Polymerization of thiophene containing cyclobutadiene Co cyclopentadiene complexes
TL;DR: In this article, a series of cyclobutadiene cobalt cyclopentadiene (CbCoCp) complexes containing electrochemically polymerizable thiophene units were synthesized.
About: This article is published in Synthetic Metals.The article was published on 2006-06-01. It has received 11 citations till now. The article focuses on the topics: Cyclobutadiene & Thiophene.
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TL;DR: In this article, the evolution of organotransition metal electrochemistry from its origin with ferrocene to its promise in future applications is presented, where key findings on the relationships of electron transfer to molecular structures and to the reactions of OMT metal complexes are given.
205 citations
TL;DR: Recent developments in the field of synthesis and potential applications of metal-functionalized polymers obtained via electropolymerization are presented, highlighting the significant advances in this field of research.
Abstract: Electropolymerization represents a suitable and well-established approach for the assembly of polymer structures, in particular with regard to the formation of thin, insoluble films. Utilization of monomers that are functionalized with metal complex units allows the combination of structural and functional benefits of polymers and metal moieties. Since a broad range of both electropolymerizable monomers and metal complexes are available, various structures and, thus, applications are possible. Recent developments in the field of synthesis and potential applications of metal-functionalized polymers obtained via electropolymerization are presented, highlighting the significant advances in this field of research.
110 citations
TL;DR: Acrylate derivatives of these compounds were found to polymerize giving rise to the first example of polymers containing neutral, 18 e cobaltoarenocenes in the side chain.
36 citations
TL;DR: In this paper, the authors employed both as an analytical instrumental technique and as a method of inducing changes in the structure and reactivity of organometallic complexes, which is the primary implemen...
34 citations
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907 citations
TL;DR: In this article, the potential that organometallic architectures consisting of two transition metal centers linked by an organic unsaturated spacer present for the study and development of new molecular wires is discussed.
551 citations
TL;DR: In this paper, a chemically derivatized microelectrode array that can function as a transistor when immersed in an electrolyte solution is described, and the key finding is that a small signal (charge) needed to turn on the device can be amplified.
Abstract: : This document reports the fabrication of a chemically derivatized microelectrode array that can function as a transistor when immersed in an electrolyte solution. The key finding is that a small signal (charge) needed to turn on the device can be amplified. The device to be described MIMICS the fundamental characteristics of solid state transistor, since the resistance between to contacts can be varied by a signal to be amplified. The chemical transistor is the set of three (drain, gate, and source) Au microelectroces covered by polypyrrole.
502 citations
01 Sep 1984
TL;DR: In this article, a chemically derivatized microelectrode array that can function as a transistor when immersed in an electrolyte solution is described, and the key finding is that a small signal (charge) needed to turn on the device can be amplified.
Abstract: : This document reports the fabrication of a chemically derivatized microelectrode array that can function as a transistor when immersed in an electrolyte solution. The key finding is that a small signal (charge) needed to turn on the device can be amplified. The device to be described MIMICS the fundamental characteristics of solid state transistor, since the resistance between to contacts can be varied by a signal to be amplified. The chemical transistor is the set of three (drain, gate, and source) Au microelectroces covered by polypyrrole.
413 citations