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Photopolymerization in 3D Printing

Ali Bagheri, +1 more
- Vol. 1, Iss: 4, pp 593-611
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TLDR
The field of 3D printing is continuing its rapid development in both academic and industrial research environments as mentioned in this paper, which offers flexibility over the final properties of the 3D printed materials (such as optical, chemical and mechanical properties) using versatile polymer chemistry.
Abstract
The field of 3D printing is continuing its rapid development in both academic and industrial research environments. The development of 3D printing technologies has opened new implementations in rapid prototyping, tooling, dentistry, microfluidics, biomedical devices, tissue engineering, drug delivery, etc. Among different 3D printing techniques, photopolymerization-based process (such as stereolithography and digital light processing) offers flexibility over the final properties of the 3D printed materials (such as optical, chemical, and mechanical properties) using versatile polymer chemistry. The strategy behind the 3D photopolymerization is based on using monomers/oligomers in liquid state (in the presence of photoinitiators) that can be photopolymerized (via radical or cationic mechanism) upon exposure to light source of different wavelengths (depending on the photoinitiator system). An overview of recent evolutions in the field of photopolymerization-based 3D printing and highlights of novel 3D print...

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Journal ArticleDOI

A review of vat photopolymerization technology: Materials, applications, challenges, and future trends of 3D printing

TL;DR: In this article, three photopolymerization technologies, namely, stereolithography (SLA), digital light processing (DLP), and continuous digital light process (CDLP), are reviewed.
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Projection micro stereolithography based 3D printing and its applications

TL;DR: This review paper summarizes a few typical applications of P μSL including mechanical metamaterials, optical components, 4D printing, bioinspired materials and biomedical applications, and offers perspectives on the directions of the further development of PμSL based 3D printing technology.
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Crosslinking Strategies for 3D Bioprinting of Polymeric Hydrogels

TL;DR: In this work, crosslinking methods used in 3D bioprinting studies are reviewed, parameters that affect bioink chemistry are discussed, and the potential toward improving crossl linking outcomes and construct performance is highlighted.
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4D Printing of a Bioinspired Microneedle Array with Backward‐Facing Barbs for Enhanced Tissue Adhesion

TL;DR: Improved tissue adhesion of the bioinspired MN allows for more stable and robust performance for drug delivery, biofluid collection, and biosensing.
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Vat photopolymerization 3D printing for advanced drug delivery and medical device applications

TL;DR: An overview of the vat polymerization techniques, their unique applications in the fields of drug delivery and medical device fabrication, material examples and the advantages they provide within healthcare, is provided.
References
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Journal ArticleDOI

Visible Light Photoinitiator for 3D-Printing of Tough Methacrylate Resins.

TL;DR: The influence of photoinitiator selection and post-processing on the thermomechanical properties of various tough photopolymers and the correlation between double-bond conversion, yield strength, and glass transition temperature was found.
Journal ArticleDOI

Photoreversible Covalent Hydrogels for Soft-Matter Additive Manufacturing.

TL;DR: Copolymerization of coumarin-containing monomers with the hydrophilic comonomer N, N-dimethylacrylamide yielded water-soluble, linear polymers that could be cured with long-wave UV light into free-standing hydrogels, even in the absence of a photoinitiator.
Journal ArticleDOI

3D printable light-responsive polymers

TL;DR: In this paper, photo-curable polymers for 3D printing are provided, exhibiting mechanical light-responsivity upon laser irradiation, which can be spatially controlled in order to locally modify the mechanical features of 3D printed objects such as microcantilevers.
Journal ArticleDOI

Copper photoredox catalysts for polymerization upon near UV or visible light: structure/reactivity/efficiency relationships and use in LED projector 3D printing resins

TL;DR: In this paper, the structure/reactivity/efficiency relationships for the copper complexes are studied as well as the chemical mechanisms involved and different substituents on the pyrazole moiety of the ligand allow tuning of the oxidation potential and the visible light absorbance of the complexes and to optimize the performance of the polymerization photoredox catalysts.
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