Polyoxometalates : from platonic solids to anti-retroviral activity

TLDR: Polyoxometalates: A Class of Compounds with Remarkable Topology as discussed by the authors, a class of compounds with remarkable topology, have been shown to have remarkable properties.

Abstract: Polyoxometalates: A Class of Compounds with Remarkable Topology.- A: Formation and Structure.- Equilibria of Polyoxometalates in Aqueous Solution.- Synthesis and Structural Chemistry of Novel Heteropolymolybdates and -tungstates.- Progress in Polytungstophosphate and -arsenate(V) Chemistry.- Crystal Structure Studies of Isopoly and Heteropoly Oxometalates. Structure of the Paradodecatungstate Molecule and Its Environment in Crystals.- Polyoxoanion-Supported Organometallic Complexes.- New Aspects of Non-Aqueous Polyoxometalate Chemistry.- Functionalization of Polyoxomolybdates: the Example of Nitrosyl Derivatives.- Polyoxoalkoxy Molybdenum and Vanadium Clusters.- Polyoxovanadates with Organic Ligands.- B: Spectroscopy and Magnetochemistry.- New Aspects of NMR Spectroscopy of Polyoxometalates.- Polyoxotungstates with Lone-Pair Assembling Atoms: Part 2: 183W NMR Structural Study of the Inorganic Cryptates [MAs4W40O140](28-n)- and [MSb9W21O86](19-n)-(Mn+ = Alkaline or Alkaline Earth Cation).- Blue Electron Distributions in Diamagnetic Reduced Heteropoly Tungstates. Insights Concerning Conduction Pathways and Spin Coupling Patterns. 183W NMR Chemical Shift Calculations.- Interactions between Delocalized and Localized Electrons in Heteropoly Blues Containing Paramagnetic Transition Metals. Magnetic Susceptibility and NMR Studies.- Polyoxovanadates: The Missing Link between Simple Paramagnets and Bulk Magnets?.- Molecular Magnetic Materials from Polyoxometalates.- The Use of Polyoxometalates in Charge Transfer Salts.- C: Applications-Catalysis and Biology.- Catalytic Chemistry of Solid Polyoxometalates and Their Industrial Applications.- Polyoxoanions in Homogeneous Catalysis: Polyoxoanion-Supported, Atomically-Dispersed Iridium, [(l,5-COD)Ir-P2W15Nb3O62]8-.- Palladium and Phosphomolybdovanadate Catalyzed Olefin Oxidation to Carbonyls.- Mixed Addenda Phosphomolybdovanadates as Catalysts for Oxidations Dioxygen and Hydrogen Peroxide.- Role of Vanadium in Oxidation Catalysis by Heteropolyanions.- Photocatalytic Processes by Polyoxometalates. Splitting of Water. The Role of Dioxygen.- Polyoxometalates for Molecular Devices: Antitumor Activity and Luminescence.- Polyoxometalates in Catalytic Selective Homogeneous Oxygenation and Anti-HIV Chemotherapy.- Of Therapy, Toxicity and Tungstates: The Anti-Retroviral Pharmacology of Polyoxometalates.- Polyoxometalates in AIDS Therapy.- Interactions of Oxovanadates and Selected Oxomolybdates with Proteins.