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Polyoxometalate chemistry : from topology via self-assembly to applications
Michael T. Pope,Achim Müller +1 more
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A.M. Proust, R.Proust and R.Villaneau as mentioned in this paper discuss the history of polyoxometalates and their application in the field of chemical engineering.Abstract:
Introduction to Polyoxometalate Chemistry: From Topology via Self-Assembly to Applications M.T. Pope, A. Muller. Synthetic Strategies. 1. Rational Approaches to Polyoxometalate Synthesis R.J. Errington. 2. Functionalization of Polyoxometalates: Achievements and Perspectives A. Proust, R. Villaneau. 3. From the First Sulfurated Keggin Anion to a New Class of Compounds Based on the [M2O2S2 2+ Building Block M-Mo,W E. Cadot, et al. 4. Organometallic Oxometal Clusters A. Proust, et al. Structures: Molecular and Electronic. 5. Spherical (Icosahedral) Objects in Nature and Deliberately Constructable Molecular Keplerates: Structural and Topological Aspects O. Delgado, et al. 6. Synthesis and Crystal Structure Studies of Novel Selenium- and Tellurium-Substituted Lacunary Polyoxometalates B. Krebs, et al. 7. Vibrational Spectroscopy of Heteropoly Acids H. Ratajczak, et al. 8. Bond-Stretch Isomerism in Polyoxometalates? M.-M. Rohmer, et al. 9. Quantum-Chemical Studies of Electron Transfer in Transition-Metal Substituted Polyoxometalates S.A. Borshch, H. Duclusaud. Solution Equilibria and Dynamics. 10. Aqueous Peroxoisopolyoxometalates O.W. Howarth, et al. 11. Molybdate Speciation in Systems Related to the Bleaching of Kraft Pulp F. Taube, et al. 12. NMR Studies of Various Ligands Coordinated to Paramagnetic Polyoxometalates B.A. Kim, H. So. From Discrete Clusters to Networks and Materials. 13. Molecular Aspect of EnergyTransfer from Tb3+ to Eu3+ in the Polyoxometalate Lattices: An Approach for Molecular Design of Rare-Earth Metal-Oxide Phosphors T. Yamase. 14. Conducting and Magnetic Organic / Inorganic Molecular Materials Based on Polyoxometalates L. Ouahab, et al. 15. Molecular Materials From Polyoxometalates J.J. Borras-Almenar, et al. 16. Framework Materials Composed of Transition Metal Oxide Clusters M.I. Khan. 17. Perspectives in the Solid State Coordination Chemistry of the Molybdenum Oxides P.J. Hagrman, et al. 18. Polyoxometalate Clusters in a Supramolecular Self-Organized Environment: Steps Towards Functional Nanodevices and Thin Film Applications D.G. Kurth, D. Volkmer. 19. Polyoxometalate Chemistry: A Source for Unusual Spin Topologies D. Gatteschi, et al. 20. Heteropolyanions: Molecular Building Blocks for Ultrathin Oxide Films J.D. Powell, et al. Applications: Catalysis, Biological Systems, Environmental Studies. 21. Selective Oxidation of Hydrocarbons with Hydrogen Peroxide Catalyzed by Iron-substituted Silicotungstates N. Mizuno. 22. Aerobic Oxidations Catalyzed by Polyoxometalates A.M. Khenkin, et al. 23. Polyoxoanions in Catalysis: From Record Catalytic Lifetime Nanocluster Catalysis to Record Catalytic Lifetime Catechol Dioxygenase Catalysis R.G. Finke. 24. Ribosomal Crystallography and Heteropolytungstates D. Janell, et al. 25. Photocatalytic Decontamination by Polyoxometalates A. Hiskia, et al. Index.read more
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Journal ArticleDOI
Polyoxometalate Embedding of a Tetraruthenium(IV)-oxo-core by Template-Directed Metalation of [γ-SiW10O36]8−: A Totally Inorganic Oxygen-Evolving Catalyst
Andrea Sartorel,Mauro Carraro,Gianfranco Scorrano,Rita De Zorzi,Silvano Geremia,Neal D. McDaniel,Stefan Bernhard,Marcella Bonchio +7 more
TL;DR: Solid state and solution evidence confirms the embedding of an adamantane-like, Ru4O6 fragment by the divacant, gamma-decatungstosilicate ligand in the resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h-1.
Journal ArticleDOI
Polyoxometalates: Fascinating structures, unique magnetic properties
Ulrich Kortz,Achim Müller,Joris van Slageren,Joris van Slageren,Jürgen Schnack,Naresh S. Dalal,Martin Dressel +6 more
TL;DR: In this article, several discrete molecular transition metal and lanthanide-containing polyoxo-tungstates and -molybdates with a focus on their magnetic properties are reported.
Journal ArticleDOI
Polyoxometalates: introduction to a class of inorganic compounds and their biomedical applications.
TL;DR: The reported antitumoral and antibiotic properties of molybdates and tungstates in vitro and in vivo are compiled and discussed, as are their influences on the blood glucose level in diabetic animals.
Journal ArticleDOI
Progress and challenges in polyoxometalate-based catalysis and catalytic materials chemistry
TL;DR: In this paper, the impact of early transition-metal oxygen-anion cluster (polyoxometalate or “POM”) geometric and electronic structural properties on POM-based catalysis is addressed.
Journal ArticleDOI
From linking of metal-oxide building blocks in a dynamic library to giant clusters with unique properties and towards adaptive chemistry
Achim Müller,Pierre Gouzerh +1 more
TL;DR: The present review presents the first comprehensive report of current knowledge (including synthesis aspects not discussed before) regarding the related giant metal-oxide clusters mainly of the type {Mo(57)M'(6)} (M' = Fe(III), V(IV)) (torus structure),
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