hybrids are needed to provide robust platforms for investigating cell physiology and fabricating tissue outside of the organism.
2,298 citations
2,276 citations
TL;DR: Polymers are by far the most utilized class of materials for AM and their design, additives, and processing parameters as they relate to enhancing build speed and improving accuracy, functionality, surface finish, stability, mechanical properties, and porosity are addressed.
Abstract: Additive manufacturing (AM) alias 3D printing translates computer-aided design (CAD) virtual 3D models into physical objects. By digital slicing of CAD, 3D scan, or tomography data, AM builds objects layer by layer without the need for molds or machining. AM enables decentralized fabrication of customized objects on demand by exploiting digital information storage and retrieval via the Internet. The ongoing transition from rapid prototyping to rapid manufacturing prompts new challenges for mechanical engineers and materials scientists alike. Because polymers are by far the most utilized class of materials for AM, this Review focuses on polymer processing and the development of polymers and advanced polymer systems specifically for AM. AM techniques covered include vat photopolymerization (stereolithography), powder bed fusion (SLS), material and binder jetting (inkjet and aerosol 3D printing), sheet lamination (LOM), extrusion (FDM, 3D dispensing, 3D fiber deposition, and 3D plotting), and 3D bioprinting....
2,136 citations
TL;DR: In this paper, the authors give an overview on 3D printing techniques of polymer composite materials and the properties and performance of 3D printed composite parts as well as their potential applications in the fields of biomedical, electronics and aerospace engineering.
Abstract: The use of 3D printing for rapid tooling and manufacturing has promised to produce components with complex geometries according to computer designs. Due to the intrinsically limited mechanical properties and functionalities of printed pure polymer parts, there is a critical need to develop printable polymer composites with high performance. 3D printing offers many advantages in the fabrication of composites, including high precision, cost effective and customized geometry. This article gives an overview on 3D printing techniques of polymer composite materials and the properties and performance of 3D printed composite parts as well as their potential applications in the fields of biomedical, electronics and aerospace engineering. Common 3D printing techniques such as fused deposition modeling, selective laser sintering, inkjet 3D printing, stereolithography, and 3D plotting are introduced. The formation methodology and the performance of particle-, fiber- and nanomaterial-reinforced polymer composites are emphasized. Finally, important limitations are identified to motivate the future research of 3D printing.
2,132 citations