Porous, Crystalline, Covalent Organic Frameworks
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Cites background from "Porous, Crystalline, Covalent Organ..."
...P orous materials such as zeolites (1), metalorganic frameworks (MOFs) (2–4), covalent organic frameworks (COFs) (5), and porous polymers (6) have widespread uses in adsorption, catalysis, separation, purification, and energy storage and production....
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...2012 Alkane/alkene separation by a MOF (55) Covalent organic frameworks (COFs) (5) High pore volume MOF, MIL-101 (40)...
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"Porous, Crystalline, Covalent Organ..." refers background in this paper
...At higher pressures, a slow rise in the isotherm occurs because of the existence of a small population of external mesopores between the crystallites; this feature is not uncommon for particles with platelet morphologies (19)....
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...These values surpass those of other layered materials, including graphite (10 m(2) g), clays (10 to 100 m(2) g), and pillared clays (50 to 300 m(2) g) and are in the range of the most porous zeolites and many porous carbons (19)....
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...The total surface area was calculated to be 711 m(2) g, with a micropore contribution of 587 m(2) g (83%) and mesopore contribution of 124 m(2) g (17%) from de Boer statistical thickness (t-plot) analysis (19)....
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